• Bulletin of the Korean Chemical Society
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• v.34 no.1
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• pp.99-106
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• 2013

Polyaniline-yttrium trioxide (PAni-$Y_2O_3$) composites were synthesized by the in-situ polymerization of aniline in the presence of $Y_2O_3$ The composite formation and structural changes in these composites were investigated by X-ray diffraction (XRD), Fourier transform infra red spectroscopy (FTIR), scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM). The direct current (DC) electrical conductivity of the order of $0.51{\times}10^{-2}\;S\;cm^{-1}-0.283\;S\;cm^{-1}$ in the temperature range 300 K-473 K indicates semiconducting behavior of the composites. Room temperature AC conductivity and dielectric response of the composites were studied in the frequency range of 10 Hz to 1 MHz. The variation of AC conductivity with frequency obeyed the power law, which decreased with increasing weight percentage (wt %) of $Y_2O_3$. Studies on dielectric properties shows the relaxation contribution coupled by electrode polarization effect. The dielectric constant and dielectric loss in these composites depend on the content of $Y_2O_3$ with a percolation threshold at 20 wt % of $Y_2O_3$ in PAni. Electromagnetic interference shielding effectiveness (EMI SE) of the composites in the frequency range 100 Hz to 2 GHz was in the practically useful range of -12.2 dB to -17.2 dB. The observed electrical and shielding properties were attributed to the interaction of $Y_2O_3$ particles with the PAni molecular chains.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2001.05a
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• pp.93-96
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• 2001

Structural polymer composites are susceptible to damage in the form of cracks, which form deep within the structure where detection is difficult and repair is almost impossible. A recent methodology for the damage repair of polymer composites using the self-healing technique is reported. The polymerization of the healing agent is triggered by contact with an embedded catalyst, being necessary to damage repair of polymer composites. For this purpose, the self-healing concept is introduced and the manufacturing process of microcapsule with the healing agent is briefly described. The polymerization between the healing agent and the catalyst is verified by the use of ESEM and IR spectroscopy. Finally the efficiency of the self-healing technique is investigated by measuring the critical load of TDCB specimen.

• Composites Research
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• v.23 no.4
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• pp.1-6
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• 2010

The dynamicresponse of biomimetic composites mimicking nacre under low velocity impact is investigated. The composites have hierarchical structures with a staggered pattern consisting of a protein and a mineral. To analyze the impact response of the composites, the finite element method is used. The effects of the hierarchical structures of the compositeson the dynamic response are examined. It is shown that the maximum stress, displacement and contact force in the composite subjected to low velocity impact decrease as the level of structural hierarchy increases.

• Composites Research
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• v.26 no.1
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• pp.48-53
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• 2013

This paper summarizes the structural characterization of borassus fruit fibers by means of various characterization techniques, optimization of alkali treatment of borassus fruit fine fibers (BFF) with a 5% concentration sodium hydroxide solution for different time intervals (1, 4, 8 and 12 h) and the changes occurring in borassus fibers. This paper also discusses the manufacturing of BFF/PP compotes using MAPP as a compatibilizer in addition to alkali treatment. Composites were evaluated for their mechanical and morphological properties. The tensile strength and modulus, flexural strength and modulus and impact strength were increased for alkali treated/MAPP composites by 4.5%, 17%, 17.2 %, 9% and 10% respectively.

• The Korean Journal of Ceramics
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• v.6 no.3
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• pp.201-205
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• 2000

Fiber reinforced plastic (FRP) composites and ceramic matrix composites (CMC) which contain electrically conductive phases have been designed and fabricated to introduce the detection capability of damage/fracture detection into these materials. The composites were made electrically conductive by adding carbon and TiN particles into FRP and CMC, respectively. The resistance of the conductive FRP containing carbon particles showed almost linear response to strain and high sensitivity over a wide range of strains. After each load-unload cycle the FRP retained a residual resistance, which increased with applied maximum stress or strain. The FRP with carbon particles embedded in cement (mortar) specimens enabled micro-crack formation and propagation in the mortar to be detected in situ. The CMC materials exhibited not only sensitive response to the applied strain but also an increase in resistance with increasing number of load-unload cycles during cyclic load testing. These results show that it is possible to use these composites to detect and/or fracture in structural materials, which are required to monitor the healthiness or safety in industrial applications and public constructions.

