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Effects of application rate and pH of carbonized rice husk on the reduction of NH3 volatilization and soil quality

  • Yun-Gu Kang;Jae-Han Lee;Jun-Yeong Lee;Taek-Keun Oh
    • Korean Journal of Agricultural Science
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    • v.50 no.2
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    • pp.231-239
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    • 2023
  • Ammonia (NH3) emitted from the use of fertilizers during agricultural practice generates particulate matter and odors. The application of carbonized rice husk, an eco-friendly material, is one of the measures used to reduce NH3. The objective of this study was to evaluate the effect of the application rate and pH of carbonized rice husk on NH3 emissions and soil quality. An experiment to assess NH3 emissions was performed in a glasshouse using a static chamber method. The pH of the carbonized rice husk was divided into acidic, neutral, and basic groups, and the carbonized rice husk application rates were 1, 3, and 5% of the soil weight. NH3 emissions showed a sharp increase within three days after the inorganic fertilizer was applied. Subsequently, NH3 emissions decreased rapidly after basal fertilization compared to primary and secondary top-dressing. When carbonized rice husks were applied to soil, NH3 emissions decreased in all treatments, and neutral carbonized rice husk was the most effective in comparison with acidic and basic carbonized rice husk. The application rate of carbonized rice husk and NH3 emissions showed a negative correlation, and the lowest emissions were found in units with a 5% application rate. Also, there was no statistically significant difference between NH3 emissions according to the application rate of carbonized rice husk, and when carbonized rice husks were applied at a 5% rate, soil OM increased excessively. Therefore, it is recommended to apply only 1% neutral carbonized rice husk to most effectively reduce NH3 emissions in the soil.

Evaluation of at-home bleaching protocol with application on different surfaces: bleaching efficacy and hydrogen peroxide permeability

  • Heloisa Forville;Michael Willian Favoreto;Michel Wendlinger;Roberta Micheten Dias;Christiane Philippini Ferreira Borges;Alessandra Reis;Alessandro D. Loguercio
    • Restorative Dentistry and Endodontics
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    • v.48 no.4
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    • pp.33.1-33.12
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    • 2023
  • Objectives: This study aimed to evaluate the bleaching efficacy and hydrogen peroxide permeability in the pulp chamber by the at-home bleaching gel in protocols applied on different dental surfaces. Materials and Methods: Forty premolars were randomly into 4 groups: control group no bleaching, only application on the buccal surface (OB), only application on the lingual surface (OL) and application in buccal and lingual surfaces, simultaneously (BL). At-home bleaching gel (White Class 7.5%) was used for the procedure. The bleaching efficacy was evaluated with a digital spectrophotometer (color change in CIELAB [ΔEab] and CIEDE 2000 [ΔE00] systems and Whitening Index for Dentistry [ΔWID]). The hydrogen peroxide permeability in the pulp chamber (㎍/mL) was assessed using UV-Vis spectrophotometry and data were analyzed for a 1-way analysis of variance and Tukey's test (α = 0.05). Results: All groups submitted to bleaching procedure showed bleaching efficacy when measured with ΔEab and ΔE00 (p > 0.05). Therefore, when analyzed by ΔWID, a higher bleaching efficacy were observed for the application on the groups OB and BL (p = 0.00003). Similar hydrogen peroxide permeability was found in the pulp chambers of the teeth undergoing different protocols (p > 0.05). Conclusions: The application of bleaching gel exclusively on the OB is sufficient to achieve bleaching efficacy, when compared to BL. Although the OL protocol demonstrated lower bleaching efficacy based on the ΔWID values, it may still be of interest and relevant in certain clinical scenarios based on individual needs, requiring clinical trials to better understand its specificities.

