• Title/Summary/Keyword: stoichiometric air ratio

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Experimental Analyses of Cell Voltages for a Two-cell PEM Stack Under Various Operating Conditions

  • Park, Sang-Kyun;Choi, Jae-Hyuk
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.7
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    • pp.881-890
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    • 2011
  • Analyses of performance and behavior of the individual PEM fuel cells (PEMFC) under different operating conditions are of importance optimally to design and efficiently to operate the stack. The paper focuses on experimental analyses of a two-cell stack under different operating conditions, which performance and behavior are measured by the voltage of a cell as well as the stack. Experimental parameters include stoichiometric ratio, temperature of the air supplied under different working stack temperatures and loads. Results showed that the cell voltages are dominantly influenced by the temperature of the air supplied among others. In addition, an inherent difference between the first and the second cell voltage exists because of the tolerances of the cell components and the resulting different over-potentials at different equilibrium states. Furthermore, it is shown that the proton conductivity in the membranes conditioned by the humidity in the cathode channel highly affects the voltage differences of the two cells.

Simplified Reaction Scheme of Hydrocarbon Fuels and Its Application to Autoignition of Gasoline with Different Octane Numbers (탄화수소계 연료의 축소반응모델과 가솔린연료의 옥탄가 변화에 따른 자발화 지연시간)

  • 여진구
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.3
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    • pp.13-19
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    • 2003
  • Mathematically simplified reaction scheme that simulates autoignitions of the end gases in spark ignition engines has been studied computationally. The five equation model is described, to predict the essential features of hydrocarbon oxidation. This scheme has been calibrated against autoignition delay times measured in rapid compression machines. The rate constants, activation temperatures, Ta, Arrhenius preexponential constants, A, and heats of reaction for stoichiometric n-heptane/air, iso-octane/air, and their mixtures have all been optimised. The optimisation has been guided by Morley's correlation of the ratio of chain branching to linear termination rates with octane number. Comparisons between computed and experimental autoignition delay times have validated the Present simplified reaction scheme and the influences of octane number upon autoignition delay times have been computationally investigated. It has been found that both cool flame and high temperature direct reactions can have an effect on autoignition delay times.

A Numerical Analysis of the NO Emission Characteristics in $CH_4/Air$ Counterflow Premix Flame (메탄/공기 대향류 예혼합화염의 NO 발생특성에 관한 수치해석)

  • Cho, Eun-Seong;Chung, Suk-Ho
    • Journal of the Korean Society of Combustion
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    • v.9 no.4
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    • pp.22-27
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    • 2004
  • Lean premix combustion is a best method in low $NO_x$ gas turbine combustor and we must know the characteristics of NO emission in high temperature and pressure condition in premix flame. Numerical analysis was performed to investigate the NO emission characteristics by adopting a counterflow as a model problem using detailed chemical kinetics. Methane $(CH_4)$ was used as a test fuel which is the main fuel of natural gas. The tested parameters were stretch rate, equivalence ratio, initial temperature, and pressure in premix flame. Results showed that NO emission was high in low stretch rate, near stoichiometric equivalence ratio, high initial temperature, and high pressure. Also, the pressure effect was sensitive in high temperature condition.

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Interacting Effects of an Ultrasonic Standing-wave on the Propagation Behavior and Structural Stabilization of Propane/Air Premixed Flame (프로판/공기 예혼합화염의 전파거동 및 구조안정화에 대한 정상초음파의 간섭효과)

  • Lee, Sang Shin;Seo, Hang Seok;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.16 no.6
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    • pp.1-8
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    • 2012
  • An experimental study has been conducted to scrutinize into the influence of ultrasonic standing wave on the propagating behavior and structural stabilization of propane/air premixed flame at various equivalence ratios in half-open rectangular duct. Evolutionary features of the flame fronts are caught by high-speed images, and the variation of flame structure and local flame velocities along the propagation are analyzed. It is revealed that the propagation velocity agitated by the ultrasonic standing wave is greater than that without the agitation: the velocity enhancement diminishes as the equivalence ratio approaches the stoichiometric. Influence of standing wave on the flame overwhelms that of the buoyancy which slants the flame front towards top of the duct, and thus the standing wave contributes to the structural stabilization of propane/air premixed flame.

