• Bulletin of the Korean Chemical Society
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• 제34권6호
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• pp.1637-1642
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• 2013

We carried out the melt copolymerization reactions of 1,2-bis(diethylamino)tetramethyldisilane with several aryldiols such as, 4,4'-biphenol, 4,4'-isopropylidenediphenol, 9H-fluoren-9,9-dimethanol, and 4,4'-(9-fluorenylidene) bis(2-phenoxyethanol) to afford poly[oxy(arylene)oxy(tetramethyldisilylene)]s containing fluorescent aromatic chromophore groups in the polymer main chain: poly[oxy(4,4'-biphenylene)oxy(tetramethyldisilylene)], poly[oxy{(4,4'-isopropylidene) diphenylene}oxy(tetramethyldisilylene)], poly[oxy(9H-fluorene-9,9-dimethylene) oxy(tetramethyldisilylene)], and poly[oxy{4,4'-(9-fluorenylidene)bis(2-phenoxyethylene)}oxy(tetramethyldisilnylene)]. These prepared materials are soluble in common organic solvents such as $CHCl_3$ and THF. The obtained polymers were characterized by several spectroscopic methods such as $^1H$, $^{13}C$, and $^{29}Si$ NMR. Further, FTIR spectra of all the polymers exhibited characteristic Si-O stretching frequencies at 1014-1087 $cm^{-1}$. These polymeric materials in THF showed strong maximum absorption peaks at 268-281 nm, strong maximum excitation peaks at 263-291 nm, and strong maximum fluorescence emission bands at 314-362 nm due to the presence of tetramethyldisilylene and several arylene chromophores in the polymer main chain. TGA thermograms indicated that most of the polymers were stable up to $200^{\circ}C$ with a weight loss of 3-16% in nitrogen.

• Bulletin of the Korean Chemical Society
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• 제32권4호
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• pp.1303-1309
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• 2011

Melt copolymerization reactions of bis(diethylamino)tetramethyldisiloxane with several aryldiols were carried out to afford poly(carbotetramethyldisiloxane)s containing fluorescent aromatic chromophore groups in the polymer main chain: poly{oxy(4,4'-biphenylene)oxytetramethyldisiloxane}, poly{oxy(1,4-phenylene)oxytetramethyldisiloxane}, poly[oxy{(4,4'-isopropylidene)diphenylene}oxytetramethyldisiloxane], poly[oxy{(4,4'-hexafluoroisopropylidene)diphenylene}oxytetramethyldisiloxane], poly{oxy(2,6-naphthalene)oxytetramethyldisiloxane}, poly[oxy{4,4'-(9-fluorenylidene)diphenylene}oxytetramethyldisiloxane], poly{oxy(fluorene-9,9-dimethylene)oxytetramethyldisiloxane}, and poly[oxy{4,4'-(9-fluorenylidene)bis(2-phenoxyethylene)}oxytetramethyldisiloxane]. These materials are soluble in common organic solvents such as $CHCl_3$ and THF. The FTIR spectra of all the polymers exhibit the characteristic Si-O-C stretching frequencies at 1021-1082 $cm^{-1}$. In the THF solution, the polymeric materials show strong maximum absorption peaks at 215-311 nm, with strong maximum excitation peaks at 250-310 nm, and strong maximum fluorescence emission bands at 310-360 nm. TGA thermograms indicate that most of the polymers are stable up to $200^{\circ}C$ with a weight loss of less than 10% in nitrogen.

• Bulletin of the Korean Chemical Society
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• 제35권6호
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• pp.1825-1831
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• 2014

