• Title/Summary/Keyword: strongly correlated metal

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Photoemission study f valence stated in Eu chalcogenides

  • Hoon Koh;Park, Won-Go;Oh, S.J.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.166-166
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    • 2000
  • We studied electronic structure of magnetic semiconductors EuO, EuS, and EuTe. The photoemission spectra show localized Eu 4f states and broad anion p bands. As the size of anion increases from oxygen to tellurium, anion p band width increases and eventually overlaps Eu 4f states. Hence in EuO and EuS, Eu 4f states are the highest occupied stated lying above anion p band, while Te 5p band spreads widely over Eu 4f states to become valence band maximum in EuTe. It was also observed that Eu 4f states have width of 0.7eV and dispersion of 0.2eV in EuS by angle resolved photoemission spectroscopy. The width of the 4f spectra mainly originates from atomic multiplets, but the much larger dispersion than that of Eu metal is due to p-f mixing.

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False Positive SOD Activity of Bifidobacterium spp. Grown in MRS Medium

  • Chang, Woo-Suk;So, Jae-Seong
    • Journal of Microbiology and Biotechnology
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    • v.8 no.4
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    • pp.305-309
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    • 1998
  • The superoxide dismutase (SOD) activity of seven Bifidobacterium spp. strains was examined by an indirect SOD assay method. Some Bifidobacterium spp. showed significant levels of SOD activity. However, we could not observe any significant differences between anaerobic and aerobic cultures. Furthermore, although several Bifidobacterium spp. exhibited some degree of tolerance to paraquat which produces superoxide radicals, the apparent SOD activity of these strains was not correlated with their resistance to paraquat. In addition, when we added increasing amounts of manganese or iron to MRS medium which had been prepared without either of the metal ions, the apparent SOD activity of cell free extracts (CFEs) was increased with increasing concentration of both metal ions. To our surprise, the heat-denatured CFEs also showed nearly identical correlative patterns. Based on these results, the apparent SOD activity was likely due to a nonenzymatic dismutation. These results strongly suggest that high concentration of divalent metal ions ($Mn^{2+}$, $Fe^{2+}$) in MRS medium result in nonenzymatic dismutation which can lead to false positive SOD activities in Bifidobacerium spp.

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Tunneling Density of States in Superconductor/d-wave Superconductor Proximity Junction (초전도체와 d-wave 초전도체 근접효과 접합에서의 터널링 상태밀도함수)

  • Lee, H. J.;Yonuk Chong;J. I. Kye;Lee, S. Y.;Z.G. Khim
    • Progress in Superconductivity
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    • v.2 no.2
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    • pp.57-64
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    • 2001
  • We have calculated the tunneling density of states (TDOS) of a metal/d-wave superconductor proximity junction, where the metal stands fur the normal metal, 5-wave superconductor, and d-wave superconductor. The tunneling direction is through the ab-plane of the d-wave superconductor. Because of the sign change in the order parameter experienced in the multiple Andreev reflection, there appears a finite TDOS at zero bias for duty geometry, which results in the anomalous zero bias conductance peak(ZBCP). For $d_{x2-y2}$ geometry, however, no TDOS peak appears at zero bias. We have calculated TDOS for various crystal orientation of HTSC and compared with the experimental conductance.

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Ion Migration in Metal Halide Perovskites

  • Nur'aini, Anafi;Lee, Seokwon;Oh, Ilwhan
    • Journal of Electrochemical Science and Technology
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    • v.13 no.1
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    • pp.71-77
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    • 2022
  • Metal halide perovskites are promising photovoltaic materials, but they still have some issues that need to be solved. Hysteresis is a phenomenon that strongly is correlated with ion migration; thus, a fast, easy, and low-temperature method for measuring ion migration is required. Through selective blocking, ion migration can be measured separately, apart from electron migration. In this study, ion migration in metal halide perovskites was measured using a vertical device. At different temperatures, ionic activation energies were obtained for a range of perovskite compositions such as MAPbI3, FAPbI3, CsPbI3, and MAPbBr3. By comparing the measured ionic activation energies with the theoretical values, we conclude that among other possibilities, I- is the migrating ion in MAPbI3, FAPbI3, CsPbI3, and Br- is the migrating in MAPbBr3.

Effect of Various Biodegradable Chelating Agents on Growth of Plants under Lead stress (생분해되는 다양한 킬레이트들이 납에 노출된 식물의 성장에 미치는 영향)

  • Lee, Sang-Man
    • Korean Journal of Environmental Agriculture
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    • v.29 no.1
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    • pp.61-65
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    • 2010
  • Phytoextraction is a method of phytoremediation using plants to remediate metal-contaminated soils. Recently, various chelating agents were used in this method to increase the bioavailability of metals in soils. Even though phytoextraction is an economic and environment-friendly method, this cannot be applied in highly metal-contaminated areas because plants will not normally grow in such conditions. This research focuses on identifying chelating agents which are biodegradable and applicable to highly metal-contaminated areas. Lead (Pb) as a target metal and cysteine (Cys), histidine (His), citrate, malate, oxalate, succinate, and ethylenediamine (EDA) as biodegradable chelating agents were selected. Ethylenediamine tetraacetic acid (EDTA) was used as a comparative standard. Plants were grown on agar media containing various chelating agents with Pb to analyze the effect on root growth. Cys strongly increased the inhibitory effect of Pb on root growth of plants, while, His did not affect on it significantly. The inhibitory effect of oxalate is weak, and malate, citrate, and succinate did not show significant effects. Both EDTA and EDA diminished the inhibitory effect of Pb on root growth. The effect of EDA is correlated with decreased Pb uptake into the plants. In conclusion, as biodegradable chelating agents, EDA is a good candidate for highly Pb-contaminated area.

The study on the measurement for the pressure drop and friction factor of corrugated metal pipes (주름관에서의 압력강하와 마찰손실 계측에 관한 연구)

  • Yun, Young-Sun;Kang, Jun-One;Yoo, Jai-Suk;Kim, Hyung-Jung
    • Journal of the Korean Society of Visualization
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    • v.4 no.2
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    • pp.76-80
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    • 2006
  • The data for friction factor of the pipe correlated by Reynolds number and relative roughness have been reported well as a Moody chart. However, the results for corrugated shapes have been not investigated sufficiently. In this research, therefore, the pressure drop and friction factor are obtained. Flexible metal tubes with corrugations for the measurement are made of stainless steel plates. The kinds of tubes for the measurement are 5 annular types and helical types. The pressure drop & the velocity of the flow are obtained by micromanometer & digital pressure sensor, supplying dry air at several steps. Then the pressure drop is calculated for each tube, using the obtained data. The result shows that the pressure drop is strongly influenced by the viscous dissipation of kinetic energy due to the circulation of flows, rather than a viscous friction loss. The pressure drop increased consistently as the Reynolds number increases.

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