Agitation Effects of an Ultrasonic Standing Wave on the Dynamic Behavior of Methane/Air Premixed Flame (메탄/공기 예혼합화염의 동역학적 거동과 정상초음파의 교반)

  • Seo, Hang-Seok;Lee, Sang-Shin;Kim, Jeong-Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.16 no.3
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    • pp.16-23
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    • 2012
  • This study has been conducted to scrutinize agitation effects of an ultrasonic standing wave on the dynamic behavior of methane/air premixed flame. The propagating flame was caught by high-speed Schlieren images, through which local flame velocities of the moving front were analyzed in unprecedent detail. It is revealed that the propagation velocity agitated by the ultrasonic standing wave is greater than that without agitation at the stoichiometric ratio: the velocity enhancement diminishes as the equivalence ratio approaches upper flammability limit or lower flammability limit. Also, vertical locations of the wave-affected frontal distortions do not vary appreciably, unless the propagating-mode characteristics (pressure amplitude and driving frequency) of ultrasonic standing wave were not changed.

LOW FUEL CONSUMPTION AND LOW EMISSIONS - ELECTROMECHANICAL VALVE TRAIN IN VEHICLE OPERATION

  • Pischinger, M.;Salber, W.;Staay, F.V.D.;Baumgarten, H.;Kemper, H.
    • International Journal of Automotive Technology
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    • v.1 no.1
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    • pp.17-25
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    • 2000
  • The electromechanical valve train (EMV) technology allows for a reduction in fuel consumption while operating under a stoichiometric air-fuel-ratio and preserves the ability to use conventional exhaust gas aftertreatment technology with a 3-way-catalyst. Compared with an engine with a camshaft-driven valve train, the variable valve timing concept makes possible an additional optimization of cold start, warm-up and transient operation. In contrast with the conventionally throttled engine, optimized control of load and in-cylinder gas movement can be used for each individual cylinder and engine cycle. A load control strategy using a "Late Intake Valve Open" (LIO) provides a reduction in start-up HC emissions of approximately 60%. Due to reduced wall-wetting, the LIO control strategy improves the transition from start to idle. "Late Exhaust Valve Open" (LEO) timing during the exhaust stroke leads to exhaust gas afterburning and, thereby, results in high exhaust gas temperatures and low HC emissions. Vehicle investigations have demonstrated an improved accuracy of the air-fuel-ratio during transient operation. Results in the New European Driving Cycle have confirmed a reduction in fuel consumption of more than 15% while meeting EURO IV emission limits.

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A Study on Tuning Effects of Intake Manifold, Intake Pipe and Air Filter upon Performance and Exhaust Emissions of Driving Car (운행자동차 성능 및 배기 배출물에 미치는 흡기 다기관, 흡기 파이프 및 공기필터의 튜닝효과에 관한 연구)

  • Bae, Myung-whan;Ku, Young Jin;Park, Hui-seong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.5
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    • pp.538-548
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    • 2016
  • The purpose of this study is to identify the possibility of effective tuning works, understand the characteristics of tuning engine, and analyse the basic data of engine tuning inspection corresponding to the safe operation and environment of a driving gasoline car. The effects of tuning on the characteristics of performance and exhaust emissions under a wide range of engine speeds are experimentally investigated by the actual driving car with a four-cycle, four-cylinder DOHC, turbo-intercooler, water-cooled gasoline engine operating at four types of non-tuning, tuning 1, 2 and 3. The tuning parts in the gasoline engine are the intake manifold, intake pipe and air filter. In the experiment, the output, torque and air-fuel ratio of the five-speed automatic transmission vehicles were measured at the chassis dynamometer(Dynojet 224xLC) with one person on board. The exhaust emissions of $NO_X$, THC, CO, $O_2$ and $CO_2$, and excess air ratio(${\lambda}$) at the other chassis dynamometer(DASAN-MD-ASM-97-KR-HD) were also measured by the idle/constant-speed mode(ASM2525 mode) test method. It is found that the actual air-fuel ratios of non-tuning and tuning engines were shown to be lower than the stoichiometric air-fuel ratio with increasing engine speed, and the actual air-fuel ratio of non-tuning engine was slightly higher than those of tuning engines when the engine speed is more than 4000 rpm. The output was significantly increased by the tuning whereby the maximum output of tuning engine was more increased to approximately 117.64% than that of non-tuning engine. In addition, CO, THC and $NO_X$ emissions of non-tuning and tuning engines measured by the constant-speed test mode were all satisfied with the inspection standards. CO emission was increased, while THC and $NO_X$ emissions were reduced by tuning.

