• 한국균학회지
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• 제29권1호
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• pp.67-71
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• 2001

민간약재로 사용되어지는 아카시재목 버섯(Fomitella fraxinea) 자실체의 에탄올 추출물로부터 ethyl acetate 추출, silica gel chromatography, preparative TLC 등의 방법으로 항산화 활성을 나타내는 steroid계 화합물, F-1을 분리 정제하였다. EI-Mass, FT-IR, $^1H$ 및 $^{13}C$ NMR 등 기기 분석에 의하여 F-1은 분자량이 412.65, 분자식이 $C_{28}H_{44}O_2$의 steroid 화합물, ergosta-7,22-diene-3-one-$16{\beta}-ol$임을 확인하였다. F-1의 지질과산화 저해활성은 $10^{\mu}g/ml$의 농도에서 86%의 지질과산화 저해활성을 나타내었으며, $IC_{50}$ 값은 $3.8{\mu}g/ml$이었다. 이 화합물은 항산화제인 ${\alpha}-tocoperol$과 유사한 항산화 활성을 나타내었다.

• Structural Engineering and Mechanics
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• 제82권3호
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• pp.295-312
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• 2022

This study investigates the effects of nano silica (NS) and micro steel fiber on the properties of ultra-high-performance concrete (UHPC). The experimental consists of three groups, each one with five percentages of NS content (0%, 2%, 4%, 6% and 8%) in addition to the 20% silica fume and 20% quartz powder proportioned according to the weight of cement added to the mixtures. In addition, three percentages of micro steel fibers (0%, 1% and 2%) were considered. Different mixtures with varying percentages of NS and micro steel fibers were prepared to set the water-to-binder ratio, such as 0.16% and 1.8% superplasticizer proportioned according the weight of the binder materials. The fresh properties, mechanical properties and elevated temperatures of the mixtures were calculated. Then, the results from the microstructure analyses were compared with that of the reference mixtureand it was found that 6% replacement of cement with NS was optimum replacement level. When the NS content was increased from 0% to 6%, the air content and permeability of the mixture decreased by 35% and 39%, the compressive and tensile strength improved by 21% and 18% and the flexural strength and modulus of elasticity increased by 20% and 11.5%, respectively. However, the effect of micro steel fibres on the compressive strength was inconclusive. The overall results indicate that micro steel fibres have the potential to improve the tensile strength, flexure strength and modulus of elasticity of the UHPC. The use of 6% NS together with 1% micro-steel fiber increased the concrete strength and reduce the cost of concrete mix.

• 한국가스학회지
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• 제26권2호
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• pp.1-8
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• 2022

본 연구에서는 탄산염암 저류층에서 활용 가능한 GPTMS((3-Glycidoxypropyl)trimethoxysilane)-SiO₂ 나노유체를 제조하고 주입 효과를 분석하였다. 표면개질에 따른 나노입자의 구조적 변화를 확인하기 위해 푸리에변환적외선분광(Fourier transform infrared spectroscopy, FTIR) 분석을 수행했으며, 0.5 mmol/g 이상의 GPTMS 농도에서 실리카 입자의 표면개질을 의미하는 2,950 cm^-1의 C-H 신축 진동(C-H stretching vibration)을 확인하였다. 또한, 친유성 상태로 에이징된 석회석과 백운석을 대상으로 나노입자의 농도와 주입률에 따른 GPTMS-SiO₂ 나노유체의 코어유동 실험을 수행하였다. 나노유체 주입에 따라 최대 18.9%의 오일이 추가로 회수되었으며, 암석의 접촉각과 투과도 변화를 확인할 수 있었다. 이는 나노입자가 탄산염암 표면에 흡착됨에 따라 습윤도를 개선함과 동시에 공극에 영향을 준다는 것을 의미한다. 따라서, 제조된 나노유체는 탄산염암 저류층을 대상으로 한 석유회수증진의 주입유체로 사용될 수 있으며 습윤도, 투과도 변화와 같은 유체 유동물성 개선에 활용될 것으로 기대된다.

