• 대한화학회지
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• 제51권6호
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• pp.595-599
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• 2007

• 분석과학
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• 제18권5호
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• pp.381-385
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• 2005

The title compound, $\{H_2NCH_2CH_2NH_2CH_2CH_2\}\{Cu(H_2O)_6\}(SO_4)_2$, I, has been synthesized under solvo/hydrothermal conditions and their crystal structure analyzed by X-ray single crystallography. Compound I crystallizes in the monoclinic system, $P2_1/n$ space group with a = 6.852(1), b = 10.160(2), $c=11.893(1){\AA}$, ${\beta}=92.928(8)^{\circ}$, $V=826.9(2){\AA}^3$, Z = 2, $D_x=1.815g/cm^3$, $R_1=0.031$ and ${\omega}R_2=0.084$. The crystal structure of the piperazine templated Cu(II)-sulfate demonstrate zero-dimensional compound constituted by doubly protonated piperazine cations, hexahydrated copper cations and sulfate anions. The central Cu atom has a elongated octahedral coordination geometry. The crystal structure is stabilized by three-dimensional networks of the intermolecular $O_{water}-H{\cdots}O_{sulfate}$ and $N_{pip}-H{\cdots}O_{sulfate}$ hydrogen bonds between the water molecules and sulfate anions and protonated piperazine cations. Based on the results of thermal analysis, the thermal decomposition reaction of compound I was analyzed to have three distinctive stages.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집
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• pp.119-122
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• 2002

The calculated and measured dielectric constant of (1-x)(Al$\sub$1/2/Ta$\sub$1/2/)O$_2$-x(Mg$\sub$1/3/Ta$\sub$2/3/)O$_2$(O$\leq$x$\leq$1.0) solid solutions were investigated by variations of ionic polarizability and crystal structure. (Al$\sub$1/2/Ta$\sub$1/2/)O$_2$ and (Mg$\sub$1/3/Ta$\sub$2/3/)O$_2$were orthorhombic and tetragonal trirutile structure, respectively. When (Al$\sub$1/2/Ta$\sub$1/2/)O$_2$ was substituted by (Mg$\sub$1/3/Ta$\sub$2/3/)O$_2$, the phase transformed to tetragonal structure over 60 mole%. Because the ionic radius of (Mg$\sub$1/3/Ta$\sub$2/3/)O$_2$was slightly bigger than one of (A1$\sub$1/2/Ta$\sub$1/2)O$_2$, the cell parameters increased with an increase of (Mg$\sub$1/3/Ta$\sub$2/3/)O$_2$ substitution. The measured dielectric constant increased with an increase of (Mg$\sub$1/3/Ta$\sub$2/3/)O$_2$ substitution and coincided with dielectric mixing rule and the calculated dielectric constant with the molecular additivity rule. There were some differences between the measured and the calculated dielectric constant. The reason of the lowered dielectric constant comparing with the calculated one was compressed stress due to the electronic structure of tantalum.

• 센서학회지
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• 제32권6호
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• pp.441-446
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• 2023

Electrical and optical characteristics of the GaN-based light-emitting diode (LED) with the improved multi-quantum well (MQW) structure have been studied for light source in bio-sensing systems. Novel GaN/In_0.1GaN/In_0.2GaN/In_0.1GaN/GaN and Al_0.1GaN/GaN/In_0.2GaN/GaN/Al_0.1GaN (MQW) structures were suggested, and their radiative recombination rate, light output power, electroluminescence, and external quantum efficiency were compared with those of the conventional GaN/In_0.2GaN/GaN MQW structure using device simulation. The LED with the GaN/In_0.1GaN/In_0.2GaN/In_0.1GaN/GaN MQW structure showed an excellent recombination rate of 5.57 × 10²⁸ cm^-3·s^-1 that was more than one order improvement over that of the conventional LED. In addition, the efficiency droop was relieved by the suggested stepped MQW structure.