• Advances in nano research
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• v.10 no.4
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• pp.327-337
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• 2021

In this review, composite structures are used for many industries for at least four decades. Polymeric composites are one of the important structures in the aerospace and aviation industry because of their high strength and low weight. In this comprehensive review, mechanical behaviors, physical and mechanical properties of polymeric composites, different types of reinforcements, different methods to fabricate polymeric composites, historical structural composite materials for aviation and aerospace industries, and also different methods for the characterization are reported. How to use various methods of composite preparation using different nanofillers as reinforcements and its effect on the physical properties and mechanical behavior of composites are discussed as well.

• Structural Engineering and Mechanics
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• v.77 no.5
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• pp.651-659
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• 2021

In this study, a new constitutive model has been developed to predict the elastic behavior of plain weave textile composites, using the finite element (FE) method. The geometric conditions and basic assumptions of this model are based on the basics of a continuum theory developed for the plane curved composites. In this model, the mechanical properties of the weave region and pure matrix region is calculated separately and then imported for the FE analysis. This new constitutive model is used to implement the mechanical properties of weave region in the representative volume element (RVE). The constitutive relations are implemented as user-material subroutine code (UMAT) in ABAQUS® FE software. The results of FE analysis have been compared with experimental results and other data available in the literature. These comparisons confirmed the capability of the presented model for the prediction of effective elastic properties of plain weave fabric composites.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.30 no.1
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• pp.23-30
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• 2017

Since shape, size and distribution of particles in particulate composites have spreaded characteristics, properties of particulate composites have variation and also system behavior using particulate composites have variation. However, it is difficult to consider spreaded characteristic of particles so that a system behavior is analysed using homogeneous techniques or using microstructure in local areas. In this study, for considering random variation of particles, RMDFs(random morphology description functions) are used to generate random microstructure and relationship between the number of gaussian functions and spreaded characteristic of particles was analysed using the geometrical moment of area. Also, multi-scale analysis was carried out for cantilever beam with full-random microstructure to study behavior of particulate composites structure. As a result, it is defined that spreaded characteristic of particles and the variation of deflections of cantilever beam are decreased as the number of Gaussian functions(N) is increased and converges at N=200.

• Journal of the Korea institute for structural maintenance and inspection
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• v.25 no.6
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• pp.27-32
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• 2021

This study was conducted to improve the workability of cementitious composites using nano-bubble water. The used nano-bubble water contains 7% of nano-sized bubbles with an averaged bubble size of 750 nm. Various different types of cementitious composites including ultar-high performance concrete, lightweight cementitious composites, and high-strength mortar have been tested to identify the changes of material properties. From the use of nano-bubble water, it was confirmed that workability has been improved by 3-22%. On the other hand, other material characteristics such as compressive strength did not have noticeable changes. Therefore, it was proposed that the use of nano-bubble water can enhance workability of cementitious composites without having significant impact on other material properties.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.1
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• pp.113-121
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• 2019

In this study, self - healing microcapsules which can be mixed directly with cement composites were prepared, and the quality and crack healing performance of cement composites with self - healing microcapsules were evaluated. In the past, it has been focused on evaluating self-healing capsules and crack healing properties. Therefore, self - healing microcapsules have been studied for their effect on the quality of cement composites when mixed with cement composites. The table flow and the air flow rate of the cement composite material mixed with self-healing microcapsules were found to have no significant influence on table flow and air volume regardless of mixing ratio. Compressive strength and splitting tensile strength tended to decrease with increasing capsule mixing ratio. As a result of evaluation of crack healing properties according to water flow, initial water permeability decreased, and reaction products were generated over time and cracks were healed.