• Title/Summary/Keyword: subcritical

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Extraction of PCBs by Subcritical Water Extraction (Subcritical Water Extraction에 의한 PCBs 추출)

  • Kwak, Dong Hwan;Moon, Ji Yong;Lee, Sung In;Jeong, Gi Ho
    • Analytical Science and Technology
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    • v.13 no.4
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    • pp.511-519
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    • 2000
  • Water in the supercritical state ($T{\geq}374^{\circ}C$, $p{\geq}221$ atm) is a good solvent for nonorganic pollutants, but it is extremely corrosive. Subcritical Water Extraction (SWE) is a very fast and an efficient method to extract nonpolar environmental pollutants adsorbed on the sediments and soils. Many nonpolar organic compounds are sufficiently soluble to be extracted to the water under subcritical conditions. Complete extraction of PCBs from the sediments and soils takes only a few minutes by applying SWE with the subcritical water at 50 atm and at $260^{\circ}C$.

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A Study on Hot Straining Embrittlement of Subcritical HAZ in Steel Weldments (강 용접 열영향부 취화역 의 열변형취화 에 관한 연구)

  • 정세희;김태영;임재규
    • Journal of Welding and Joining
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    • v.3 no.2
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    • pp.35-41
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    • 1985
  • The fracture toughness of subcritical HAZ in the hot strained weldments of two structural steels(SB 41 and SA 537) has been investigated by COD test method and metallurgical study. The obtained results are summarized as follows; 1. The hot straining embitterment of subcritical HAZ depends on the hot straining amounts of notch tip, and the transition temperature( $T_{tr}$ ) increases with the accumulated hot straining amounts(.SIGMA. vertical bar .delta.$_{t}$vertical bar). 2. The fracture toughness of subcritical HAZ depends on materials and microstructure. The transition temperature( $T_{tr}$ ) of subcritical HAZ in SB 41 is almost same as that of parent material, however in SA 537 the temperature is higher than that of parent and lower than that of transformed HAZ. 3. The subcritical HAZ in SA 537 shows a higher toughness at small amounts of hot straining (.SIGMA. vertical bar .delta. $_{t}$vertical bar<0.3mm).mm).

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Numerical Simulations of Subcritical Reactor Kinetics in Thermal Hydraulic Transient Phases

  • J. Yoo;Park, W. S.
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05a
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    • pp.149-154
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    • 1998
  • A subcritical reactor driven by a linear proton accelerator has been considered as a nuclear waste incinerator at Korea Atomic Energy Research Institute(KAERI). Since the multiplication factor of a subcritical reactor is less than unity, to compensate exponentially decreasing fission neutrons from spallation reactions are essentially required for operating the reactor in its steady state. furthermore, the profile of accelerator beam currents is very important in controlling a subcritical reactor, because the reactor power varies in accordance of the profile of external neutrons. We have developed a code system to find numerical solutions of reactor kinetics equations, which are the simplest dynamic model for controlling reactors. In a due course of our previous numerical study of point kinetics equations for critical reactors, however, we learned that the same code system can be used in studying dynamic behavior of the subcritical reactor. Our major motivation of this paper is to investigate responses of subcritical reactors for small changes in thermal hydraulic parameters. Building a thermal hydraulic model for the subcritical reactor dynamics, we performed numerical simulations for dynamic responses of the reactor based on point kinetics equations with a source term. Linearizing a set of coupled differential equations for reactor responses, we focus our research interest on dynamic responses of the reactor to variations of the thermal hydraulic parameters in transient phases.

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In vitro cytotoxic activity of ginseng leaf/stem extracts obtained by subcritical water extraction

  • Lee, Kyoung Ah;Kim, Kee-Tae;Chang, Pahn-Shik;Paik, Hyun-Dong
    • Journal of Ginseng Research
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    • v.38 no.4
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    • pp.289-292
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    • 2014
  • Ginseng leaf/stem extract produced by subcritical water extraction at high temperature ($190^{\circ}C$) posses higher cytotoxic activity against human cancer cell lines than ethanol extract. Subcritical water extraction can be a great candidate for extraction of functional substance from ginseng leaves/stems.

Extraction of Reducing Sugar with Anti-Oxidative Scavengers from Peels of Carya cathayensis Sarg.: Use of Subcritical Water

  • Shimanouchi, Toshinori;Ueno, Shohei;Yang, Wei;Kimura, Yukitaka
    • Environmental Engineering Research
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    • v.19 no.1
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    • pp.41-45
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    • 2014
  • The peels of Carya cathayensis Sarg. (PCCS) were treated under subcritical water conditions ($130^{\circ}C$ to $280^{\circ}C$ for 0 to 120 min). The extract from PCCS included reducing sugar, proteins, and compounds with radical scavenging activity. Addressing the reducing sugar that is a resource of bioethanol, we could maximize the reducing sugar under the subcritical water ($190^{\circ}C$ for 60 min) and obtain 0.24 g/g-sample together with 9.7 units/mg-sample of radical scavenging activity. The obtained extract was estimated to correspond to 1 L of bioethanol/100 g-sample. It was therefore considered that the treatment by subcritical water could yield reducing sugar and natural compounds with radical scavenging activity.

