• 한국광물학회지
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• 제9권1호
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• pp.7-16
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• 1996

Partially sericitized tourmaline from a pegmatite, Black Hills, South Dakota, U.S.A., was investigated using high-resolution transmission electron microscopy (HRTEM). Muscovite occurs as the only alteration product of tourmaline, and it is developed extensively as narrow veinlets along the {110} and {100} cleavage directions of tourmaline, indicating that a cleavage-controlled alteration mechanism was dominant. Muscovite was characterized mainly as two-layer polytypes with minor stacking disorder, but tourmaline is almost free of structural defects. HRTEM images of tourmaline-muscovite interfaces revealed that the interfaces between two minerals are composed of well-defined {110} and {100} boundaries of tourmaline. The (001) of muscovite is in general parallel to the c-axis of tourmaline, but tourmaline and replacing muscovite do not show specific crystallographic orientation relationship; muscovite consists of numerous 100-1000$\AA$ thick subparallel packets, and the angles between the (001) of muscovite and (110) of tourmaline is highly variable. Al/Si ratios of both minerals suggest that tourmaline to muscovite alteration by late magnetic fluids has been facilitated by their similar Al/Si ratio in the incipient alteration stage, in that the hydration reaction with preservation of Al and Si would require only addition of K+ and H2O. Aluminous minerals other than muscovite were not characterized as the alteration products of tourmaline, indicating that tourmaline reacted directly to muscovite; the tourmaline alteration apparently occurred by the presence of residual fluids in which K+ is available and silica was not undersaturated.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2359-2362
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• 2007

MALDI-TOF-MS technique was applied to obtain structural and compositional information of synthetic polyamides, Nylon6 and Nylon66. Mass spectra of both the original and the hydrolyzed polyamide samples were analyzed using the self calibration method as well as the internal calibration method with the standard materials of known masses. The MALDI-TOF mass spectra of Nylon6 samples showed the presence of protonated, sodiated, and potassiated ions that were assigned to cyclic and NH2/COOH terminated linear oligomers. From the MALDI-TOF mass spectra of Nylon66 samples, the potassiated linear oligomers with three different end groups are identified as well as the cyclic oligomers, i.e., NH2/COOH terminated oligomers, NH2/NH2 terminated oligomers, and COOH/COOH terminated oligomers. Full characterization of the molecular species and end groups present in the polyamide samples has been achieved, and also the changes in mass spectral patterns after the hydrolysis of the samples are presented.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1995년도 가을 학술발표회 논문집
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• pp.246-251
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• 1995

To reduce the size of structural members high strength concrete has recently been utilized for structrue such as ultra-high-rise buildings and prestressed concrete bridges in North America. and its compressive strength has gone up to 1300kgf/$\textrm{cm}^2$. In Japan, research on high-strength concrete has been undertaken on a large scale by the national enterprise so-called New RC Project, and this project purposed to develop the design compressive sstength of 1200kgf/$\textrm{cm}^2$. Considering these circumstance. the aim of this aim of this experimental study is to develop ultra-high-strength concrete with compressive stength over 2300kgf/$\textrm{cm}^2$ with domestic current materials. There are so many factors which influence on manufacturing of ultrahigh-strength concrete. The experimental factors selected in this study are mixing methods, curing methods, water-binder ratio, maximum size of coarse aggregate, and the replacement proportion of cement by silica fume. The results of this expermental study show that it is possible to develop the ultra-high-strength concrete with compressive strength over 2300kgf/$\textrm{cm}^2$.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1995년도 가을 학술발표회 논문집
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• pp.252-255
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• 1995

To reduce the size of structural members, high strength concrete has recently been utilized for structure such as ultra-high-rise buildings and prestressed concrete bridges in North America. And its compressive strength has gone up to 1300kgf/$\textrm{cm}^2$. In Japan. research on high-strength concrete has been undertaken on a large scale by the national enterprise so-called New RC Project, and this Project purposed to develop the design compressive strength of 1200kgf/$\textrm{cm}^2$. Considering these circumstance. the aim of this experimental study is to develop ultra-high-strength concrete with compressive strenght over 2300kgf/$\textrm{cm}^2$ with domestic current materials. There are so many factors which influence the manufacturing of ultra-high-strength concrete. The experimental factors selected in this study are mixing methods. curing methods. water-binder ratio, maximum size of coarse aggregate, and the replacement proportion of cement by silica fume. The results of this expermental study show that it is possible to develop the ultra-high-stength concrete with compressive strength over 2300kgf/$\textrm{cm}^2$.

• 콘크리트학회지
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• 제9권1호
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• pp.165-172
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• 1997

경량기포콘크리트란 시멘트슬러리 속에 미리 생성된 기포를 혼합시켜 양생시킴으로써 동일한 체적의 보통콘크리트보다 가볍게 만든 콘크리트를 의미한다. 본 연구의 목적은 고분자기포제를 이용하여 초경량성과 타설에 충분한 유동성을 확보하면서 소요강도를 갖는 최적의 선기포방식의 경량기포콘크리트를 개발하는데 있다. 연구결과 실리카흄, 플라이애쉬 등의 혼화재와 산업부산물인 발포포리스티렌비드의 혼합으로 경량기포콘크리트의 역학적 특성을 개선시켜 기존의 선기포방식으로 제조된 경량기포콘크리트보다 유동성 , 경량성과 강도특성이 우수한 경량기포콘크리트를 개발하였다. 본 논문에서는 개발된 경량기포콘크리트의 여러 가지 배합인자에 따른 유동성 및 압축강도를 규명하였으며 최적 배합비를 도출하였다.

