• Title/Summary/Keyword: stirred reactor

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Application of High-performance Jet Loop Reactor for the Decolorization of Reactive black 5 and Mineralization of Oxalic Acid by Ozone (색도물질과 옥살산의 오존분해를 위한 고효율 Jet Loop 반응기의 적용)

  • Byun, Seok-jong;Geissen, Sven-Uwe;Vogelpohl, Aflons;Cho, Soon-haing;Yoon, Je-yong;Kim, Soo-Myung
    • Journal of Korean Society on Water Environment
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    • v.20 no.1
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    • pp.78-85
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    • 2004
  • As an ozone contactor, we newly adopted HJLR (High-performance Jet Loop Reactor) for the decolorization of Reactive black 5 and the mineralization of oxalic acid, which has been applied exclusively in biological wastewater treatments and well-known for high oxygen transfer characteristics. The ozonation efficiency for organic removals and ozone utilization depending on the mass transfer rate were compared to those of Stirred bubble column reactor, which was controlled by varing energy input in the HJLR and Stirred bubble column reactor. The results were as follows; first, the decolorization rate of Reactive black 5 in the HJLR reactor was nearly proportional to the increasing $k_La$. When the $k_La$ was increased by 25 % from $13.0hr^{-1}$ to $16.4hr^{-1}$, 30 % of the k' (apparent reaction rate constant) was increased from 0.1966 to $0.2665min^{-1}$ (Stirred bubble column; from 0.1790 to $0.2564min^{-1}$). Ozone transfer was found to be a rate-determining step in decolorizing Reactive black 5, which was supported by that no residual ozone was detected in all of the experiments. Second, the mineralization of oxalic acid was not always proportional to the increasing $k_La$ in the RJLR reactor. The rate-determining step for this reaction was OH(OH radical) production with ozone transfer, because residual ozone was always detected during the ozonation of oxalic acid in contrast with Reactive black 5. This result indicates that the increase of $k_La$ in the HJLR reactor is beneficial only when there are in ozone transfer limited regions. In addition, regardless of $k_La$, the mineralization of oxalic acid was nearly accomplished within 60 minutes. It was interpreted as that the longer staying of residual ozone by whirling liquid in the HJLR reactor contributed to an high ozone utilization(83-94%), producing more OR radicals.

A Study on the Design of Denitrification Reactor and the Characteristics (탈질화 반응기의 설계 및 특성에 관한 연구)

  • 김선화;송주영
    • Journal of Life Science
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    • v.11 no.3
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    • pp.273-278
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    • 2001
  • Removal of nitrogen compound from waste water is essential and often accomplished by biological process. Deni-trification bacterium. Paracoccus denitrificans(KCTC 2350) is employed to estimate the ability and the characteristics of denitrification. In the immobilized biological reactor system, the measurement of absolute amount of active strain in the reactor is comparatively difficult or impossible. In this study, strain immobilized denitrification reactor was designed with the unwoven texture wrapped peeped hole plastic tube to calculated the absolute amount of active strain by comparing the activity of the immobilized reactor adn the free cell reactor. The reactor system was continuous stirred tank reactor and the rate of substrate consumption was assumed to be Michaelis-Menten equation. As a result, we found that the amount of immobilized active strain was the half of the total active strain in the reactor and the time required to reach in the equilibrium state in the immobilized reactor system was shorter than that of the free cell reactor system.

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Spore Production of Entomopathogenic Fungus, Beauveria bassiana 726, Using Molasses (당밀을 이용한 곤충병원성 곰팡이 Beauveria bassiana 726의 포자생산)

  • 김병혁;강성우;윤철식;성재모;홍석인;김승욱
    • KSBB Journal
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    • v.14 no.3
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    • pp.365-370
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    • 1999
  • To optimize the culture conditions for Beauveria bassiana 726, the effects of culture medium, pH, and temperature on mycelium and spore production were investigated. The optimum temperature and pH for the cultivation of B. bassiana 726 were 28 $^{\circ}C$ and 5.0, respectively. The optimized medium was composed of 1.0~2.0% total sugar from molasses, 0.5% corn steep liquor and 0.05% KH$_2$PO$_4$. In the cultivation of B. bassiana 726 with the optimum medium, the specific growth rate and substrate utilization were well-fitted with the proposed kinetic model in the shake flask and stirred tank reactor. When the fed-batch cultivation using carbon suorce, nitrogen source, and mineral salt as a feeding medium was compared with batch cultivation in stirred tank reactor, mycelium (12.7 g/L) and spore production (5.4$\times$$10^8/mL$) were enhanced up to 110% and 85%, respectively.