Progressive Failure of a Rock Slope by the Subcritical Crack Growth of Asperities Along Joints (절리면의 응력확대계수가 파괴인성보다 작은 암반사면의 진행성 파괴)

  • Kim, Chee-Hwan;Kemeny, John
    • Tunnel and Underground Space
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    • v.19 no.2
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    • pp.95-106
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    • 2009
  • Numerical analysis of the progressive failure of a rock slope was conducted using a 3-D rock joint element considering fracture mechanics and subcritical crack growth of asperities in the rock joints. Even though the stress state in the rock slope is not changing, the elapse of time causes subcritical crack growth to break asperities in the joints. The increase of broken asperities causes failure of joints in the rock slope and the increase of failed joints results in failure of a jointed rock slope. As a result, the progressive failure of a jointed rock slope due to the gradual breaking of small asperities along joints generated by subcritical crack growth occurs at a lower stress than if rock failure occurred by exceeding the static strength or fracture toughness.

Computational design and characterization of a subcritical reactor assembly with TRIGA fuel

  • Asuncion-Astronomo, Alvie;Stancar, Ziga;Goricanec, Tanja;Snoj, Luka
    • Nuclear Engineering and Technology
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    • v.51 no.2
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    • pp.337-344
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    • 2019
  • The TRIGA fuel of the Philippine Research Reactor-1 (PRR-1) will be used in a subcritical reactor assembly (SRA) to strengthen and advance nuclear science and engineering expertise in the Philippines. SRA offers a versatile and safe training and research facility since it can produce neutrons through nuclear fission reaction without achieving criticality. In this work, we used a geometrically detailed model of the PRR-1 TRIGA fuel to design a subcritical reactor assembly and calculate physical parameters of different fuel configurations. Based on extensive neutron transport simulations an SRA configuration is proposed, comprising 44 TRIGA fuel rods arranged in a $7{\times}7$ square lattice. This configuration is found to have a maximum $k_{eff}$ value of $0.95001{\pm}0.00009$ at 4 cm pitch. The SRA is characterized by calculating the 3-dimensional neutron flux distribution and neutron spectrum. The effective delayed neutron fraction and mean neutron generation time of the system are calculated to be $748pcm{\pm}7pcm$ and $41{\mu}s$, respectively. Results obtained from this work will be the basis of the core design for the subcritical reactor facility that will be established in the Philippines.

MULTIPLICITY RESULT OF THE SOLUTIONS FOR A CLASS OF THE ELLIPTIC SYSTEMS WITH SUBCRITICAL SOBOLEV EXPONENTS

  • JUNG, TACKSUN;CHOI, Q-HEUNG
    • Korean Journal of Mathematics
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    • v.23 no.4
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    • pp.619-630
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    • 2015
  • This paper is devoted to investigate the multiple solutions for a class of the cooperative elliptic system involving subcritical Sobolev exponents on the bounded domain with smooth boundary. We first show the uniqueness and the negativity of the solution for the linear system of the problem via the direct calculation. We next use the variational method and the mountain pass theorem in the critical point theory.

Stability Analysis of an Accelerator-Driven Fluid-Fueled Subcritical Reactor System

  • Kim, Do-Sam;Cho, Nam-Zin
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05a
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    • pp.90-95
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    • 1997
  • In this work, linear dynamics of a circulating fluid-fueled subcritical reactor system with temperature feedback and external neutron source was modeled and examined. In a circulating fluid-fuel system, the stable region is slightly moved by a circulation fluid effect. The effects of subcriticality and temperature feedback coefficient on the reactor stability were tested by calculating frequency response of neutron density originated from reactivity perturbation or external source oscillation of system. The amplitude transfer function has a different shape near subcritical region due to the exponential term in the transfer function. The results of the study show that at a slightly subcritical region, low frequency oscillation in accelerator current or reactivity can be amplified depending on the temperature feedback. However, as the subcriticality increases, the oscillation becomes negligible regardless of the magnitude of the temperature feedback coefficient.

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Study on Subcritical Water Degradation of RDX Contaminated Soil in Batch and Dynamic Mode (배치형과 연속흐름형에 의한 토양 중 RDX의 아임계 분해특성 비교연구)

  • Choi, Jae-Heon;Lee, Hwan;Lee, Cheol-Hyo;Kim, Ju-Yup;Park, Jeong-Hun;Jo, Young-Tae
    • Journal of Soil and Groundwater Environment
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    • v.20 no.6
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    • pp.95-102
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    • 2015
  • The purpose of this study is to compare the degradation characteristics by subcritical water of RDX contaminated soil using batch mode and dynamic mode devices. First, upon application of RDX contaminated soil, RDX treatment efficiency was increased with increasing the temperature in both modes. At 150℃, the treatment efficiency was 99.9%. RDX degradation efficiency got higher with lower ratio of solid to liquid. However, the treatment efficiency in the dynamic mode tended to be decreased at a certain ratio of solid to liquid or lower. The treatment efficiency was increased when it took longer time for the reactions in both modes. As the results of analysis on concentration of treated water after subcritical water degradation, the RDX recovery rate of dynamic and batch modes at 150℃ was 10.5% and 1.5%, respectively. However, both modes showed very similar recovery rates at 175℃ or higher. RDX degradation products were analyzed in treated water after it was treated with subcritical water. According to the results, RDX degradation mechanism was mostly oxidation reaction and reduction reaction was partially involved. Therefore, it suggested that most of RDX in soil was degraded by oxidation of subcritical water upon extraction. According to this result, it was found that both batch and dynamic modes were very effectively applied in the treatment of explosive contaminated soil.