• Title/Summary/Keyword: structural silica

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Evaluation of Corrosion Resistance with Grout Type and Tendon (그라우트 품질을 고려한 텐던의 부식저항성 평가)

  • Ryu, Hwa-Sung;An, Ki-Hong;Koh, Kyung-Taek;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.4
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    • pp.76-82
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    • 2018
  • Grout in duct is very effective protection from tendon corrosion in PSC(Prestressed Concrete) structure. In the work, durability and mechanical tests are performed for two types of grout which are conventionally used one and the improved grout with reduced w/c (water to cement) ratio and silica fume. Tendon system with 1000mm height is prepared and various tests including strength, flow, absorption, and bleeding ratio are conducted. ICM(Impressed Current Method) is adopted for corrosion acceleration in tendon with 12.7mm diameter inside grout. For 2 and 4 days, corrosion acceleration is performed for 2 different type of grout and corrosion amount is investigated. The improved grout shows higher compressive strength by 10 MPa and lower absorption ratio by 50% than the conventional one. It also provides an excellent corrosion reduction to 39.8 %~48.2 % for 2~4 days of acceleration period.

An Experimental Study on Developing Ultra-High Strength Powder Concrete Using Low-heat Portland Cement (저열 포틀랜드 시멘트를 사용한 초고강도 분체 콘크리트 개발에 관한 실험적 연구)

  • Jo, Byung-Wan;Yoon, Kwang-Won;Kim, Heoun;Park, Jin-Mo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.6 s.58
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    • pp.135-147
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    • 2009
  • In order to develop the ultra high strength concrete over 400Mpa at 28 day, Low-heat portland cement, ferro-silicon, silica-fume and steel fiber were mixed and tested under the special autoclave curing conditions. Considering the influence of Ultra high strength concrete. normal concrete is used as a comparison with low water-cement ratio possible Low-heat portland cement. Additionally, as a substitution of aggregates, we analyzed the compressive strength of Ferro Silicon by making the states of mixed and curing conditions differently. In addition, SEM films testified the development of C-S-H hydrates of Type III & Type IV, and tobermolite, zonolite due to the high temperature, high pressure of autoclave curing. Fineness of aggregate, filler and reactive materials in concrete caused 420Mpa compressive strength at 28day successfully.

Performance Evaluation of Admixture for Durability Improvement of Shielding Materials Used Waste Glass as Fine Aggregate (폐유리를 잔골재로 사용한 차폐채움재의 내구성 개선을 위한 혼화재료의 성능평가)

  • Hwang, Byoung-Il;Kim, Hyo-Jung;Song, Yong-Soon;Yi, Seong-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.2
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    • pp.20-27
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    • 2019
  • Compared to the development and manufacturing technology of electronic goods, the development of waste glass recycling technology is relatively insufficient, leading to the acceleration of waste of resources and environmental pollution. Although waste glass recycling technology is being actively developed overseas, waste glass recycling technology is insufficient in Korea, leading to the illegal dumping or burial of waste glass. Waste glass has been confirmed to have pozzolan reaction potential when having hydration reaction with cement. Waste glass is also reported to be effective in reducing bleeding and inhibiting the development of hydration heat by improving the physical properties of concrete and the rheology properties of fresh concrete. Therefore, this paper analyzed the strength characteristics and the effect of alkalic-silica reaction on the expansion of shielding concrete that used waste glass as fine aggregate. Where, suitable admixture materials were used as a measure to suppress the expansion.