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Development of a Detailed Chemical Kinetic Reaction Mechanism of Surrogate Mixtures for Gasoline Fuel (가솔린 연료를 위한 대용혼합물의 상세한 화학반응 메카니즘 개발)

  • Lee, Ki-Yong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.1
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    • pp.46-52
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    • 2009
  • The oxidation of surrogate mixtures for gasoline fuel was studied numerically in perfectly stirred reactor(PSR) to develope the needed detailed reaction mechanism. The reaction mechanism was assembled with the mechanisms for the oxidation of iso-octane or kerosene. It was shown that the reaction model predicted reasonably well the concentration profiles of fuel and major species reported in the literature. As the addition of kerosene into iso-octane as fuel was increased, the concentrations of $C_2H_2$ and benzene became high. Especially benzene known as a carcinogen appeared at a very high concentration in the flue gases.

Production of Structured Lipid Containing Capric and Conjugated Linoleic Acids and Studies of Physicochemical Characteristics (Capric acid와 conjugated linoleic acid를 함유한 재구성 지질의 합성 및 특성연구)

  • Shin, Jung-Ah;Lee, Ki-Teak
    • Korean Journal of Food Science and Technology
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    • v.36 no.4
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    • pp.537-541
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    • 2004
  • Based on reaction time and substrate molar ratio, structured lipid (SL-corn) was produced at 1:2:2(corn oil/capric acid/CLA) and 4% immobilized lipase from Rhizomucor miehei (RM IM). Reaction was carried out for 24 hr at $55^{\circ}C$ in 1-L stirred-batch reactor. After reaction, 13.3 mol% capric acid and 8.9%, CLA were incorporated into corn oil. Iodine and saponification values of SL-corn were 68 and 202, respectively. Tocopherol content decreased after reaction (about 39%). SL-corn showed more yellowish color than corn oil (p<0.05). Reversed-phase HPLC indicated triacylglycerol species containing capric acid in SL-corn resulted in faster crystallization than that of corn oil.

CFD Simulation of the Effects of Inlet Flow rate on Hydraulic Behavior in Continuous Stirred-Tank Reactor (CSTR) (CFD 모사 기법을 이용한 유입 유량에 의한 연속 완전혼화 반응조 수리거동 고찰에 관한 연구)

  • Lee, Young Joo;Oh, Jeong Ik;Yoon, Sukmin;Kim, Jong-Oh;Park, No-Suk
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.1
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    • pp.25-33
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    • 2016
  • This paper describes three-dimensional computational fluid dynamics (CFD) simulation of liquid-liquid flow and transient tracer tests in a full-scale continuous stirred-tank reactor (CSTR) used for drinking water treatment. To evaluate the effects of inlet flow rate on hydrodynamic behavior in the selected CSTR, inlet flow rate was changed from 10% to 100% of the design flow rate. From the results of CFD simulation and analysis, as the inlet flow rate increases, Modal index and ${\beta}$ value are increased. Also, Morrill index shows local minimal points in relation to the inlet flow rate, which are observed at 20% and 40% of the design flow. As inlet flow Increases more than 40%, it is shown that Morrill index re-increases to close to ideal CSTR.

