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http://dx.doi.org/10.5012/bkcs.2012.33.1.60

Synthesis of Silver Nanoparticles from the Decomposition of Silver(I) [bis(alkylthio)methylene]malonate Complexes  

Lee, Euy-Jin (Department of Chemistry and GETRC, Kongju National University)
Piao, Longhai (Department of Chemistry and GETRC, Kongju National University)
Kim, Jin-Kwon (Department of Chemistry and GETRC, Kongju National University)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.1, 2012 , pp. 60-64 More about this Journal
Abstract
Silver(I) [bis(alkylthio)methylene]malonates were synthesized from the reaction of silver nitrate and potassium [bis(alkylthio)methylene]malonates. The structures of the Ag complexes were characterized with nuclear magnetic resonance (NMR), inductively coupled plasma atomic emission spectrometry (ICP-AES) and elemental analysis. Ag nanoparticles (NPs) were obtained from the decomposition of the Ag complexes in 1,2-dichlorobenzene at $110^{\circ}C$ without an additional surfactant. The average sizes of the Ag NPs are in the range of 5.1-6.3 nm and could be controlled by varying the length of the alkyl chain. The optical properties, crystalline structure and surface composition of Ag NPs were characterized with ultraviolet-visible (UV-visible) spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), gas chromatography-mass spectrometry (GC-MS), X-ray Photoelectron Spectroscopy (XPS) and thermal gravimetric analysis (TGA).
Keywords
Silver; Dicarboxylate complexes; Nanoparticles; Thermal decomposition;
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