Compositions of fatty acids and structural identification in human breast milk (모유 중 지방산 조성 및 구조 분석)

  • Ji-Woo, Yoo;Young-Soo, Keum;Nam Mi, Kang
    • Analytical Science and Technology
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    • v.35 no.6
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    • pp.229-236
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    • 2022
  • Lipidomic analyses of transient breast milk are far more limited than those of other dairy products. As a preliminary analysis of breast milk lipidomes, analytical methods for polar and nonpolar lipids from transient breast milk were developed, and detailed fatty acid profiles were determined in this study. The newly developed methods include solvent fractionation of phospholipids and acyl glycerol, one-pot derivatization to FAMEs and pyridylcarbinol esters, and instrumental analysis, including GC-FID and GC-MS. The results indicate that breast milk contains 16 major common fatty acids with 8-22 carbons. Additionally, 29 minor fatty acids were identified, including odd-numbered fatty acids and branched analogues with 11-23 carbons. Their detailed concentrations in different fractions were measured using the internal standard method. In addition to ordinary fatty acids, breast milk contains several branched fatty acids, including iso/anteiso acids with 15-18 carbons. Structural studies have been performed on selected minor fatty acids via chemical synthesis.

The Experimental Study of Full-scale Centrifugal Formed High Strength Concrete Prismatic Beam(CFPB) Composited with Deck Slab (상부 슬래브와 합성된 원심성형으로 제작된 초고강도 각형보의 실험연구 )

  • Doo-Sung Lee;Sung-Jin Kim;Jeong-Hoi Kim
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.1
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    • pp.19-29
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    • 2023
  • An ultra-high strength prestressed prismatic beam of 100 MPa in compressive strength was developed by increasing the watertightness of concrete by utilizing centrifugal molding processes without adding expensive admixtures such as silica fume. The ultra-high strength centrifugal shaped square beam installed on the wall is composited with the upper slab concrete and then subjected to a service load. Horizontal shear stress is generated by bending between the centrifugal molding beam and the floor plate, which causes the beam and floor plate to perform composite behavior through shear connections such as studs and rebars. In this study, a flexural load test was performed on a mock-up specimen that was synthesized by fabricating an RC slab on top of a 100 MPa-class centrifugal shaped beam produced at the factory. proven reliability.

Stress-strain behavior and toughness of high-performance steel fiber reinforced concrete in compression

  • Ramadoss, P.;Nagamani, K.
    • Computers and Concrete
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    • v.11 no.2
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    • pp.149-167
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    • 2013
  • The complete stress-strain behavior of steel fiber reinforced concrete in compression is needed for the analysis and design of structures. An experimental investigation was carried out to generate the complete stress-strain curve of high-performance steel fiber reinforced concrete (HPSFRC) with a strength range of 52-80 MPa. The variation in concrete strength was achieved by varying the water-to-cementitious materials ratio of 0.40-0.25 and steel fiber content (Vf = 0.5, 1.0 and 1.5% with l/d = 80 and 55) in terms of fiber reinforcing parameter, at 10% silica fume replacement. The effects of these parameters on the shape of stress-strain curves are presented. Based on the test data, a simple model is proposed to generate the complete stress-strain relationship for HPSFRC. The proposed model has been found to give good correlation with the stress-strain curves generated experimentally. Inclusion of fibers into HPC improved the ductility considerably. Equations to quantify the effect of fibers on compressive strength, strain at peak stress and toughness of concrete in terms of fiber reinforcing index are also proposed, which predicted the test data quite accurately. Compressive strength prediction model was validated with the strength data of earlier researchers with an absolute variation of 2.1%.

Structural Analysis and Biological Activities of Sesquiterpene Lactones Isolated from the Leaves and Stems of Chrysanthemum boreale Makino (산국의 잎과 줄기에서 분리한 Sesquiterpene Lactone들의 구조규명 및 생리활성)

  • Lee, Jong Rok;Park, Moon Ki
    • Journal of Environmental Science International
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    • v.26 no.11
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    • pp.1285-1295
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    • 2017
  • Chrysanthemum boreale Makino is widely distributed in Korea, China, Japan and Southeast Asian countries. C. boreale is one of the herbs used for treating various inflammatory diseases in oriental medicine. The present study was conducted to identify biologically active compounds from the leaves and stems of C. boreale. We isolated two sesquiterpene sactones from the leaves and stems of C. boreale using silica gel column chromatography and recyclic high perfomance liquid chromatography. The lactones were characterized by their spectroscopic data (NMR, IR, MASS). These compounds were subjected to Farnesyl Protein Transferase (FPTase) inhibition, Nitric Oxide (NO) release inhibition and apoptosis inhibition. The structur of the following isolated compound were elucidated 8,10-${\small{O}$-Acetyl-2-methoxy-10-hydroxy-3,11(13)-guaiadiene-12,6-olide and 4,10-dihydroxy-8-${\small{O}$-Acetyl-2,11(13)-guaiadiene-12,6-olide. In the NO release inhibition assay, compound 2 showed strong activities, with an $IC_{50}$ value of $7{\mu}g/mL$, whereas compound 1 did not exhibit significant activity with an $IC_{50}$ value of over $14{\mu}g/mL$ against murine macrophage.