Electrodeposited WO3 films and their application in electrochromic boards

  • Kim, Dae-Hyeon;Kang, Kwang-Mo;Nah, Yoon-Chae
    • Journal of the Korean institute of surface engineering
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    • v.55 no.4
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    • pp.187-195
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    • 2022
  • WO3 thin films were synthesized by electrodeposition, and their electrochromic properties were investigated. The application of static voltage produced WO3 films with a smooth, compact surface morphology, and the film thickness linearly increased with the application time. The thicker film showed a strong color contrast but a slow color-switching speed. High-temperature heat treatment exceeding 300 ℃ induced a phase transformation from an amorphous to a monoclinic structure and resulted in degraded electrochromic performance. Furthermore, the optimized WO3 thin films demonstrated their potential application as electrochromic boards for writing and erasing letters using a simple modified 3D printer in a rapid, accurate process

Assessment of Nitrogen Fate in the Soil by Different Application Methods of Digestate (혐기성 소화액의 농지환원에 따른 질소 거동)

  • Nkombo, Laure Lysette Chimi;Hong, Seong Gu
    • Journal of The Korean Society of Agricultural Engineers
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    • v.63 no.3
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    • pp.35-45
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    • 2021
  • Digestate or slurry produced from anaerobic digestion is mostly applied to crop lands for its disposal and recovering nutrients. However, minimizing nitrogen losses following field application of the digestate is important for maximizing the plant's nitrogen uptake and reducing environmental concerns. This study was conducted to assess the effects of three different biogas digestate application techniques (sawdust mixed with digestate (SSD), the hole application method (HA), and digestate injected in the soil (SD)) on nitrate leaching potential in the soil. A pot laboratory experiment was conducted at room temperature of 25 ± 2 ℃ for 107 days. The experimental results showed that sawdust application method turned out to be appropriate for quick immobilization of surplus N in the form of microbial biomass N, reflecting its lower total nitrogen and NH4-N contents and low pH. The NH4-N and total nitrogen fate in the soil fertilized with manure showed no statistically significant (p > 0.05) differences between the different methods applied during the incubation time under room temperature. In contrast, NO3-N concentration indicates significant reduction in sawdust treatment (p < 0.05) compared to the control and other application methods. However, the soil sawdust mixed with digestate was more effective than the other methods, because of the cumulative labile carbon contents of the amendment, which implies soil net N immobilization.

Acidification and Biochar Effect on Ammonia Emission and Nitrogen Use Efficiency of Pig Slurry in the Vegetative Growth of Maize (Zea mays L.)

  • Lee, Seung Bin;Park, Sang Hyun;Lee, Bok Rye;Kim, Tae Hwan
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.42 no.1
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    • pp.47-53
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    • 2022
  • The objective of this study was to verify the effect of pig slurry application with acidification and biochar on feed value, nitrogen use efficiency (NUE) of maize forage, and ammonia (NH3) emission. The four treatments were applied: 1) non-pig slurry (only water as a control, C), 2) only pig slurry application (P), 3) acidified pig slurry application (AP), 4) acidified pig slurry application with biochar (APB). The pig slurry and biochar were applied at a rate of 150 kg N ha-1 and 300 kg ha-1, respectively. The AP and APB treatments enhanced all feed values compared to C and P treatments. The NUE for plant N was significantly increased 92.1% by AP and APB treatment, respectively, compared to the P treatment. On the other hand, feed values were not significantly different between AP and APB treatments. The acidification treatment with/without biochar significantly mitigated NH3 emission compared to the P treatment. The cumulative NH3 emission throughout the period of measurement decreased by 71.4% and 74.8% in the AP and APB treatments. Also, APB treatment reduced ammonia emission by 11.9% compared to AP treatment. The present study clearly showed that acidification and biochar can reduce ammonia emission from pig slurry application, and pig slurry application with acidification and biochar exhibited potential effects in feed value, NUE, and reducing N losses from pig slurry application through reduction of NH3 emission.

