• Bulletin of the Korean Chemical Society
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• v.33 no.1
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• pp.60-64
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• 2012

Silver(I) [bis(alkylthio)methylene]malonates were synthesized from the reaction of silver nitrate and potassium [bis(alkylthio)methylene]malonates. The structures of the Ag complexes were characterized with nuclear magnetic resonance (NMR), inductively coupled plasma atomic emission spectrometry (ICP-AES) and elemental analysis. Ag nanoparticles (NPs) were obtained from the decomposition of the Ag complexes in 1,2-dichlorobenzene at $110^{\circ}C$ without an additional surfactant. The average sizes of the Ag NPs are in the range of 5.1-6.3 nm and could be controlled by varying the length of the alkyl chain. The optical properties, crystalline structure and surface composition of Ag NPs were characterized with ultraviolet-visible (UV-visible) spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), gas chromatography-mass spectrometry (GC-MS), X-ray Photoelectron Spectroscopy (XPS) and thermal gravimetric analysis (TGA).

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.1
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• pp.21-28
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• 2011

Fe, Ni and Co, typical active components, were dispersed on $Al_2O_3$ and $TiO_2$ for $SO_3$ decomposition. $SO_3$ decomposition was conducted at the temperature ranges from $750^{\circ}C$ to $950^{\circ}C$ using the prepared catalysts. Alumina based catalysts showed the surface areas higher than Titania based catalysts, which resulted from spinel structure formation of alumina based catalysts. Catalytic $SO_3$ decomposition reaction rates were in the order of Fe>Co${\gg}$Ni. The metal sulfate decomposition temperature were in the order of Ni>Co>Fe from TGA/DTA analysis of metal sulfate. During $SO_3$ decomposition, metal sulfate can form on the catalysts. $SO_2$ and $O_2$ can be produced from the decomposition of metal sulfate. In that point of view, the less is the metal sulfate deomposition temperature, the higher can be the $SO_3$ decomposition activity of the metal component. Therefore, it can be concluded that metal component with the low metal sulfate decomposition temperature is the pre-requisite condition of the catalysts for $SO_3$ decomposition reaction.

• Journal of the Korean Society of Combustion
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• v.6 no.2
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• pp.29-35
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• 2001

Unsteady numerical study has been conducted on combustion dynamics of a lean-premixed swirl-stabilized gas turbine swirl injector. A three-dimensional computation method utilizing the message passing interface (MPI) parallel architecture, large eddy simulation(LES), and proper orthogonal decomposition (POD) technique was applied. The unsteady turbulent flame dynamics are simulated so that the turbulent flame structure can be characterized in detail. It was observed that some fuel lumps escape from the primary combustion zone, and move downstream and consequently produce hot spots. Those flame dynamics coincides with experimental data. In addition, basis modes of the unsteady turbulent flame are characterized using proper orthogonal decomposition (POD) analysis. The flame structure based on odd basis modes is apparently larger than that of even ones. The flame structure can be extracted from the summation of the basis modes and eigenvectors at any moment.

• Nuclear Engineering and Technology
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• v.46 no.5
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• pp.655-666
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• 2014

The CUPID code has been developed at KAERI for a transient, three-dimensional analysis of a two-phase flow in light water nuclear reactor components. It can provide both a component-scale and a CFD-scale simulation by using a porous media or an open media model for a two-phase flow. In this paper, recent advances in the CUPID code are presented in three sections. First, the domain decomposition parallel method implemented in the CUPID code is described with the parallel efficiency test for multiple processors. Then, the coupling of CUPID-MARS via heat structure is introduced, where CUPID has been coupled with a system-scale thermal-hydraulics code, MARS, through the heat structure. The coupled code has been applied to a multi-scale thermal-hydraulic analysis of a pool mixing test. Finally, CUPID-SG is developed for analyzing two-phase flows in PWR steam generators. Physical models and validation results of CUPID-SG are discussed.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.2
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• pp.30-37
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• 2014

In this study, we studied how to perform the structural analysis which need a large-capacity flash memory with the computer program when the flash memory storage of a personal computer has no enough room for the analysis of structure. As one of the solutions of this problem, the blocking method of stiffness matrix, which is a method that stiffness matrix is divided by a few blocks and each block is sequentially used for the calculation of matrix decomposition, is proposed and an algorithm available in computer program is derived on the method. Finally, A structural analysis program (sNs) based on this study is developed and the correctness and efficiency of the algorithm is founded through some examples which are fundamental in structural analysis.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.24 no.4
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• pp.365-373
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• 2011