• Structural Engineering and Mechanics
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• 제84권5호
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• pp.685-697
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• 2022

Nanotechnology has become one of the interesting technique used in material science and engineering. However, it is low used in civil engineering structures. The purpose of the present study is to investigate the static behavior of concrete plates reinforced with silica-nanoparticles. Due to agglomeration effect of silica-nanoparticles in concrete, Voigt's model is used for obtaining the equivalent nano-composite properties. Furthermore, the plate is simulated mathematically with higher order shear deformation theory. For a large use of this study, the concrete plate is assumed resting on a Pasternak elastic foundation, including a shear layer, and Winkler spring interconnected with a Kerr foundation. Using the principle of virtual work, the equilibrium equations are derived and by the mean of Hamilton's principle the energy equations are obtained. Finally, based on Navier's technique, closed-form solutions of simply supported plates have been obtained. Numerical results are presented considering the effect of different parameters such as volume percent of SiO₂ nanoparticles, mechanical loads, geometrical parameters, soil medium, on the static behavior of the plate. The most findings of this work indicate that the use of an optimum amount of SiO₂ nanoparticles on concretes increases better mechanical behavior. In addition, the elastic foundation has a significant impact on the bending of concrete slabs.

• Structural Engineering and Mechanics
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• 제88권2호
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• pp.141-157
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• 2023

In the present paper, the effect of recycled aggregates on the rheological and mechanical properties of self-consolidating concrete is investigated experimentally and numerically. Hence, the specimen with two types of recycled aggregates, i.e., known and unknown resistance origins, are utilized for the studied specimens. The experiments in this study are designed using the Box-Behnken method, which is one of the response surface methods. Input variables in mixtures include silica fume in the range of 5-15% as a percentage substitute for cement weight and recycled coarse and fine aggregates in the range of 0-50% for both series of recycled materials as a substitute for natural materials. The studied responses are slump flow, V funnel, compressive strength, tensile strength, and durability. The results indicate that the increase in the amount of recycled aggregates reduces the rheological and mechanical properties of the mixtures, while silica fume effectively improves the mechanical properties. In addition, the results demonstrate that the fine recycled aggregates affect the total response of the concrete significantly. The results of tensile and compressive strengths indicate that the mixtures including 50% recycled materials with known resistance origin demonstrate better responses up to 8 and 10% compared to the materials with unknown resistance origins, respectively. Recycled materials with a specific resistance origin also show better results than recycled materials with an unknown resistance origin. Durability test results represent those concretes containing recycled coarse aggregates have lower strength compared to recycled fine aggregates. Also, a series of mathematical relationships for all the responses are presented using variance analysis to predict mixtures' rheological and mechanical properties.

• Advances in nano research
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• 제16권3호
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• pp.217-229
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• 2024

This paper presents results of visual analysis of cracks formation and propagation of concretes made of quaternary binders (QBC). A composition of the two most commonly used mineral additives, i.e. fly ash (FA) and silica fume (SF) in combination with nanosilica (nS), has been proposed as a partial replacement of the cement. The principal objective of the present study is to achieve information about the effect of simultaneous incorporation of three pozzolans as partial replacement to the OPC on the fracture processes in concretes made from quaternary binders (QBC). The modern and precise non-contact measurement method (NCMM) via digital image correlation (DIC) technique was used, during the studies. In the course of experiments it was established that the substitution of OPC with three pozzolans including the nanoadditive in FA+SF+nS FA+SF+nS combination causes a clear change of brittleness and behavior during fractures in QBCs. It was found that the shape of cracks in unmodified concrete was quasi-linear. Substitution of the binder by SCMs resulted in a slight heterogeneity of the structure of the QBC, including only SF and nS, and clear heterogeneity for concretes with the FA additive. In addition, as content of FA rises throughout each of QBC series, material becomes more ductile and shows less brittle failure. It means that an increase in the FA content in the concrete mix causes a significant change in fracture process in this composite in comparison to concrete with the addition of silica modifiers only.

