• Title/Summary/Keyword: structure stability

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Analyses of Larg Cell Area MCFC System Dynamics (대면적 용융탄산염 연료전지 시스템 동특성 분석)

  • 강병삼;고준호;이충곤;임희천
    • Journal of Energy Engineering
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    • v.8 no.4
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    • pp.592-604
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    • 1999
  • The steady state and dynamic characteristics of large cell area MCFC stacks were analyzed to solve the problems such as temperature difference generated in stacks and pressure difference between anode and cathode. Manipulated variables (current density, duel utilization rate, oxidant utilization rate) and controlled variables (temperature difference, anode and cathode pressure difference) which had an important effect on the MCFC stack performance were determined using operation results of two types of MCFC stacks (5kW (3,000 $\textrm{cm}^2$, 20 ea). 3kW (6,000 $\textrm{cm}^2$, 5ea)). The stability and transfer function representing system dynamics were obtained by steady state gain rate which showed the relative change between MVs and CVs. The transfer function was a 3$\times$3 matrix and a typical first order system without time delay. The optimal operating condition of large cell area MCFC stacks could be determined by analyzing dynamic characteristics. In case of a 5 kW MCFC stack, pressurized operation with recycle flow should be used to control the outlet temperature less than 68$0^{\circ}C$ and to control the MCFC system effectively. MIMO control or decoupler should be used to remove the interaction between MVs and CVs. This result will be used as important data in determining the control structure design and operation mode of large cell area MCFC systems in the future.

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Corrosion Analysis of Ni alloy according to the type of molten metal (용융아연도금욕에 적용되는 용탕에 따른 Ni합금의 부식성 분석)

  • Baek, Min-Sook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.6
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    • pp.459-463
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    • 2017
  • Hot dip galvanizing in the steel plant is one of the most widely used methods for preventing the corrosion of steel materials including structures, steel sheets, and materials for industrial facilities. While hot dip galvanizing has the advantage of stability and economic feasibility, it has difficulty in repairing equipment and maintaining the facilities due to high-temperature oxidation caused by Zn Fume where molten zinc used in the open spaces. Currently, SM45C (carbon steel plate for mechanical structure, KS standard) is used for the equipment. If a part of the equipment is resistant to high temperature and Zn fume, it is expected to improve equipment life and performance. In this study, the manufactured Ni alloy was tested for its corrosion resistance against Zn fume when it was used in the hot dip galvanizing equipment in the steel plant. Two kinds of materials currently used in the equipment, new Ni alloy and Inconel(typical corrosion-resistant Ni alloy), were selected as the reference groups. Two kinds of molten metal were used to confirm the corrosion of each alloy according to the molten metal. Zn fume was generated by bubbling Ar gas from molten Zn in a furnace($500{\sim}700^{\circ}C$) and the samples were analyzed after 30 days. After 30 days, the specimens were taken out, the oxide layer on the surface was confirmed with an optical microscope and SEM, and the corrosion was confirmed using a potentiodynamic polarization test. Corrosion depends on the type of molten metal.

A Study on the Characteristics of Inorganic Polymer Mortar for Concrete Sectional Rehabilitation (콘크리트 단면복구용 무기성 모르타르의 특성에 관한 연구)

  • Hwang, Tae-Ha;Song, Tae-Hyeob;Im, Chil-Soon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.3
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    • pp.171-177
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    • 2010
  • As concrete structures are exposed to chemical substances, damaged from salt, or progressed to the neutralization, the surface damage of the structures is generated timely fashion, resulting shortened service life. Especially, the sulfate erosion causes rapid surface defects, and the steel skeleton becomes corroded due to the water infiltration, generating stability deterioration of the concrete structure. In this study, the physical characteristics of the acid-resistant mortar with aluminosilicates was investigated in order to resolve problems of the acid resistance, one of the most serious problems of the cement type repair material. As the result of the experiment, the test specimen turned to exhibit almost equivalent physical characteristics with those of concrete sectional repair materials in terms of compressive and bending strengths. As both the cement sectional repair material and the test specimen were immerged in sulfuric acid solution to examine weight changes, the test specimens exhibited only 4% loss of their weights while the cement sectional repair materials reached at the level of 80% or above, proving the excellence acid resistant characteristics of the test specimens. Consequently, the physical characteristics of acid resistant mortar with aluminosilicates were revealed to be superior than those of concrete sectional repair materials. It can be utilized as a sectional repair material where the acidic erosion is anticipated.