Acidogenesis of Lipids-Containing Wastewater in Anaerobic Sequencing Batch Reactor (혐기성 연속 회분식 반응조를 이용한 지질 함유 폐수의 산발효 특성)

  • Kim, Sang-Hyoun;Shin, Hang-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.12
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    • pp.1075-1080
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    • 2009
  • The partial lipid degradation with the saturation of double-bond at the acidogenesis stage is known to help subsequent methanogenesis during anaerobic digestion. Acidogenic reactions in an anaerobic sequencing batch reactor (ASBR) and a continuously stirred tank reactor (CSTR) were carried out to compare their performances. A mixture of two unsaturated (oleate and linoleate) and two saturated (palmitate and stearate) long-chain fatty acids (LCFAs) was used as a model substrate. Biomass retention in the ASBR contributed to the enhanced performance at hydraulic retention time (HRT) below 15 hr. Biomass retention in the ASBR contributed to the enhanced performance compared to CSTR even at shorter HRT. ASBR would be a proper reactor configuration for the acidogenesis of lipid-containing wastewater.

Removal Characteristic of Nitrogenous Compounds According to the Combination of Feeding Ratio between the Supernatant of Precipitation Tank and Raw Domestic Wastewater (침전조 상등액과 유입하수의 유량대비에 따른 하수 내 질소 화합물 제거특성)

  • Park, Sang Min;Park, Jin Hee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.13 no.4
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    • pp.128-135
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    • 2005
  • This study was done to improve the effectiveness of nitrification and denitrification using the aeration-anoxic combination method using CFSTR(continuous-flow stirred-tank reactor) attached with an anoxic reactor filled with a media. In order to calculate the concentration of nitric acid within the aeration tank proportional to the anoxic rate within the reactor, supernatant within the inflow and precipitation tanks were influxed into the anoxic reactor. The rate of nitrogen removal was calculated using the concentration of inflow and flow of returned supernatant. From the results of this experiment, the carbon source needed in the anoxic reactor came from the inflow so that anoxification was achieved completely using the inflow source without the introduction of an external carbon source. However, as the ratio of nitric acid becomes large in inflow and nitric acid flow, the carbon source within the input source decreases so that the concentration of carbon source is important.

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Production and Characterization of New Structured-Oligosaccharides from Immobilized Mixed-enzyme Reactor (고정화 혼합효소를 이용한 새로운 구조의 올리고당 생산 및 특성 연구)

  • ;;;;;Seiya Chiba;Atsuo Kimura
    • KSBB Journal
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    • v.15 no.1
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    • pp.88-95
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    • 2000
  • We have produced new-structured oligosaccharides using immoobilized mixed-enzyme reactor of destransucrase from Leuconostoc mesenteroides B-512FMCM and $\alpha$-amylase from Aspergillus oryzae. The reactors of immobilized mixed-exzyme beads were more efficient for the production of oligosaccharides than that of each immobilized enzyme bead in stirred-tank reactior(STR) or in packed-bed reactor(PCR). In continuous flow reactor, the immobilized mixed-enzyme bead in PBR was more stable than in STR, and 52% of initial yield was maintained for 200 hr. New structured-oligosaccharides (NOS) reduced the change of pH in the culture of Streptococcus mutans. It also showed an inhibitory effect on the growth of Staphylococcus aureus.

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ANALYSIS OF MIXING EFFICIENCY OF A TUBULAR HEAT-EXCHANGER REACTOR USING CFD (CFD를 이용한 관상 열교환기형 반응기의 mixing 효율 분석)

  • Lee Ji Hyun;Song Hyun-Seob;Han Sang Phil
    • 한국전산유체공학회:학술대회논문집
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    • 2005.10a
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    • pp.45-47
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    • 2005
  • We have investigated the mixing behavior of a tubular heat exchanger reactor using CFD and compared its mixing performance with different type of reactors such as jet mixer and continuous stirred tank reactor (CSTR). The mixedness in each reactor was quantified introducing a statistical average value, the coefficient of variation (CoV), which is a normalized standard deviation of concentration of a component over the whole fluid domain. Through the analysis of the flow pattern and turbulent energy distribution, we suggested a simple but effective way to improve the mixing performance of the tubular heat-exchanger reactor, which include the addition of the internals and/or the increase of the recycle flow rate. It was found that the CoV value of the tubular reactor could be nearly equivalent to that of CSTR by applying those two alternatives suggested here.

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