• 제목/요약/키워드: steam-explosion

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폭쇄법을 이용한 목질계 바이오매스의 종합적 이용 (III) - 소나무와 신갈나무 폭쇄재로부터 셀룰로오스 아세테이트의 제조 - (Total Utilization of Woody Biomass by Steam Explosion (III) - The Preparation of Acetate from Pine and Oak Exploded Wood -)

  • 이종윤;장준복;양재경
    • Journal of the Korean Wood Science and Technology
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    • 제23권2호
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    • pp.26-31
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    • 1995
  • Acetylcellulose(AC) was prepared with steam exploded wood(EXW) and EXW after delignification with sodium chlorite, pine (Pinus densiflora) and oak (Quercus mongolica) woods. The color of acetylated pine and oak exploded wood was brown, degree of substitution(D.S) of pine was 1.47~2.09, and this of oak was 1.49~2.29. The hemicellulose content of acetylated pine and oak exploded wood was 0~3.4% and 1.49~11.3%, individually. The degree of substitution of acetylated wood prepared from delignified EXW in the pine and oak wood was 0.50~0.71 and 0.70~0.88, individually. Hemicellulose content of acetylated EXW with sodium chlorite after delignification in the pine and oak wood was less than 1% and 0.6~2.5%. The color of acetylated wood after delignification was white. IR-spectra of acetylated pine and oak EXW after delignification were found that peaks at around 1740$cm^{-1}$ and 1200$cm^{-1}$ increase markedly, due to ester carbonyl group.

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Modeling of Reinforced Concrete for Reactor Cavity Analysis under Energetic Steam Explosion Condition

  • Kim, Seung Hyun;Chang, Yoon-Suk;Cho, Yong-Jin;Jhung, Myung Jo
    • Nuclear Engineering and Technology
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    • 제48권1호
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    • pp.218-227
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    • 2016
  • Background: Steam explosions may occur in nuclear power plants by molten fuel-coolant interactions when the external reactor vessel cooling strategy fails. Since this phenomenon can threaten structural barriers as well as major components, extensive integrity assessment research is necessary to ensure their safety. Method: In this study, the influence of yield criteria was investigated to predict the failure of a reactor cavity under a typical postulated condition through detailed parametric finite element analyses. Further analyses using a geometrically simplified equivalent model with homogeneous concrete properties were also performed to examine its effectiveness as an alternative to the detailed reinforcement concrete model. Results: By comparing finite element analysis results such as cracking, crushing, stresses, and displacements, the Willam-Warnke model was derived for practical use, and failure criteria applicable to the reactor cavity under the severe accident condition were discussed. Conclusion: It was proved that the reactor cavity sustained its intended function as a barrier to avoid release of radioactive materials, irrespective of the different yield criteria that were adopted. In addition, from a conservative viewpoint, it seems possible to employ the simplified equivalent model to determine the damage extent and weakest points during the preliminary evaluation stage.

폭쇄처리(爆碎處理)된 목질계(木質系) Biomass의 산소가수분해(酸素加水分解)(I) -리그닌의 함량(含量)과 섬유소(纖維素)의 결정화도(結晶化度)가 산소가수분해(酸素加水分解)에 미치는 영향 (The Enzymatic Hydrolysis of Exploded Woody Biomass(I) -Effects of Lignin Contents and Cellulose Crystallinity on the Enzymatic Hydrolysis-)

  • 박영기;오정수
    • Journal of the Korean Wood Science and Technology
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    • 제21권3호
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    • pp.53-60
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    • 1993
  • Substrates used were hardwood-Suwon poplar-(Populus alba${\times}$glandulosa L.) and softwood-pitch pine-(Pinus rigida M.). And these substrates were steam exploded then treated with sodium chlorite at 75$^{\circ}C$ with occasional stirring in order to obtain samples which had different lignin contents and crystallinity. And then this resulting samples incubated with a commercial cellulase derived from Trichoderma ressei. The contents of Klason lignin were decreased as the increasing of the ratio of sodium chlorite in the two species. The effect of hardwood was more effective than that of softwood in the same ratio of sodium chlorite. The minimum contents of Klason lignin were 0.8% and 5.1% respectively. And the crystallinities of cellulose were increased very little as increasing of the ratio of sodium clorite. The hydrolysis extent of the two species were increased as the increasing of delignification. Especially, the hydrolysis extent of hardwood was more higher than that of softwood. The maximum hydrolysis extent were 89.8% and 71.1%, respectively.