• Smart Structures and Systems
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• 제29권5호
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• pp.747-755
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• 2022

Hierarchical structure parameters, proposed in She-Leveque model, are investigated for velocity components obtained from different flow types over a large range of Reynolds numbers 255 < Re_𝜆 < 720. The values of intermittency parameter 𝛽, with respect to a fixed velocity component, are observed nearly same for all four types of turbulence. The parameter 𝛾, for streamwise velocity components is nearly the same but significantly different for vertical components in different flows. It is also observed that for both parameters, an obvious relation between the longitudinal and transverse components 𝛽_T < 𝛽_L (and 𝛾_T < 𝛾_L) always holds. However, the difference between 𝛽_L and 𝛽_T is found very small in all types of turbulent flows, we studied here. It is evidenced that at low Reynolds numbers, the deviations from K41 scaling are mainly due to the most intense structures and slightly because of more heterogeneous hierarchy of fluctuation structures. However, at higher Reynolds numbers the deviations seem as a consequence of the most intense structures only. Over all, the study suggests that the hierarchy parameter 𝛽 may be consider as a universal constant.

• 한국초전도ㆍ저온공학회논문지
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• 제25권2호
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• pp.5-9
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• 2023

The effect of La_0.7Sr_0.3MnO₃ (LSMO) addition on the superconducting property of Bi_1.6Pb_0.4Sr₂Ca₂Cu₃O_10+δ ((Bi, Pb)-2223) polycrystalline samples was studied. LSMO (0.3 wt.% to 2.0 wt.%) added (Bi, Pb)-2223 samples were prepared by using a solid-state reaction method. The XRD analyses show that as the LSMO addition increases, the volume fraction of the Bi-2223 phase is gradually decreased. The critical temperature (T_c) exhibits a gradual decrease with a single transition as the LSMO amount increases up to 1.0 wt.%, but a further addition of LSMO induces an abrupt decrease of T_c with a dual transition. The analyses on the local structure of the CuO₂ plane from the X-ray absorption fine structure (EXAFS) measurements showed that for the samples with low concentration of LSMO up to 1.0 wt.%, the Cu-O bond length and the CuO₂ plane ordering do not degrade from the values of pure (Bi, Pb)-2223, while they get worsen with a further increase of LSMO addition. These results open up the possibility of LSMO as artificial pinning centers of the (Bi, Pb)-2223 system for power application.

• 대한수학회지
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• 제39권3호
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• pp.411-424
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• 2002

We construct the canonical connection associated with a hypercontact structure. Moreover, we discuss the canonical connection associated with a sub-Riemannian 3-structure. As an application, we study the sub-symmetry property in terms of the canonical connection.

• Bulletin of the Korean Chemical Society
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• 제35권4호
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• pp.1225-1228
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• 2014

• 대한화학회지
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• 제60권5호
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• pp.321-326
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• 2016

Two new polymeric complexes, [Zn(dpa)(pyz)_0.5]_n (1; dpa = diphenate and pyz = pyrazine) and [Mn₃(bpdc)₃(py)₄]_n (2; bpdc = biphenyl-4,4'-dicarboxylate and py = pyridine) were successfully isolated by the hydro- and solvo-thermal technique, respectively. The complexes were characterized by elemental and thermal analysis, vibrational IR spectroscopy, and by single crystal x-ray structure determination. For 2, magnetic property was also investigated. Complex 1 is a two-dimensional layer structure consisting of a paddle-wheel building unit of Zn-dpa chains bridged by pyrazine. While, complex 2 consists of linear trimeric Mn3 cluster as building unit to form 3D network. In the complexes, dpa²⁻ (1) and bpdc²⁻(2) ligands show a typical bis-monodendate bridging and two kinds of bridging modes; a typical bridging and chelating/bridging mode, respectively.

• Applied Microscopy
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• 제46권3호
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• pp.160-163
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• 2016

Effect of dealloying condition on the formation of nanoporous structure in melt-spun $Al_{60}Ge_{30}Mn_{10}$ alloy has been investigated in the present study. In as-melt-spun $Al_{60}Ge_{30}Mn_{10}$ alloy spinodal decomposition occurs in the undercooled liquid during cooling, leading to amorphous phase separation. By immersing the as-melt-spun $Al_{60}Ge_{30}Mn_{10}$ alloy in 5 wt% HCl solution, Al-rich amorphous region is leached out, resulting in an interconnected nano-porous $GeO_x$ with an amorphous structure. The dealloying temperature strongly affects the whole dealloying process. At higher dealloying temperature, dissolution kinetics and surface diffusion/agglomeration rate become higher, resulting in the accelerated dealloying kinetics, i.e., larger dealloying depth and coarser pore-ligament structure.