• Title/Summary/Keyword: styrene-acrylonitrile

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The Effect of Injection Molding Temperature on the Morphology of Polycarbonate/ABS blends (Polycarbonate/ABS 블렌드에서 사출온도에 따른 모폴로지 변화에 관한 연구)

  • Son, Young-Gon
    • Elastomers and Composites
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    • v.39 no.4
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    • pp.324-329
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    • 2004
  • The phase morphology, degree of craze and impact property in Polycarbonate (PC)/Acrylonitrile-Butadiene- styrene (ABS) blend containing the phosphate based flame retardant were studied in terms of injection molding temperatures. As the injection molding temperature increases, significant amount of coalescences and crazes were observed and impact strength decreased. It was also observed that the addition of compatibilizer into the blends suppresses the coalescence and craze.

Evaluation of proficiency and improvement of accuracy on the analysis of brominated flame retardants (PBDEs) in ABS polymer (ABS수지 중 polybrominated diphenyl ether(PBDE)류 분석 숙련도 평가 및 정확도 향상)

  • Ryu, Jehoon;Kim, Dalho
    • Analytical Science and Technology
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    • v.28 no.6
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    • pp.446-452
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    • 2015
  • In order to evaluate and improve the ability of Korean testing laboratories to measure Polybrominated diphenyl ethers in acrylonitrile-butadiene-styrene (ABS), a proficiency test was organised by Korea Research Institute of Standards and Science (KRISS) based on ISO/IEC 17043. The proficiency test material used was 10 g of a granular ABS fortified with a mixture of congeners of PBDE (BDE-154, 183, 206, 209). Homogeneity and stability were investigated to assess the adequacy of the test material. The certified value established by KRISS based on the national reference was used for assigned value of each PBDE. The test materials were distributed to the 16 participating laboratories. The participating laboratories were requested to analyse the samples employing the methods used in their routine analysis. Each laboratory was given it’s own code to secure the anonymity. Participants results were evaluated with z-scores according to ISO/IEC 17043. The standard deviation for proficiency assessment was set by standard deviation of the participants results except for outlier. The results, the laboratory's performance and improvement of accuracy were discussed.

A Study of 3D Printing of Self-Customization Cast by Using Fused Deposition Modeling Technique of ABS Resin (ABS 수지의 용융적층조형방식에 의한 자가 맞춤형 부목의 3차원 출력 사례 연구)

  • Seoung, Youl-Hun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.9
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    • pp.6019-6026
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    • 2015
  • In this study, we have tried to use 3D-printing technology, which is very useful for small amount production and individual personalization manufacturing to produce a cast customized by individual. To do this, we have made casts by the 3D printer in the method of fused deposition modeling technique using ABS(acrylonitrile butadiene styrene) resin which is thermoplastic plastics. The computed tomography of human hand part was used as the modeling of the cast and it was designed to circulate air well. As a result, an individual personalized cast that fitted well with the model part was produced. In addition, we could get more excellent radiography from the cast than the existing cast. In conclusion, this study of 3D-printing could be used as basic data when a similar designed structure in fused deposition modeling technique by ABS resin is printed out.

Effect of Acrylonitrile-Butadiene Rubber on the Properties of Silica-Filled Styrene-Butadiene Rubber Compounds: Reduction of Silane Coupling Agent and Diphenylguanidine (실리카로 보강된 SBR 배합물의 특성에 미치는 NBR 효과: 실란커플링제와 DPG의 사용량 감소)

  • Choi, Sung-Seen;Chang, Dong-Ho;Kim, Ik-Sik
    • Elastomers and Composites
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    • v.37 no.4
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    • pp.217-223
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    • 2002
  • Silica-filled rubber compounds show poor filler dispersion and slow cure characteristics compared to carbon black-filled ones. In general, a silica-filled rubber compound contains silane coupling agent (bis-(3-(triethoxysilyl)-propyl)-tetrasulfide, TESPT) and diphenylguanidine (DPG) to improve the filler dispersion and to make fast cure characteristics. Acrylonitrile-butadiene rubber (NBR) improves the filler dispersion in silica-filled styrene-butadiene rubber (SBR) compounds. In this study, effect of NBR on the properties of silica-filled SBR compounds was investigated. Properties of the compounds which contain NBR without DPG or with small amount of TESPT (Compound A) were compared with those of the compounds which contain TESPT and DPG without NBR (Compound B). Scorch time of Compound A is faster than those of Compound B. Modulus and tensile strength of Comound A are slightly lower than those of Compound B. Traction property of the Comound A is better than that of the Compound B. Addition of NBR leads to reduction of the used amount of TESPT and DPG.

