• Bulletin of the Korean Chemical Society
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• 제19권9호
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• pp.934-942
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• 1998

$^13CO$ chemisorbed on platinum particles in L-zeolite has been investigated by static and magic angle spinning NMR spectroscopy. The representative spectra are composed of a broad asymmetric peak with a center of gravity at 230±30 ppm and a sharp symmetric peak at 124±2 ppm which is tentatively assigned to physisorbed $CO_2$, on inner walls of L-zeolite. Overall, the broad resonance component is similar to our previous results of highly dispersed (80-96%) CO/Pt/silica or CO/Pt/alumina samples, still showing metallic characters. The principal difference is in the first moment value. The broad peak in the spectra is assigned to CO linearly bound to Pt particles in the L-zeolites, and indicates a distribution of isotropic shifts from bonding site to bonding site. The NMR results reported here manifest that the Pt particles inside of the L-zeolites channels are not collectively the same with the ones supported on silica or alumina with similar dispersion in terms of Pt particle shape and/or ordering of Pt atoms in a particle. As a result, Pt particles of CO/Pt/L-zeolite were agglomerated accompanying CO desorption upon annealing. There were no definite changes in the NMR spectra due to differences of exchanged cations. Comparison of our observation on CO/Pt/L-zeolite with Sharma et al.'s reveals that even when the first moment, the linewidtb, and the relaxation times of the static spectra and the dispersion measured by chemisorption are similar, the properties of Pt particles can be dramatically different. Therefore, it is essential to take advantage of the strengths of several techniques together in order to interpret data reliably, especially for the highly dispersed samples.

• Earthquakes and Structures
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• 제26권2호
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• pp.131-147
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• 2024

Damage caused by an earthquake depends on not just the intensity of an earthquake but also the region-specific construction practices. Past earthquakes in Asian countries have highlighted inadequate construction practices, which caused huge life and property losses, indicating the severe need to strengthen existing structures. Strengthening activities shall be proposed as per the proposed weighting factors, first at the higher weighted members to increase the capacity of the building immediately and thereafter, the other members. Through this study on gravity load-designed (GLD) buildings, relative weights are assigned to each storey and exterior and interior columns within a storey based on their contribution to the energy dissipation capacity of the building. The numerical study is conducted on mid-rise archetype GLD buildings, i.e., 4, 6, 8, and 10 stories with variable storey heights, in the high seismic zones. Non-linear static analysis is performed to compute weights based on energy dissipation capacities. The results obtained are verified with the non-linear time history analysis of 4 GLD buildings. It was observed that exterior columns have higher weightage in the energy dissipation capacity of the building than interior columns up to a certain building height. The damage in stories is distributed in a convex to concave parabolic shape from bottom to top as building height increases, and the maxima location of the parabola shifts from bottom to middle stories. Relative weighting factors are assigned as per the damage contribution. And the sequence for strengthening activities is proposed as per the computed weighting factors in descending order for regular RCC buildings. Therefore, proposals made in the study would increase the efficacy of strengthening activities.

• 한국정보통신학회논문지
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• 제9권4호
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• pp.772-776
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• 2005

최근 급속히 증가하는 데이터 트래픽을 지원할 수 있도록 네트웍을 관리해야 할 뿐만 아니라 안정적인 인프라를 유지하기 위해 트래픽 엔지니어링을 지원할 수 있는 MPLS가 필요하게 되었다. 트래픽 엔지니어링은 대규모 사용자가 트래픽을 네트웍 상의 특정 노드를 지나는 사전 지정된 경로로 이동시키는 방법으로 트래픽 플로우를 물리적인 네트웍 토폴로지에 매핑시키는 작업이라고 할 수 있다. 본 논문에서는 기존 RSVP의 트래픽 엔지니어링의 단점을 보완하고 보다 안정된 인프라를 구축하기 위해 ERSVP 시그널링 프로토콜에 대한 진화방향을 제시하고져 한다.

• Applied Science and Convergence Technology
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• 제23권4호
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• pp.192-199
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• 2014

The electronic property of graphene was investigated by hydrazine treatment. Hydrazine ($N_2H_4$) highly increases electron concentrations and up-shifts Fermi level of graphene based on significant shift of Dirac point to the negative gate voltage. We have observed contact resistance and channel length dependent mobility of graphene in the back-gated device after hydrazine monohydrate treatment and continuously monitored electrical characteristics under Nitrogen or air exposure. The contact resistance increases with hydrazine-treated and subsequent Nitrogen-exposed devices and reduces down in successive Air-exposed device to the similar level of pristine one. The channel conductance curve as a function of gate voltage in hole conduction regime keeps analogous value and shape even after Nitrogen/Air exposure specially whereas, in electron conduction regime change rate of conductance along with the level of conductance with gate voltage are decreased. Hydrazine could be utilized as the highly effective donor without degradation of mobility but the stability issue to be solved for future application.

