• Analytical Science and Technology
• /
• v.18 no.5
• /
• pp.386-390
• /
• 2005

The zinc(II) complex, $Zn(NCS)_2(C_3H_4N_2S)_2$, I, has been synthesized and characterized by single crystal X-ray diffraction, thermal analysis and infrared spectroscopy. The complex I crystallizes in the triclinic system, $P\bar{1}$ space group with a = 7.587(1), b = 8.815(1), $c=12.432(2){\AA}$, ${\alpha}=75.584(8)$, ${\beta}=83.533(9)$, ${\gamma}=68.686(8)^{\circ}$, $V=750.0(2){\AA}^3$, Z = 2, $R_1=0.036$ and ${\omega}R_2=0.101$. The central Zn(II) atom has a tetrahedral coordination geometry, with the heterocyclic nitrogen atoms of 2-aminothiazole ligands and the nitrogen atoms of isothiocyanate ligands. The crystal structure is stabilized by one-dimensional networks of the intermolecular $N-H{\cdots}S$ hydrogen bonds between the amino group of 2-aminothiazole ligands and the sulfur atom of isothiocyanate ligands. Based on the results of thermal analysis, the thermal decomposition reaction of complex I was analyzed to have three distinctive stages such as the loss of 2-aminothiazole, the decomposition of isothiocyanate and the formation of metal oxide.

• The Journal of Industrial Distribution & Business
• /
• v.8 no.1
• /
• pp.5-13
• /
• 2017

Purpose - In this article, a dynamic model like a VAR is an appropriate choice for estimating the possible interrelationship between ownership structure and firm performance as a dynamic process. Research design, data, and methodology - Data of this work are collected from Chinese stock exchange including 350 Chinese-listed firms during the period of 1999-2012. We hypothesize that this interrelationship dynamically exists between ownership structure and firm performance. To examine the correlation, a panel Vector Auto-regression (PVAR) approach generated by GMM method is utilized to test the possible dynamic relation embedded in corporate governance. Another two dynamic analysis solutions such as orthogonalized impulse-response function and variance decomposition are also used simultaneously. Results - Findings of this study indicate the evidence that dynamically endogenous relationship exists between ownership structure and firm performance. Further, there is a dynamical correlation between investment and performance. Impulse response and variance decomposition illustrate that impact of a shock to variables themselves is the main source for their variability. Conclusions - The conclusion in this study is that there is a bidirectional and inter-temporal effect between proportion of ownership and corporate performance for a long run in accordance with impulse response function. Overall, our results suggest that corporate governance in China is more market oriented.

• Environmental and Resource Economics Review
• /
• v.24 no.1
• /
• pp.189-224
• /
• 2015

To meet sectoral emission target by 2020 and prepare for the emission trading scheme from 2015, decomposition analysis of energy consumption and GHG emission is required by 18 subsectors in industry sector where emission targets are established. Log Mean Divisia Index decomposition method was used to analyze factors' effects on energy and emission in the industry sector and by 18 subsectors from 2004 to 2011. Industrial energy consumption was increased due to the production effect and energy intensity effect. However structure effect contributes to the decrease of energy consumption. In terms of emissions (including indirect emission due to electricity consumption) in the industry sector, only structure effect contributed to the emission reduction. Factors' effects by subsectors were different. Cement industry, which is included at Nonmetal shows different results from those of Nonmetal industry and machinery industry, which is a subsector of Fabricated Metal, was also similar. In this regard, we should not apply the policy implications from decomposition analysis of aggregated industry such as Nonmetal or Fabricated Metal to its subsectors uniformly and develop a differentiated policy for each subsector industry.

• KSBB Journal
• /
• v.18 no.5
• /
• pp.356-362
• /
• 2003

This study defines the biotechnology industry, examines its position in the domestic economy, and analyses its structure with I-O tables of year 1985, 1990 and 1995. Structural decomposition analysis is used in order to estimate the impact of different sources of growth. We classifies Korean biotechnology industry into 6 sectors, based on the survey of domestic biotechnology industry by Bioindustry Association of Korea. Empirical results indicate that each sector of bioindustry has various sources of growth and industrial demand has led the growth in all sectors except for food-bio and agriculture-bio. For the growth of the industry, each sector needs to cope with the change of the private demand and to improve the import and export structure.