Characteristics of Al2O3, Cr2O3, WC-Ni, and Chromizing Surface Coatingsunder Environment with HighTemperature, Wear, and Corrosion (고온, 마모 및 부식환경에 적용가능한 Al2O3, Cr2O3, WC-Ni 및 크로마이징 코팅층의 기계적 특성 평가)

  • Cho, Hee Keun
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.6
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    • pp.895-900
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    • 2013
  • Several plasma spray and metallurgical surface coatings such as $Al_2O_3$, $Cr_2O_3$, WC-Ni, and chromizing coating have been examined for their application in environments with high temperature, wear, and corrosion. The chromizing coating is different from others coatings in the manufacturing process the surface. These coatings' characteristics were tested experimentally, and the results were compared. WC-Ni shows good performance against thermal barrier, wear, and corrosion and is one of the best candidates for the environment considered herein. These coatings were studied for their application in the steel manufacturing industry. The most commonly required functions in this industry are thermal and wear resistance.

In-office dental bleaching with violet light emitting diode: bleaching efficacy and pulpal temperature rise

  • Brunna Katyuscia de Almeida Guanaes;Talyta Neves Duarte;Gisele Maria Correr;Marina da Rosa Kaizer;Carla Castiglia Gonzaga
    • Restorative Dentistry and Endodontics
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    • v.47 no.1
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    • pp.7.1-7.14
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    • 2022
  • Objectives: This study evaluated the bleaching efficacy of different in-office protocols associated with violet light emitting diode (V-LED), and measured the pulpal temperature rise caused by V-LED with or without gel application. Materials and Methods: Bovine incisors were distributed in 4 groups (n = 10): VL - V-LED; HP - 35% hydrogen peroxide (control); HYB - hybrid protocol, V-LED applied without gel for 10 irradiation cycles followed by V-LED applied with gel for another 10 irradiation cycles; and HPVL - gel and V-LED applied for 20 irradiation cycles. Three bleaching sessions were performed with 7-day intervals. Bleaching efficacy was evaluated with ΔEab*, ΔE00 and ΔWID. Data were recorded at baseline, 7, 14, 21 and 70 days. For pulpal temperature rise, thermocouples were placed inside the pulp chamber of human incisors. To determine intrapulpal temperature, the teeth were irradiated with V-LED with or without application of bleaching gel. Color difference data were analyzed by 2-way repeated measures ANOVA and Tukey's test. Pulpal temperature was analyzed by t-test (α = 5%). Results: VL exhibited lower color (ΔEab* and ΔE00) and whiteness changes (ΔWID) than the other groups. HPVL presented higher color change values than HYB. HYB and HPVL showed not different ΔWID values; and HP showed the highest whiteness changes at all times. There were significant differences comparing ΔT with gel (8.9℃) and without gel application (7.2℃). Conclusions: HPLV was more efficient than HYB. The 2 protocols with VL showed similar results to control. Gel application combined with VL promoted higher pulpal temperature than to the no gel group.

Effects of Charcoal Application on Ammonia Emission and Nitrogen Use Efficiency of Pig Slurry in the Vegetative Growth of Maize (Zea Mays L.)

  • Lee, Seung Bin;Park, Sang Hyun;Kim, Tae Hwan
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.41 no.4
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    • pp.280-286
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    • 2021
  • The objective of this study was to prove the effect of pig slurry application with charcoal on nitrogen use efficiency (NUE), feed value and ammonia (NH3) emission from maize forage. The four treatments were applied: 1) non-pig slurry (only water as a control), 2) only pig slurry application (PS), 3) pig slurry application with large particle charcoal (LC), 4) pig slurry application with small particle charcoal (SC). The pig slurry was applied at a rate of 150 kg N ha-1, and the charcoal was applied at a rate of 300 kg ha-1 regardless of the size. To determine the feed value of maize, crude protein, dry matter intake, digestible dry matter, total digestible nutrient, and relative feed value were investigated. All feed value was increased by charcoal treatment compared to water and PS treatment. Also, the NUE for plant N was significantly higher in charcoal treatments (LC and SC) compared to PS treatment. On the other hand, there is no significant difference for feed value and NUE between LC and SC. The NH3 emission was significantly reduced 15.2% and 27.9% by LC and SC, respectively, compared to PS. Especially, SC significantly decreased NH3 emission by 15% compared to LC. The present study clearly showed that charcoal application exhibited positive potential in nitrogen use efficiency, feed value and reducing N losses through NH3 emission.