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공랭식 응축기 관내 응축수 동결 방지에 관한 연구 (Preventing Freezing of Condensate inside Tubes of Air-Cooled Condenser)

  • 주정아;황인환;조영일;이동환
    • 대한기계학회논문집B
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    • 제36권8호
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    • pp.811-819
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    • 2012
  • 공랭식 응축기는 대기중의 공기를 이용해 스팀을 응축수로 전환시키는 발전용 냉각설비이다. 추운 겨울철, 공랭식 응축기는 열교환부 관내의 응축수가 동결되어 튜브 자체가 터지는 심각한 동파 문제를 수반한다. 이는 기존 공랭식 응축기 시스템이 가지는 튜브 출구의 구조적 문제로 인한 응축되지 않은 스팀 및 비응축성 기체의 역류가 주요 원인이 된다. 따라서 본 연구에서는 유사 모의 공랭식 응축기 시스템을 설계 및 제작하여 기존의 공랭식 응축기 시스템이 가지고 있는 문제점을 구현하고, 이를 해결하기 위한 설계가 가능함을 실험적으로 증명하였다. 기존 공랭식 응축기 시스템의 작동 원리와 유사한 조건에서 실시한 실험에서 역류에 의한 튜브 동결을 관찰할 수 있었다. 반면 신개념 공랭식 응축기 시스템을 적용한 실험에서는 역류 및 동결 발생없이 열교환이 잘 이루어짐을 확인할 수 있었다.

농산 및 임산폐자원의 xylan을 이용한 기능성 물질 생산(I) - Xylan의 단리 및 정제 - (Manufactures of Functional Materials by Using Xylan from Agricultural & Forest Residues(I) - The Isolation and Purification of Xylan -)

  • 변지혜;임부국;양재경;장준복;이종윤
    • Journal of the Korean Wood Science and Technology
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    • 제28권3호
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    • pp.25-33
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    • 2000
  • 본 연구는 농산 및 임산폐자원을 폭쇄처리한 후 xylan을 단리하기 위한 최적의 방법과 조건을 확립하기 위해 수행하였다. 농산 및 임산폐자원으로는 볏짚, 보릿짚 및 신갈나무를 시료로 하였다. 농산 및 임산폐자원의 화학 조성을 살펴보면, 볏짚 및 보릿짚에서의 추출물 함량과 무기물 함량은 신갈나무보다 약 10~20% 정도 높게 나타났다. 폭쇄전처리는 20kgf/$cm^2$의 압력에서 3, 6분처리 하였다. 폭쇄처리된 시료의 리그닌 함량은 폭쇄처리 전보다 약 3~22% 정도 높게 났다. 열수 및 0.5% 수산화칼륨 용액 추출에 의한 xylan 단리를 시도하였다. 열수 및 0.5% 수산화칼륨 용액 추출에 의해서 단리된 xylan의 형태를 살펴보면, 열수추출로 단리된 xylan은 소당류 형태로 존재하고 있음을 확인할 수 있었다. 1차적으로 열수 및 0.5% 수산화칼륨 용액으로 단리된 xylan을 5% 수산화바륨 용액과 에탄올 적하법으로 정제를 시도하였다. 최종적으로 정제된 xylan의 xylose 함량은 약 85% 이상이었지만, 기타의 당류들이 존재하였다.