• YAKHAK HOEJI
• /
• v.34 no.6
• /
• pp.415-421
• /
• 1990

The effects of temperature, pH, light and concentration on the degradation of trimebutine maleate in aqueous solution were investigated on the basis of accelerated stability analysis, and the stabilization of the solution was attempted by addition of several additives. The decomposition of trimebutine maleate in solution followed first-order reaction the was not only accelerated by temperature elevation but also the lower the concentratin the more speeded up the reaction. The decomposition mechanism of trimebtine could be confirmed by hydrolysis of ester bond in the structure. It was assumed trimebutine maleate is so photosensitive that the solution of the drug underwent accelerated decomposition under UV rays. What is more, the degradation of trimebutine solution was supposed to catalyzed by specific acid-base catalysis considered the pH dependence for the hydrolysis of ester, and the solution was most stable over the range of pH 2-2.8 in solution. The additives, citric acid, asparitc acid and glutamic acid, inhibited considerably the decomposition of the drug solution, and these additives might be used as stabilizers in trimebutine maleate solution.

• Applied Chemistry for Engineering
• /
• v.26 no.2
• /
• pp.145-153
• /
• 2015

$Cr_2O_3/AP$ (ammonium perchlorate) energetic composites were prepared by a method of solvent/anti-solvent. XRD analysis revealed that the crystalline structure of AP in $Cr_2O_3/AP$ composites is the same as that of pure AP. SEM photomicrograph shows that an average size of cuboid $Cr_2O_3/AP$ composites is approximately $2.5{\mu}m$. TGA analysis shows that the addition of submicron $Cr_2O_3$ particles into AP lowers the HTD (high-temperature decomposition) compared to that of neat AP and the activation energy of the $Cr_2O_3/AP$ composites was calculated by the isoconversional Starlink method. Considering changes in the activation energy, the decomposition reaction mechanism of AP was suggested as follows; the decomposition with the formation of nucleation sites renders formation of porous structure in the composites up to conversion of about 0.25 and after further conversion of over 0.3, it seems that decomposition reaction vigorously takes place rather than sublimation of AP.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2011.11a
• /
• pp.31-37
• /
• 2011

Detail flow structure in a large solid rocket motor with two inhibitors has been investigated using 3D Large Eddy Simulation and Proper Orthogonal Decomposition(POD) analysis. Vortex shedding frequencies periodically occurred by inhibitors are coupled with flow acoustics induced by the impinging of vorticity on nozzle head. As a result of 3D analysis, it was observed that the nozzle exit flow causes roll-torques from the vortex being decomposed in unbalanced shape for the impinging of vorticity on the nozzle head.

• The Korean Journal of Applied Statistics
• /
• v.35 no.6
• /
• pp.703-724
• /
• 2022

Although longitudinal studies mainly produce multivariate longitudinal data, most of existing statistical models analyze univariate longitudinal data and there is a limitation to explain complex correlations properly. Therefore, this paper describes various methods of modeling the covariance matrix to explain the complex correlations. Among them, modified Cholesky decomposition, modified Cholesky block decomposition, and hypersphere decomposition are reviewed. In this paper, we review these methods and analyze Korean children and youth panel (KCYP) data are analyzed using the Bayesian method. The KCYP data are multivariate longitudinal data that have response variables: School adaptation, academic achievement, and dependence on mobile phones. Assuming that the correlation structure and the innovation standard deviation structure are different, several models are compared. For the most suitable model, all explanatory variables are significant for school adaptation, and academic achievement and only household income appears as insignificant variables when cell phone dependence is a response variable.

• Advances in nano research
• /
• v.11 no.6
• /
• pp.641-648
• /
• 2021

In this article, the dynamic parameters (frequencies, mode shapes, damping ratios) of the scaled concrete structure and the dynamic parameters (frequencies, mode shapes, damping ratios) of the entire outer surface of titanium dioxide, 80 micron in thickness are compared using operational modal analysis method. Ambient excitation was provided from micro tremor ambient vibration data on ground level. Enhanced Frequency Domain Decomposition (EFDD) was used for the output only modal identification. From this study, a good correlation between mode shapes was found. Titanium dioxide applied to the entire outer surface of the scaled concrete structure has an average of 11.78% difference in frequency values and 10.15% in damping ratios, proving that nanomaterials can be used to increase rigidity in structures, in other words, for reinforcement. Another important result determined in the study was the observation of the adherence of titanium dioxide and similar nanomaterials mentioned in the introduction to concrete structure surfaces was at the highest level.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2007.05a
• /
• pp.1090-1095
• /
• 2007

A study was carried out to investigate the fluid-structure interaction phenomena of buried hydrophone system that exposed complex loads due to handling, transportation and installation. The buried hydrophone system has necessarily neighborhood structures for installation. Because of the neighborhood structure, acoustic field is deformed. We analyze the piezoelectric-structural-acoustic coupled problem and the results to use a finite element analysis software, ANSYS, which has an coupled field analysis capability. The effect of the component of hydrophone system is revealed altogether in pressure distribution. So, we classify and analyze the problem by four different compositions for decomposition.