Synthesis and Characterization of IPA-co-HDO-co-(TPA/MA) Anion-Exchange Membrane for All-Vanadium Redox Flow Battery (전바나듐계 레독스-흐름 전지용 IPA-co-HDO-co-(TPA/MA) 음이온교환막의 합성 및 특성)

  • Jung, Jae-Chul;Kwak, Noh-Seok;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.35 no.6
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    • pp.593-598
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    • 2011
  • The IPA-co-HDO-co-(TPA/MA) copolymers for all-vanadium redox flow battery were synthesized by melt condensation polymerization using isophthalic acid(IPA), 1,6-hexandiol (HDO), terephthalic acid(TPA) and maleic anhydride(MA). The amination of chloromethylated IPA-co- HDO-co-(TPA/MA)(CIHTM) copolymer was carried out using trimethylamine, and the anion exchange membrane was also prepared by UV crosslinking reaction. The structure and thermal stability of IHTM copolymers were confirmed by FTIR, $^1H$ NMR, and TGA analysis. The anion membrane properties such as water uptake, ion exchange capacity, electric resistance and electrical conductivity, were measured by gravimetry, titration and LCR meter. The efficiency of the all-vanadium redox flow battery was analyzed. The ion exchange capacity, electric resistance and electrical conductivity were 1.10 meq/g, $1.98{\Omega}{\cdot}cm^2$, and 0.009 S/cm, respectively. The efficiency of charge-discharge, voltage, and energy for the allvanadium redox flow battery were 96.5, 74.6, 70.0%, respectively.

The effect of Swd2's binding to Set1 on the dual functions of Swd2 in Saccharomyces cerevisiae (Saccharomyces cerevisiae의 Swd2와 Set1의 결합이 Swd2의 이중적인 기능에 미치는 영향)

  • Park, Shinae;Lee, Jung-Shin
    • Korean Journal of Microbiology
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    • v.53 no.4
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    • pp.286-291
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    • 2017
  • In eukaryotic cells, histone modification is an important mechanism to regulate the chromatin structure. The methylation of the fourth lysine on histone H3 (H3K4) by Set1 complex is one of the various well-known histone modifications. Set1 complex has seven subunits including Swd2, which is known to be important for H2B ubiquitination dependent on H3K4 methylation. Swd2 was reported to regulate Set1's methyltransferase activity by binding to near RNA recognition motif (RRM) domain of Set1 and to act as a component of CPF (Cleavage and Polyadenylation Factors) complex involved in RNA 3' end processing. According to the recent reports, two functions of Swd2 work independently of each other and the lethality of Swd2 knockout strain was known to be caused by its function as a component of CPF complex. In this study, we found that Swd2 could influence the Set1's stability as well as histone methyltransferase activity through the association with RRM domain of Set1. Also, we found that ${\Delta}swd2$ mutant bearing truncated-Set1, which cannot interact with Swd2, lost its lethality and grew normally. These results suggest that the dual functions of Swd2 in H3K4 methylation and RNA 3' end processing are not independent in Saccharomyces cerevisiae.

Labor Transition and Exclusion of Unprivileged Female Breadwinners (저소득 여성가구주의 노동이행과 배제)

  • Kim, Jeung-Hyun
    • Korean Journal of Family Social Work
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    • no.43
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    • pp.61-85
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    • 2014
  • The aim of this study is to examine how labour transition of female householders is proceeded, and to identify mechanisms that cause them to be excluded from labor market. For this, thirteen lone mothers who have had labor experience in the market, while raising children were interviewed. This qualitative case study was proceeded by way of participants' interviews and questionnaires. Finding shows, impoverished lone mothers were horizontally moving incessantly on second labor market. As poverty worsens by years, poor lone mothers tend to be more dependant on the government's support and to transit downward to work-poor labor market. The unprivileged women were excluded from multi-dimentions: market structure, social relations and gender norms. The sex-segmental and human capital-oriented market has excluded women who gave up their career for caring. Female breadwinners were frequently excluded from social relations and opportunities for labor due to their stigma. sometimes they were self-excluded from the market for they had to care for their children. In conclusion, suggestions are given to enhance qualities of lone mother's lives and help them exit from poverty. It is necessary to implement positive labor policy with labor flexibility and stability and to practice socialization of care as care support system is very important for maintaining their jobs. Above all, social awareness of gender role must be changed.

Thermal and Optical Properties of Poly{1-(Cholesteryloxycarbonylalkanoyloxy)ethylene}s (폴리{1-(콜레스테릴옥시카보닐알카노일옥시)에틸렌}들의 열 및 광학 특성)

  • Jeong, Seung-Yong;Ma, Yung-Dae
    • Polymer(Korea)
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    • v.33 no.2
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    • pp.144-152
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    • 2009
  • The thermal and optical properties of poly {1-(cholesteryloxycarbonylalkanoyloxy) ethylene}s (PCALEn, n=2$\sim$8,10, the number of methylene units in the spacer) were investigated. All of the homologues formed monotropic cholesteric phases with left-handed helical structures. PCALEn with n=2 or 10, in constrast with PCALEn with $3{\leq}n{\leq}8$, did not display reflection colors over the full cholesteric range, suggesting that the helical twisting power of the cholesteryl group highly depends on the length of the spacer connecting the cholesteryl group to the polyethylene chain. The glass transition temperatures decreased with increasing n. The isotropic-cholesteric phase transition temperatures decreased with increasing n up to 7 and showed an odd-even effect. However it became almost constant when n is more than 7. This behavior is rationalized in terms of the change in the average shape of the side chain on varing the parity of the spacer. This rationalization also accounts for the observed variation of the entropy gain for the clearing transition. The thermal stability and degree of order in the mesophase and the temperature dependence of the optical pitch observed for PCALEn were significantly different from those reported for cellulose tri(cholesteryloxycarbonyl)alkanoates. The results were discussed in terms of the differences in the chemical structure and flexibility of main chain and the number of the mesogenic units per repeating unit.