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목질계 바이오에탄올 제조공정에서 열화학적 전처리에 관한 고찰 (A review on thermochemical pretreatment in Lignocellulosic bioethanol production)

  • 고재중;윤상린;강성원;김석구
    • 유기물자원화
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    • 제16권1호
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    • pp.79-88
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    • 2008
  • 지구온난화에 따른 대체연료의 하나로 바이오에탄올의 생산이 증대되면서 곡물가격 상승과 같은 문제를 야기하고 있다. 차세대 바이오에탄올의 원료로서 목질계 바이오매스는 큰 잠재성에도 불구하고 높은 생산단가로 인하여 상업화 되지는 않고 있다. 생산단가의 절감을 위해 필요한 핵심기술은 가수분해율을 높이고 단당의 회수율을 높이는 것으로 전체 바이오에탄올 생산공정에서 열화학적 전처리이다. 본 연구에서는 목질계 바이오에탄올 제조공정에서의 열화학적 전처리에 대하여 소개하고 극복해야 할 문제들에 대하여 제시하고자 한다. 산, 알칼리, 열수, 용매, 암모니아, 산소 등을 첨가하는 전처리는 리그닌과 헤미셀룰로오스를 제거하고 셀룰로오스의 결정성을 감소시킨다. 이러한 전처리 방식들은 침엽수, 활엽수, 곡식의 줄기 등 목질계 원료에 따라 최적의 처리 조건들이 확립되어져야 한다.

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우도응회과의 분출기기구와 분출과정 (Eruptive mechanisms and processes at Udo tuff cone, Udo Island, Korea)

  • Hwang, Sang-Koo
    • 암석학회지
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    • 제1권2호
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    • pp.91-103
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    • 1992
  • Eruptive mechanisms and processes at Udo tuff cone can be inferred from indicative characters of products, bedforms and lithofacies, and ring faults. In terms of bedforms and lithofa-cies in particular, massive lapilli tuff beds and chaotic lapilli tuff beds are derived from subaerial falls of aggregated tephra of wet tephra finger jets, occurring dominantly at the lower sequences of proximal part at the tuff cone. Crudely stratified lapilli tuff are derived from subaerial falls of slightly aggregated tephra of less wet tephra finger jets, whereas reversely graded lapilli tuff beds are from slightly disaggregated subaerial falls of continuous uprush. Both beds frequently occur in the middle sequences at proximal and near medial part of the tuff cone. Block and lapilli tephra lenses, ash-coated lapilli tephra beds(lenses) and thin-bedded tuff beds are derived from extremely disaggregated subaerial falls of dry tephra in the continuous uprush, frequently occurring at the upper sequences of medial part at the tuff cone. Udo tuff cone is a basaltic volcano emergent through the sea water surface while water could flood across or into the vent area. Emergence of the tuff cone was from the type-Surtseyan eruption characterized by earlier tephra finger jets and later continuous uprush columns of tephra with copious volumes of steam. Explosions began when boiling of wter produced a bubble column reducing the hydrostatic pres-sure, allowing exsolution of gases from the magma. This expansion of magma into a vesiculating froth fragmented the magma and permitted mixing of magma and water so that a more vigorous generation of steam could proceed. Tephra finger jetting explosions continued to build the crater rims, then remove water from the vent that their deposits flowed like slsurries until the continuous uprush explosion ensued. Continuous uprush explosions were associated with most rapid accumula-tion of tephra. The increasing volume rate led to partial removal of water from the vent area by the newly tephra ring so that more vigorous activity could be attended by a reducing water supply. This might restrain surplus of cold water entering the vent and thus enhance the vigour of the eruption by allowing optimal heat exchange. Eventually the crater became so deep and unsuported that piecemeal sliding, or massive subsidence on indipping ring faults, filled and closed the vent, and the cycle of explosions and collapse began anew.