Grignard metathesis polymerizations of 1,1-disubstituted-2,5-dibromo-3,4-diphenylsiloles such as 1,1-dimethyl-2,5-dibromo-3,4-diphenylsilole, 1,1-diethyl-2,5-dibromo-3,4-diphenylsilole, 1,1-diisopropyl-2,5-dibromo-3,4-diphenylsilole, and 1,1-dihexyl-2,5-dibromo-3,4-diphenylsilole were performed to yield poly(1,1-disubstituted-3,4-diphenyl-2,5-silole)s containing fluorescent aromatic chromophore groups such as phenyl and silole in the polymer main chain: poly(1,1-dimethyl-3,4-diphenyl-2,5-silole), poly(1,1-diethyl-3,4-diphenyl-2,5-silole), poly(1,1-diisopropyl-3,4-diphenyl-2,5-silole), and poly(1,1-dihexyl-3,4-diphenyl-2,5-silole), respectively. The obtained materials are highly soluble in common organic solvents such as chloroform and tetrahydrofuran. Fourier-transform infrared spectra of all the polymers have characteristic C=C stretching frequencies at $1620-1628cm^{-1}$. The prepared organosilicon polymers exhibit strong absorption maximum peaks at 273-293 nm in the tetrahydrofuran solution, showing a red-shift of 18-34 nm relative to those of the monomer, strong excitation maximum peaks at 276-303 nm, and strong fluorescence emission maximum bands at 350-440 nm. Thermogravimetric analysis shows that most of the polymers are stable up to $200^{\circ}C$ with a weight loss of 6-16% in nitrogen.

• 한국축산식품학회지
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• 제18권2호
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• pp.157-163
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• 1998

This study was carried out to examine that pepsin-hydrolyzed bovine lactoferrin has applicabilities which are market milk and dairy products. The stability of pepsin-hydrolyzed bovine apo-lactoferrin and the change of its antibacterial character has been studied under various method for pasteurization (LTLT; 65$^{\circ}C$ / 30min., HTST ; 75$^{\circ}C$ / 15sec., UHT ; 135$^{\circ}C$ / 3sec.) and pH Values (pH 2.0, pH 4.0, pH 6.8). The ehated samples were assayed for minimal bacteriocidal concentrations (MBCs) and bacteriocidal effect against E. coli. The results obtained were summarized as follows: After fractionation of pepsin-hydrolyzed bovine lactofeerin by gel filtration. several peptide fractions were found that had strong antibacterial activity. SDS-PAGE showed that the one of these fractions with strong antibacterial activity, which had a molecular mass a range of 30∼33KDa. The MBCs for pepsin-hydrolyzed bovine lactoferrin fraction No. 2 against E. coli required to cause complete inhibition of growth varied within the range of 200∼400 $\mu\textrm{g}$/ml, depending on heat treatments and pH conditions. The peptide fraction No. 2 showed strong bacteriocidal activity against E. coli at LTLT and HTST treatments under acidic pH conditions. and was reduced activity at UHT treatment under pH 6.8 condition.

• Bulletin of the Korean Chemical Society
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• 제33권6호
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• pp.2031-2036
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• 2012

Melt copolymerization reactions of several bis(diethylamino)silane derivatives, bis(diethylamino)methylphenylsilane, bis(diethylamino)methyloctylsilane, 1,2-bis(diethylamino)tetramethyldisilane, and 1,3-bis(diethylamino) tetramethyldisiloxane, with 2,7-dihydroxyfluoren-9-one were carried out to yield poly[oxy(2,7-fluoren- 9-onenylene)oxy(diorganosilylene)]s bearing the fluoren-9-one fluorescent aromatic group in the polymer main chain: poly[oxy(2,7-fluoren-9-onenylene)oxy(methylphenylsilylene)], poly[oxy(2,7-fluoren-9-onenylene) oxy(methyloctylsilylene)], poly[oxy(2,7-fluoren-9-onenylene)oxy(tetramethyldisilylene)], and poly[oxy- (2,7-fluoren-9-onenylene)oxy(tetramethyldisiloxanylene)]. These polymeric materials are soluble in common organic solvents such as $CHCl_3$ and THF. FTIR spectra of all the materials reveal characteristic Si-O-C stretching frequencies at 1012-1018 $cm^{-1}$. In the THF solution, the prepared materials show strong maximum absorption peaks at 258-270 nm, strong maximum excitation peaks at 260-280 nm, and strong maximum fluorescence emission bands at 310-420 nm. TGA thermograms suggest that most of the polymers are essentially stable to $200^{\circ}C$ without any weight loss and up to $300^{\circ}C$ with only a weight loss of less than 5% in nitrogen.