• Transactions on Electrical and Electronic Materials
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• 제12권3호
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• pp.119-122
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• 2011

A series of mesoporous silicalites was synthesized using different compositions of tetraethylorthosilicate and methyltriethoxysilane (MTES) as the silica source. Cetyltrimethylammonium bromide was used as the organic template. Their detailed pore structures were investigated by transmission electron microscopy, X-ray diffraction, and N2 adsorption method. The thermal properties of these silicalites were studied by thermogravimetric analysis. The increased amount of MTES destroyed mesoporous channels and reduced pore sizes from 3.4 nm to 2.8 nm in calcined silicalites. The calcined silicalite transformed completely into an amorphous state at 30% MTES loading. Methyl pending groups of MTES hindered the structural ordering of ≡Si-O- frameworks, resulting in an amorphous structure. This was caused by the insufficient formation of supramolecular assembly with the organic template. No capillary condensation step was found in MS 7/3 silicalite. The other capillary condensation steps shifted toward the lower relative pressure with increasing MTES content, indicating the reduction of pore sizes.

• Advances in concrete construction
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• 제9권4호
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• pp.345-354
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• 2020

Cement is the most significant component in concrete. Large scale manufacturing of cement consumes more energy and release harmful products (Carbon dioxide) into the atmosphere that adversely affect the environment and depletes the natural resources. A lot of research is going on in globally concentrating on the recycling and reuse of waste materials from many industries. A major share of research is focused on finding cementitious materials alternatives to ordinary Portland cement. Many industrial waste by-products such as quartz powder, metakaolin, ground granulated blast furnace slag, silica fume, and fly ash etc. are under investigations for replacement of cement in concrete to minimize greenhouse gases and improve the sustainable construction. In current research, the effects of a new generation, ultra-fine material i.e., alccofine which is obtained from ground granulated blast furnace slag are studied as partial replacement by 25% and with varying amounts of sulfonated naphthalene formaldehyde (i.e., 0.3%, 0.35% and 0.40%) on mechanical, water absorption, thermal and microstructural properties of concrete. The results showed moderate improvement in all concrete properties. Addition of SNF with combination of alccofine showed a significant enhancement in fresh, hardened properties and water absorption test as well as thermal and microstructural properties of concrete.

• 한국정밀공학회지
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• 제23권5호
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• pp.190-196
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• 2006

Transparent materials are widely used in the fields of optic parts and bio industry. We have experiment to find out the characteristics of the micromachining inside transparent materials using femtosecond laser pulses. With its non-linear effects by very high peak intensity, filament (plasma channel) was formed by the cause of the self-focusing and the self-defocusing. Physical damage could be found when the intensity is high enough to give rise to the thermal stress or evaporation. At the vicinity of the power which makes the visible damage or modification, the structural modification occurs with the slow scanning speed. According to the polarization direction to the scanning direction, the filament quality is quite different. There is a good quality when the polarization direction is parallel to the scanning direction. For fine filament, we could suggest the conditions of the high numerical aperture lens, the short shift of focusing point, the low scanning speed and the low power below 20 mW. As the examples of optics parts, we fabricated the fresnel zone plate with the $225{\mu}m$ diameter and Y-bend optical wave guide with the $5{\mu}m$ width.

• 한국세라믹학회지
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• 제41권7호
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• pp.503-507
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• 2004

The importance of porous ceramics has been increasingly recognized and adequate strength of porous ceramics is now required for structural applications. Porosities of porous ceramics act as flaws in inner volume and outer surface which result in severe strength degradation. The effect of pore structure, however, on strength and reliability of porous ceramics has not been clearly understood. We investigate the relationship between pore structure and mechanical properties using a sphere indentation on bilayer structure, porous ceramic top layer with soft polymer substrate. Porous alumina and silica were prepared to characterize the isolated pore structure and interconnected pore structure, respectively. The porous ceramic with 1mm thickness were bonded to soft polycarbonate substrate and then fracture strengths were estimated from critical loads for radial cracking of porous ceramics during sphere indentation from top surface. This simple and reproducible technique provides Weibull modulus of strength of porous ceramics with different pore structure. It shows that the porous ceramics with isolated pore structure have higher strength and higher Weibull modulus as well, than those with interconnected pore structure even with the same porosity.

• Bulletin of the Korean Chemical Society
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• 제29권3호
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• pp.609-614
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• 2008

A periodic mesoporous organosilica material was synthesized by microwave heating (PMO-M) using 1,2-bis(trimethoxysilyl)ethane as a precursor in a cationic surfactant solution, and textural properties were compared with those of the product produced by conventional convection heating (PMO-C). These synthesized materials were characterized using XRD, TEM/SEM, N2 adsorption isotherm, 29Si and 13C NMR, and TGA, which confirmed their good structural orders and clear arrangements of uniform 3D-channels. Synthesis time was reduced from 21 h in PMO-C to 2-4 h in PMO-M. PMO-M was made of spherical particles of 1.5-2.2 m m size, whereas PMO-C was made of decaoctahedron-shaped particles of ca. 8.0 m m size. Effect of synthesis temperature, time, and heating mode on the PMO particle morphology was examined. The particle size of PMO-M could be controlled by changing the heating rate by adjusting microwave power level. PMO-M demonstrated improved separation of selected organic compounds compared to PMO-C in a reversed phase HPLC experiment. Ti-grafted PMO-M also resulted in higher conversion in liquid phase cyclohexene epoxidation than by Ti-PMO-C.