An Experimental Study on the Flame Structure of Partially Premixed Flame using OH PLIF (OH PLIF를 이용한 부분 예혼합 화염의 화염구조에 관한 실험적 연구)

  • Lee, Seung-Young;Lee, Jong-Ho;Jeon, Chung-Hwan;Chang, Young-June
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.54-59
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    • 2001
  • OH radical concentration have been measured in a methane-air partially premixed flames using PLIF. Excitation lines were selected $Q_{1}(6)$ branch, (1,0) band. The system is consisted of Nd:YAG laser, dye laser and frequency doubler to make pump beam for OH radical. On the direct photographs, flame height increases as fuel flow rate and equivalence ratio increase. And on the PLIF images, OH radical is distributed from premixed flame front to nonpremixed flame front through the flame structure with all equivalence ratio. OH overall concentrations increase with equivalence ratio. At the stoichiometric equivalence ratio, the peak of OH radical concentration exists strongly near the inner cone. As equivalence ratio is changed to richer, OH radical distribution goes thinly and the peak is increased as longitudinal direction. As the flow goes to the downstream, OH radical concentration decreases and broadens, because OH radical reacts with another species after OH formation at the initial oxidization. This phenomenon resembles radial distribution. At the l00cc fuel flowrate, the radial peak of OH radical exists from x/R=l.0 to 1.5.

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Numerical Study of Hydrogen/Air Combustion in Combustion Chamber of Ultra Micro Gas Turbine by Change of Flow Rate and Equivalence Ratio (공급 유량 및 당량비 변화에 따른 초소형 가스터빈 연소실 내 수소/공기 연소의 수치해석 연구)

  • Kwon, Kilsung;Hwang, Yu Hyeon;Kang, Ho;Kim, Daejoong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.2
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    • pp.103-109
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    • 2013
  • In this study, we performed a numerical study of hydrogen/air combustion in the combustion chamber of an ultra micro gas turbine. The supply flow rate and equivalence ratio are used as variables, and the commercial computational fluid dynamic program (STAR-CCM) is used for the numerical study of the combustion. The flow rate significantly affects the flame position, flame temperature, and pressure ratio between the inlet and the outlet. The flame position is close to the outlet in the combustion chamber, and the flame temperature and pressure ratio monotonously increases with the supply flow rate. The change in the equivalence ratio does not affect the flame position. The maximum flame temperature occurs under stoichiometric conditions.

Fuzzy Variable Structure Control System for Fuel Injected Automotive Engines (연료분사식 자동차엔진의 퍼지가변구조 제어시스템)

  • Nam, Sae-Kyu;Yoo, Wan-Suk
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.7 s.94
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    • pp.1813-1822
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    • 1993
  • An algorithm of fuzzy variable structrue control is proposed to design a closed loop fuel-injection system for the emission control of automotive gasoline engines. Fuzzy control is combined with sliding control at the switching boundary layer to improve the chattering of the stoichiometric air to fuel ratio. Multi-staged fuzzy rules are introduced to improve the adaptiveness of control system for the various operating conditions of engines, and a simplified technique of fuzzy inference is also adopted to improve the computational efficiency based on nonfuzzy micro-processors. The proposed method provides an effective way of engine controller design due to its hybrid structure satisfying the requirements of robustness and stability. The great potential of the fuzzy variable structure control is shown through a hardware-testing with an Intel 80C186 processor for controller and a typical engine-only model on an AD-100 computer.