• Geomechanics and Engineering
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• 제31권3호
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• pp.319-328
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• 2022

Ensuring the integrity of a country's infrastructure is necessary to protect surrounding communities in case of disaster. Embankment dam systems across the US are an essential component of infrastructure, referred to as lifeline structures. Embankment dams are crucial to the survival of life and if these structures were to fail, it is imperative that states be prepared. Southern California is particularly concerned with the stability of embankment dams due to the frequent seismic activity that occurs in the state. The purpose of this study was to create a numerical model of an existing embankment dam simulated under seismic loads using previously recorded data. The embankment dam that was studied in Los Angeles, California was outfitted with accelerometers provided by the California Strong Motion Instrumentation Program that have recorded strong motion data for decades and was processed by the Center for Engineering Strong Motion Data to be used in future engineering applications. The accelerometer data was then used to verify the numerical model that was created using finite element modeling software RS2. The results from this study showed Puddingstone Dam's simulated response was consistent with that experienced during previous earthquakes and therefore validated the predicted behavior from the numerical model. The study also identified areas of weakness and instability on the dam that posed the greatest risk for its failure. Following this study, the numerical model can now be used to predict the dam's response to future earthquakes, develop plans for its remediation, and for emergency response in case of disaster.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 1996년도 제24회 추계학술대회
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• pp.202-206
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• 1996

An experimental study of the characteristics of the repulsiveytype magnetic bearing using high Tc superconductor is presented. In field cooling superconductor has the position-stability due to a flux pinning effect and the strong damping due to hysterisis, while in zero field cooling it has the only strong repulsive force due to Meissner effect. Lift force in superconducting levitation has a hysterisis characteristics, and it is the dissipation of energy, the mechanism of damping. As the relative linear velocity between a magnet and a superconductor increases, the area of the hysterisis loop becomes smaller. It means the decrease of damping. In field cooling, the static stiffness is very nonlinear in smaller than initial gap, but almost linear in larger than initial gap.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2002년도 제18회 학술발표대회 논문초록집
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• pp.41-42
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• 2002

The powered missiles with very high thrust level can make highly underexpanded jet plume downstream of tile exhaust nozzle exit so that strong interactions between the exhaust plume and a free stream occur around the body at transonic or supersonic speeds. The interactions result in extremely complicated flow phenomena, which consist of plume-induced boundary layer separation, strong shear layers, various shock waves, and interactions among these. The flow characteristics are inherent nonlinear and severe unstable during the flight at its normal speed as well as taking-off and landing. Eventually, the induced boundary layer separation and pitching and yawing moments by the interactions cause undesirable effects ell the static stability and control of a missile.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 1991년도 봄 학술발표회 논문집
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• pp.72-78
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• 1991

An improved procedure for earthquake resistant design of multistory building structures is proposed in this study. The effect of gravity load on seismic response of structures is evaluated through nonlinear dynamic analyses of a single story example structure. The presence of gravity load tends to initiate plastic hinge formation in earlier stage of a strong earthquake. However, the effect of gravity load seems to disapper as ground motion is getting stronger. And one of shortcomings in current earthquake resistant codes is overestimation of gravity load effects when earthquake load is applied at the same time so that it may leads to less inelastic deformation or structural damage in upper stories, and inelastic deformation is increased in lower stories. Based on these observation, an improved procedure for earthquake resistant design is derived by reducing the factor for gravity load and inceasing that for seismic load. Structures designed by the proposed design procedure turned out to have increased safety and stability against strong earthquakes.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• 제11권1호
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• pp.1-11
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• 2007

A linear stability analysis applied to a system consist of a horizontal fluid layer overlying a layer of a porous medium affected by a vertical magnetic field on both layers. Flow in porous medium is assumed to be governed by Darcy's law. The Beavers-Joseph condition is applied at the interface between the two layers. Numerical solutions are obtained for stationary convection case using the method of expansion of Chebyshev polynomials. It is found that the spectral method has a strong ability to solve the multilayered problem and that the magnetic field has a strong effect in his model.