Design Methodology on Steel-type Breakwater II. Pile Design Procedure (철재형 이안제 설계기법 연구 II. 하부기초 설계 단계)

  • Kwon, Oh-Kyun;Oh, Se-Boong;Kweon, Hyuck-Min
    • Journal of the Korean Society of Hazard Mitigation
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    • v.11 no.3
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    • pp.219-228
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    • 2011
  • In this paper, the design procedure of substructure of the steel-type breakwater was described and the actual foundation design was performed for the test bed. The site investigation was executed at the Osan-port area, in Uljin, Gyeongbuk, where the steeltype detached breakwater is constructed. The foundation mainly depends on the lateral load and uplift force due to the wave force. Since the superstructure is stuck out about 9.0m from the ocean bed, the foundation must resist on the lateral force and bending moment. After considering various factors, the foundation type of this structure was determined by the steel pipe pile(${\varphi}711{\times}t12mm$). On the stability of pile foundation, the safety factors of the pile on the compressive, lateral and uplift forces were grater than the minimum factor of safety. The displacements of pile under the working load were evaluated as the values below the permissible ones. Based on the subgrade reaction method, we evaluated the relationship of subgrade reaction and displacement for the lateral and the vertical directions in the layers. The structural analyses along with the foundation were perfomed and the effect of pile foundations were compared quantitatively.

A Study on the Analysis of Monitoring Settlement Considering the History of the Groundwater Level in the Dredged Landfill Area Affected by Algae (조류의 영향을 받는 준설매립지역에서 지하수위 이력을 고려한 계측침하 분석에 관한 연구)

  • Jang, Ji-Gun;Son, Su-Won;Hong, Seok-Woo
    • Journal of the Korean Geotechnical Society
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    • v.37 no.7
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    • pp.13-23
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    • 2021
  • If roads, bridges, buildings, etc. are built on the ground with soft clay or organic soil, there may be a lot of problems in geotechnical engineering such as settlement and stability due to the large settlement and lack of bearing capacity. In extreme cases, it may appear due to shear failure or collapse of the constructed structure, so a ground improvement method is indispensable to increase the strength of the ground and to suppress settlement. In this study, the settlement according to each groundwater level condition was analyzed using the measurement results for the groundwater level conditions, one of the important factors in predicting the settlement in dredged and reclaimed ground, and the groundwater level conditions applied to the settlement analysis were proposed by comparing it with settlement generated 5 years after construction. As a result of the analysis, it is judged that it is reasonable to apply the measured groundwater level during construction and the low water ordinary neap tide (L.W.O.N.T) during load application for the groundwater level in the settlement analysis. In addition, in the case of the dredged and reclaimed ground, it is estimated that the water pressure acting on the clay layer is nonlinear, as the result of the observations of the head of water at the observation points above and below the in-situ clay layer were different.

Faunal Composition and Spatial Distributions of Macrozoobenthos in the Tidal Flat of the Nakdong River Estuary, Korea (낙동강 하구 모래갯벌에 서식하는 대형저서동물의 군집구조와 분포양상)

  • Seo, Jin-Young;Choi, Jin-Woo;Shin, Kyoungsoon
    • Journal of Marine Life Science
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    • v.5 no.2
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    • pp.81-91
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    • 2020
  • This study was conducted to find the faunal composition and distribution patterns of macrobenthos where the sand tidal flat around barrier island at Nakdong River estuary in May, 2016 and 2017. The number of species ranged from 31 to 39, and density was from 789 to 1,644 ind.m-2 during the study period in the three tidal flats. The number of species and density were the highest in the tidal flat of Shinja-do and Jinwoo-do, respectively. The dominant species were Gammaridae unid. in amphipods of crustacea, Scoletoma heteropoda, Scoloplos armiger, Heteromastus filiformis, Prionospio japonica in polychaeta and Batillaria cumingii, Laternula marilina in mollusks from the three tidal flats. The proportion of carnivores such as crustacea and mollusks was higher in the upper part of the tidal flat, and polychaetes of deposit feeders, dominated in the middle and lower tidal flat. Overall, the intertidal macrobenthic communities in the study area showed a high proportion of carnivores. However, the sites where the mud content is high such as muddy sand sites, they showed a higher proportion of surface deposit feeders belonging to tube-builders which contribute to sediment stability. From this study, it seemed that the macrobenthic fauna of the sandy tidal flat at the Nakdong River estuary showed a similar fauna composition and zonal distribution patterns from those in other sandy tidal flats in Korea.