Rheological, Mechanical and Morphological Properties of Poly(acrylonitrile-butadiene-styrene)/Polycarbonate Blends with ABS-g-MAH (ABS-g-MAH를 포함한 Poly(acrylonitrile-butadiene-styrene)과 Polycarbonate 고분자 블렌드의 유변학적, 기계적, 형태학적 물성)

  • Song, Ki-Heon;Hong, John-Hee;Sung, Yu-Taek;Kim, Youn-Hee;Han, Mi-Sun;Yoon, Ho-Gyu;Kim, Woo-Nyon
    • Polymer(Korea)
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    • v.31 no.4
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    • pp.283-288
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    • 2007
  • Polymer blends containing poly(acrylonitrile-butadiene-styrene) (ABS) and polycarbonate(PC) (70/30, wt%) with compatibilizer were prepared using twin screw extruder. Compatibilizers were prepared by reactive extrusion with the ABS, maleic anhydride(MAH) and dicumyl peroxide(DCP) using twin screw extruder In the ABS/PC (70/30) blends, tensile strength did not change significantly, but increased from 52.25 to 55.03 MPa when the ABS-g-MAH was added in the amount of 5 phr. From the results of rheological properties, storage modulus of the ABS/PC/ABS-g-MAH blends at low frequencies showed lager value than that of the ABS/PC(70/30) blend. From the results of the morphological properties of the ABS/PC(70/30) blend, it was observed that the drop size of the PC ranged from 1.2 to $1.5\;{\mu}m$ and did not change significantly with the addition of the ABS-g-MAH($1{\sim}10\;phr$). From the results of the storage modulus, complex viscosity, and tensile strength of the ABS/PC (70/30) blends, it is found that the ABS-g-MAH is an effective compatibilizer in the ABS/PC (70/30) blends when the ABS-g-MAH is added in the amount of 5 phr.

Morphology and Physical Properties of ABS/NBR Blends: The Effect of AN Content in NBR

  • Lee, Kwan-Hee;Ahn, Sang-Jun;Kim, Byung-Kyu;Jeong, Han-Mo
    • Macromolecular Research
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    • v.9 no.1
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    • pp.30-36
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    • 2001
  • Polybutadiene latex grafted (g-PB) in g-PB/SAN blends, i.e., acrylonitrile-butadiene-styrene terpolymer (ABS) were partially replaced by acrylonitrile-butadiene copolymer (NBR) with various acrylonitrile (AN) contents. Changes in morphology, physical and rheological properties were examined. The dispersed size of NBR was decreased as the miscibility with matrix SAM, was increased by increasing AN content in NBR upto 50 wt%. Impact strength was enhanced about two-fold due to the NBR dispersed with a slight larger size than the original g-PB. Gloss was effectively reduced as the particle size of NBR was increased. Tensile yield strength was decreased, and elongation at break or yield behavior at low shear rate were increased as g-PB was partially replaced by NBR having AN content less that 40 wt%.

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Effects of Blend Composition and Compatibilizer on the Mechanical Properties of Polypropylene/Acrylonitrile-Butadiene-Styrene Blends (블렌드 조성과 상용화제가 폴리프로필렌/ABS 블렌드의 기계적 물성에 미치는 영향)

  • Park, Jung-Hoon;Sung, Yu-Taek;Kim, Woo-Nyon;Hong, John-Hee;Hong, Byeong-Kwon;Yoo, Tae-Wook;Yoon, Ho-Gyu
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.19-24
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    • 2005
  • Polymer blends containing polypropylene (PP) with compatibilizers were prepared using twin screw extruder. Physical properties were investigated using universal test machine (UTM) and Izod impact tester. In the PP/acrylonitrilebutadiene-styrene (ABS) blends, mechanical strength was increased with the addition of PP-g-styrene acryloritrile (PP-g-SAN) compatibilizer, and the ductility was increased with the addition of ethylene-ethyl acrylate-maleic anhydride (E-EAMAH-g-SAN) compatibilizer. For the PP/ABS/ polycarbonate (PC)/Nylon-6,6 blends, impact strength was increased with the addition of ethylene glycidylmethacrylate (E-GMA compatibilizer) up to 0.5 phr. In the case of the PP/ABS/PC/Nylon-6,6/poly(methyl methacrylate) (PMMA)/poly(oxymethylene) (POM)/poly(vinyl acetate) (PVC)/poly(butylene terephthalate) (PBT) blends, mechanical properties were increased by the complex compatibilizing effects of PP-g-SAN, E-EA-MAH-g-SAN and E-GMA, respectively.