Damage of reinforced concrete panel subjected to blast load using parallel and domain decomposition is analyzed. The numerical results are sensitive to the mesh size because blast waves are generated during the extremely short term. In order to investigate the effect of mesh size on the blast wave, the analysis results from various wave mesh size using AUTODYN, the explicit finite element analysis program, were compared with existing experimental results. The smaller mesh size was, the higher accuracy was. However, in this case, the analysis was inefficient. Therefore, in order to increase numerical efficiency, the parallel analysis using decomposed method based on Euler and Lagrangian description was performed. Finally, the decomposed method using both the structure domain based on Lagrange description and the blast wave domain based on Euler description was more efficient than the decomposed method using only the Lagrange mesh on structure domain.

• Smart Structures and Systems
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• v.25 no.2
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• pp.123-133
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• 2020

Compressive sensing (CS) is a newly developed data acquisition and processing technique that takes advantage of the sparse structure in signals. Normally signals in their primitive space or format are reconstructed from their compressed measurements for further treatments, such as modal analysis for vibration data. This approach causes problems such as leakage, loss of fidelity, etc., and the computation of reconstruction itself is costly as well. Therefore, it is appealing to directly work on the compressed data without prior reconstruction of the original data. In this paper, a direct approach for modal analysis of damped systems is proposed by decomposing the compressed measurements with an appropriate dictionary. The damped free vibration function is adopted to form atoms in the dictionary for the following sparse decomposition. Compared with the normally used Fourier bases, the damped free vibration function spans a space with both the frequency and damping as the control variables. In order to efficiently search the enormous two-dimension dictionary with frequency and damping as variables, a two-step strategy is implemented combined with the Orthogonal Matching Pursuit (OMP) to determine the optimal atom in the dictionary, which greatly reduces the computation of the sparse decomposition. The performance of the proposed method is demonstrated by a numerical and an experimental example, and advantages of the method are revealed by comparison with another such kind method using POD technique.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.5
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• pp.883-890
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• 2001

In practical design studies, most of designers solve multidisciplinary problems with large size and complex design system. These multidisciplinary problems have hundreds of analysis and thousands of variables. The sequence of process to solve these problems affects the speed of total design cycle. Thus it is very important for designer to reorder the original design processes to minimize total computational cost. This is accomplished by decomposing large multidisciplinary problem into several multidisciplinary analysis subsystem (MDASS) and processing it in parallel. This paper proposes new strategy for parallel decomposition of multidisciplinary problem to raise design efficiency by using genetic algorithm and shows the relationship between decomposition and multidisciplinary design optimization (MDO) methodology.

• Proceedings of the KWS Conference
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• 2003.11a
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• pp.156-158
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• 2003

An implicit finite element implementation for Leblond's transformation plasticity constitutive equations, which are widely used in welded steel structure is proposed in the framework of parallel computing. The implementation is based upon the multiplicative decomposition of deformation gradient and hyper elastic formulation. We examine the efficiency of parallel computation for the finite element analysis of a welded structure using domain-wise multi-frontal solver.

• Journal of the Korean Society of Safety
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• v.14 no.1
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• pp.101-107
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• 1999

$TiO_2$ and $xTiO_2-ySiO_2$ system photocatalysts were developed by sol-gel method based on the change of production parameters, and their structure of crystallization and the specific surface area was measured. Considering the efficiency of the ethanol decomposition using the catalyst, the conclusion was made as follows: 1) By means of X-ray analysis of $TiO_2$ powder that is obtained from water and Titanium alkoxide with various molar ratios, it is shown that structure of crystallization is a dominating structure and, on the other hand, the crystallization of rutile also partly exists. The specific surface area is at its maximum value at R=6, which is the molar ratio of water vs. alkoxide, whereas its value goes down as the molar ratio increases. In the reaction of using $TiO_2$ catalyst, the ethanol is decomposed into the extent of 15 ~30% in an hour and three hours are necessitated for 70% decomposition. 2) $TiO_2/SiO_2$ powder is developed from Titanium and Silicon alkoxide by a hetero-condensation process. The increase of SiO$_2$ contents causes the decrease of the degree of crystallization of the gel, whereas the specific surface area preferentially increases. In the decomposition reaction of the ethanol, the decomposition efficiency represents 25~60% in an hour. It is, however, examined that the efficiency inactively increases corresponding to the duration of reaction time. It is shown that more than 90% of ethanol is decomposed when reaction time is about three hours and the efficiency illustrates the maximum value for 60-$TiO_2/4O-SiO_2$ catalyst.