• 한국재료학회지
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• 제26권4호
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• pp.182-186
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• 2016

Zircon, having excellent thermal, chemical, and mechanical properties, is utilized in refractory materials, electronic materials, chemical machines, structural materials, etc. However, zircon generally shows thermal dissociation to zirconia($ZrO_2$) and silica($SiO_2$) around the sintering temperature of $1540^{\circ}C$, and when zircon particles are small and impurities are present, thermal dissociation is known to occur at around $1100^{\circ}C$. This reduces the mechanical properties of $ZrSiO_4$. In this research, the effect of adding $SiO_2$ and 3Y-TZP to $ZrSiO_4$ has been studied in order to suppress dissociation and improve the mechanical properties. Addition of $SiO_2$ suppressed the dissociation of $ZrSiO_4$ at lower temperatures. It also enabled optimum packing between the particles, resulting in a dense microstructure and good mechanical properties. When 3Y-TZP was added, recombination with the dissociated $SiO_2$ resulted in good mechanical properties by suppressing the generation of pores and the densification of the microstructure.

• Computers and Concrete
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• 제9권2호
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• pp.153-169
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• 2012

The contribution of steel fibers on the 28-day compressive strength of high-performance steel fiber reinforced concrete was investigated, is presented. An extensive experimentation was carried out over water-cementitious materials (w/cm) ratios ranging from 0.25 to 0.40, with silica fume-cementitious materials ratios from 0.05 to 0.15, and fiber volume fractions ($V_f$= 0.0, 0.5, 1.0 and 1.5%) with the aspect ratios of 80 and 53. Based on the test results of 44 concrete mixes, mathematical model was developed using statistical methods to quantify the effect of fiber content on compressive strength of HPSFRC in terms of fiber reinforcing index. The expression, being developed with strength ratios and not with absolute values of strengths, is independent of specimen parameters and is applicable to wide range of w/cm ratios, and used in the mix design of steel fiber reinforced concrete. The estimated strengths are within ${\pm}3.2%$ of the actual values. The model was tested for the strength results of 14 mixes having fiber aspect ratio of 53. On examining the validity of the proposed model, there exists a good correlation between the predicted values and the experimental values of different researchers. Equation is also proposed for the size effect of the concrete specimens.

• Structural Engineering and Mechanics
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• 제51권1호
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• pp.1-13
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• 2014

This paper reports an experimental study into the rheological behaviour of self consolidating concrete (SCC). The investigation aimed at quantifying the impact of the varying amounts of mineral admixtures on the rheology of SCC containing natural sand. Apart from the ordinary Portland cement (OPC), the cementitious materials such as fly ash (FA), ground granulated blast furnace slag (GGBS) and micro-silica (MS) in conjunction with the mineral admixtures were used in different percentages keeping the mix paste volume and flow of concrete constant at higher atmospheric tempterature ($30^{\circ}$ to $40^{\circ}C$). The rheological properties of SCC were investigated using an ICAR rheometer with a four-blade vane. The rheological properties of self-consolidating concrete (SCC) containing different mineral admixtures (MA) were investigated using an ICAR rheometer. The mineral admixtures were fly ash (FA), ground granulated blast furnace slag (GGBS), and micro silica (MS). The results obtained using traditional workability results are compared with those obtained using ICAR rheometer. The instrument ICAR (International Center for Aggregate Research) rheometer employed in the present study for evaluating the rhelogical behaviour of the SCC is found to detect systematic changes in workability, cementitious materials, successfully. It can be concluded that the rheology and the slump flow tests can be concurrently used for predicting the flow behaviours of SCC made with different cementitious materials.

• Structural Engineering and Mechanics
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• 제76권2호
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• pp.175-191
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• 2020

In this study, the effect of Nano silica (SiO2) on the buckling strength of the glass fiber reinforced laminates containing the machining process causes holes were investigated. The tests have been applied on two status milled and non-milled. To promote the mechanical behavior of the fiber-reinforced glass epoxy-based composites, Nano sio2 was added to the matrix to improve and gradation. Nano sio2 is chosen because of flexibility and high mechanical features; the effect of Nanoparticles on surface serenity has been studied. Thus the effect of Nanoparticles on crack growth and machining process and delamination caused by machining has been studied. We can also imply that many machining factors are essential: feed rate, thrust force, and spindle speed. Also, feed rate and spindle speed were studied in constant values, that the thrust forces were studied as the main factor caused residual stress. Moreover, entrance forces were measured by local calibrated load cells on machining devices. The results showed that the buckling load of milled laminates had been increased by about 50% with adding 2 wt% of silica in comparison with the neat damaged laminates while adding more contents caused adverse effects. Also, with a comparison of two milling tools, the cylindrical radius-end tool had less destructive effects on specimens.