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The Effect of Wood Extract as a Water-Soluble Fertilizer in the Growth of Lactuca sativa

  • JUNG, Ji Young;HA, Si Young;YANG, Jae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • 제49권4호
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    • pp.384-393
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    • 2021
  • Recently, due to environmental and toxicity issues, there has been increasing attention on research regarding natural products that can reduce the use of chemical fertilizers. Wood extracts derived from the biorefining process contain various fertilizer ingredients. HPLC analysis revealed that wood extract contains approximately 5.2% hemicellulosic sugar. The growth of lettuce (Lactuca sativa) upon treatment with wood extract (extract obtained from steam-exploded pine) or water-soluble fertilizers containing different nutrients was analyzed in this study. After two weeks, the growth characteristics of lettuce as affected by wood extract or water-soluble fertilizers were significantly different. The effect of water-soluble fertilizers containing ascorbic acid, magnesium sulfate, citric acid, potassium nitrate, amino acids, or seaweed extract was less desirable than that of wood extracts regarding plant height (18.6 cm), number of leaves (10), leaf length (14.1 cm), shoot fresh wight (9.8 g/plant), root fresh weight (0.8 g/plant) and shoot dry weight (0.6 g/plant). The plant height, number of leaves, leaf length, shoot fresh wight, root fresh weight, shoot dry weight of water-soluble fertilizers containing wood extract were significantly different compared to the control (plant height :13.5 cm, number of leaves : 7, leaf length : 9.4 cm, shoot fresh wight : 5.3 g/plant, root fresh weight : 0.7 g/plant, shoot dry weight : 0.4 g/plant, root dry weight : 0.07 g/plant). From these results, it was concluded that wood extract can be used as a potential water-soluble fertilizer to increase the yield of leafy vegetables.

석탄화력발전소 보일러 연료제어 알고리즘과 분산제어시스템의 개발 (The Development of Boiler Fuel Control Algorithm and Distributed Control System for Coal-Fired Power Plant)

  • 임건표;이흥호
    • 전기학회논문지P
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    • 제62권1호
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    • pp.36-44
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    • 2013
  • This paper is written for the development and application of boiler fuel control algorithm and distributed control system of coal-fired power plant by the steps of design, coding, simulation test, site installation and site commissioning test. Fuel control algorithm has the upper algorithm and it is boiler master control algorithm that controls the fuel, feed water, air by generation output demand. Generation output demand by power load influences fuel control. Because fuel can not be supplied fast to the furnace of boiler, fuel control algorithm was designed adequately to control the steam temperature and to prevent the explosion of boiler. This control algorithms were coded to the control programs of distributed control systems which were developed domestically for the first time. Simulator for coal-fired power plant was used in the test step. After all of distributed control systems were connected to the simulator, the tests of the actual power plant were performed successfully. The reliability was obtained enough to be installed at the actual power plant and all of distributed control systems had been installed at power plant and all signals were connected mutually. Tests for reliability and safety of plant operation were completed successfully and power plant is being operated commercially. It is expected that the project result will contribute to the safe operation of domestic new and retrofit power plants, the self-reliance of coal-fired power plant control technique and overseas business for power plant.

Protective Effect of Oak Extracts on Oxidative Stress Induced by Hydrogen Peroxide

  • Nam, Jeong Bin;Park, Hyung Bin;Jung, Ji Young;Yang, Jae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • 제42권5호
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    • pp.523-532
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    • 2014
  • This study was done to evaluate the antioxidant effect of oak hot water extracts on the oxidative stress induced by reactive oxygen species (ROS). The cytotoxicity of $H_2O_2$-induced oxidative stress was performed by 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide (MTT) assay for the cell viability according to the dose-dependent treatment. Oak extracts demonstrated a dose-dependent ability to inhibit $H_2O_2$-induced apoptosis in cultured tenofibroblasts, as assessed by MTT assay and FACS analysis. $H_2O_2$ increased the phosphorylation of extracellular regulated kinase1/2 (ERK1/2) and of c-Jun N-terminal kinase (JNK) and the production of reactive oxygen species (ROS). In contrast, treatment with oak extracts was decreased this activation of ERK1/2 and JNK, as confirmed by western blot analysis, and reduced the production of ROS, as verified by fluorescent microscopic and flow cytometry (FACS) analyses. These findings suggest that oak extracts, by suppressing JNK, ERK1/2, and intracellular ROS production, have a concentration-dependent antiapoptotic effect on achilles tenofibroblasts exposed to an oxidative stressor, and may have therapeutic potential.