X-ray diffraction analysis on sapphire wafers with surface treatments in chemical-mechanical polishing process (사파이어 웨이퍼 연마공정에서의 표면처리효과에 대한 X-선 회절분석)

  • 김근주;고재천
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.5
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    • pp.218-223
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    • 2001
  • The chemical-mechanical polishing process was carried out for 2"-dia. sapphire wafer grown by horizontalBridgman method on the urethane lapping pad with the silica sol. The polished wafer shows the full-width at halfmaximum of 200~400 arcsec in double-crystal X-ray diffraction, indicating that the slicing, grinding and lapping processes before the polishing process affected the crystalline structural property of the wafer surface by the mechanical residual stress. For the inclusion of surface treatments after chemical-mechanical polishing such as the thermal annealing at the temperature of $1,200^{\circ}C$for 4 hrs. and chemical etching, the crystalline quality was sigdicantly enhanced with the reduced full-width at half maximum up to 8.3 arcsec.arcsec.

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A Study of the Basic Properties of Lightweight Aggregate Concrete for Offshore Structures Application (해양구조물 적용을 위한 경량골재콘크리트의 기초물성에 관한 연구)

  • Kim, Myung-Sik;Jang, Hee-Suk;Kim, Chung-Ho;Baek, Dong-Il
    • Journal of Ocean Engineering and Technology
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    • v.25 no.1
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    • pp.73-79
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    • 2011
  • The various properties of concrete have been required, as civil engineering structures are getting larger and complicated. Therefore, the high performance of concrete, such as high strength, high fluidity, and low hydration heat, has been investigated largely. In this study, the properties of lightweight concrete-reducing self-weight of structure member have been studied in order to check the applicability of lightweight aggregate concrete to structural material. The experiments on compressive strength, splitting tensile strength, unit weight, and modulus of elasticity have been conducted with varying PLC, LWCI, LWCII, LWCII-SF5, LWCII-SF15 to check the basic properties. The compressive strength of 21MPa was obtained easily by using lightweight aggregate concrete and the addition of silica fume to increase the compressive strength slightly. To use lightweight aggregate concrete for civil engineering structures, systematic and rigorous studies are necessary.

Studies on the Presence of all $cis-{\Delta}^{5,11,14}-C_{20:3}$ Fatty Acid in the Seed Oils of Ginkgo (은행종실유의 all $cis-{\Delta}^{5,11,14}-C_{20:3}$ 지방산 존재에 관한 연구)

  • Kim, Seong-Jin;Lee, Kyeng-Hee;Kim, Yeon-Sim;Joh, Yong-Goe
    • Journal of the Korean Applied Science and Technology
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    • v.10 no.1
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    • pp.57-65
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    • 1993
  • The fatty acid, all $cis-{\Delta}^{5,11,14}-C_{20:3}$, in the Gingko nuts oils, was isolated and, purified by urea-adduct method, silver ion silica gel chromatography and HPLC equipped with reversed phase ${\mu}-Bondapak$ $C_{18}$ column. Its structural elucidation was conducted by IR and $^1H$-, $^{13}C$-NMR technique. The fatty acid composition of seed oils mainly consists of linoleic acid(37.73%), vaccenic acid(18.30%), oleic acid(15.18%), palmitic acid(3.37%), palmitoleic acid(3.37%) and ${\Delta}^5$ NMDB fatty acids(8.50%) in which all $cis-{\Delta}^{5,11,14}-C_{20:2}$ predominates.