• 한국정보통신학회:학술대회논문집
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• 한국해양정보통신학회 2005년도 춘계종합학술대회
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• pp.105-108
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• 2005

최근 급속히 증가하는 데이터 트래픽을 지원할 수 있도록 네트웍을 관리해야 할 뿐만 아니라 안정적인 인프라를 유지하기 위해 트래픽 엔지니어링을 지원할 수 있는 MPLS가 필요하게 되었다. 트래픽 엔지니어링은 대규모 사용자가 트래픽을 네트웍 상의 특정 노드를 지나는 사전 지정된 경로로 이동시키는 방법으로 트래픽 플로우를 물리적인 네트웍 토폴로지에 매핑시키는 작업이라고 할 수 있다. 본 논문에서는 기존 RSVP의 트래픽 엔지니어링의 단점을 보완하고 보다 안정된 인프라를 구축하기 위해 ERSVP 시그널링 프로토콜에 대한 진화방향을 제시하고져 한다.

• 지능정보연구
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• 제9권3호
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• pp.23-47
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• 2003

전통적인 고객관계관리 연구는 특정 시점에서 고객관계관리에 중점을 두어 연구되었다. 이러한 정적인 고객관계관리와 고객 행동에 관한 지식은 마케팅 관리자가 제한된 마케팅 자원을 이익의 극대화를 위해 사용할 수 있게 해주었다. 그러나 시간이 경과하게 되면 이러한 정적인 지식은 쓸모가 없어지게 된다. 그러므로 고객관계관리는 고객의 동적 특성을 반영해야 한다. 과거 고객의 구매 행위를 관찰하여 현재 또는 미래 시장의 고객을 세분화하며 구분된 고객 군집에 대해 서로 다른 마케팅 전략을 사용할 수 있다. 고객의 구매행동을 근간으로 한 고객관계관리는 수십 년 전부터 연구되어왔지만 동적인 고객관계관리에 대한 연구는 최근에 들어와서야 활발하게 진행되고 있다. 본 논문은 인터넷 상점의 고객 데이터로부터 추출된 지식과 시간 경과에 따른 고객 행동 패턴의 분석을 위해 데이터마이닝과 모니터링 에이전트 시스템(MAS)을 이용하며, 이를 통한 동적인 고객관계관리 모델을 제시한다. 이 모델은 고객이력경로에 대한 예측과 고객에게 나타나는 집단이력경로의 분석, 그리고 시간 경과에 따른 고객 군집의 변화에 대한 분석과 그에 따른 마케팅 전략 도출을 포함한다. 이 모델의 제안은 많은 온라인 소매상이 직면하고 있는 경영상의 문제를 해결하는데 유용할 것이다.

• 유통과학연구
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• 제14권1호
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• pp.93-102
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• 2016

Purpose - The purpose of paper is studying the static and dynamic side for long-term memory storage properties, and increase the explanatory power regarding the long-term memory process by looking at the long-term storage attributes, Korea Composite Stock Price Index. The reason for the use of GPH statistic is to derive the modified statistic Korea's stock market, and to research a process of long-term memory. Research design, data, and methodology - Level shifts were subjected to be an empirical analysis by applying the GPH method. It has been modified by taking into account the daily log return of the Korea Composite Stock Price Index a. The Data, used for the stock market to analyze whether deciding the action by the long-term memory process, yield daily stock price index of the Korea Composite Stock Price Index and the rate of return a log. The studies were proceeded with long-term memory and long-term semiparametric method in deriving the long-term memory estimators. Chapter 2 examines the leading research, and Chapter 3 describes the long-term memory processes and estimation methods. GPH statistics induced modifications of statistics and discussed Whittle statistic. Chapter 4 used Korea Composite Stock Price Index to estimate the long-term memory process parameters. Chapter 6 presents the conclusions and implications. Results - If the price of the time series is generated by the abnormal process, it may be located in long-term memory by a time series. However, test results by price fixed GPH method is not followed by long-term memory process or fractional differential process. In the case of the time-series level shift, the present test method for a long-term memory processes has a considerable amount of bias, and there exists a structural change in the stock distribution market. This structural change has implications in level shift. Stratum level shift assays are not considered as shifted strata. They exist distinctly in the stock secondary market as bias, and are presented in the test statistic of non-long-term memory process. It also generates an error as a long-term memory that could lead to false results. Conclusions - Changes in long-term memory characteristics associated with level shift present the following two suggestions. One, if any impact outside is flowed for a long period of time, we can know that the long-term memory processes have characteristic of the average return gradually. When the investor makes an investment, the same reasoning applies to him in the light of the characteristics of the long-term memory. It is suggested that when investors make decisions on investment, it is necessary to consider the characters of the long-term storage in reference with causing investors to increase the uncertainty and potential. The other one is the thing which must be considered variously according to time-series. The research for price-earnings ratio and investment risk should be composed of the long-term memory characters, and it would have more predictability.

• Journal of Mechanical Science and Technology
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• 제18권2호
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• pp.185-192
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• 2004

The aeroacoustic characteristics of a centrifugal fan for a vacuum cleaner and its noise reduction method are studied in this paper. The major noise source of a vacuum cleaner is the centrifugal fan. The impeller of the fan rotates at over 30000 rpm, and generates very high-level noise. It was revealed that the dominant noise source is the aerodynamic interaction between the rotating impeller and stationary diffuser. The directivity of acoustic pressure showed that most of the noise propagates backward direction of the fan-motor assembly. In order to reduce the high tonal sound generated from the aerodynamic interaction, unevenly pitched impeller and diffuser, and tapered impeller designs were proposed and experiments were performed. Uneven pitch design of the impeller changes the sound quality while the overall sound power level (SPL) and the performance remains similar. The effect of the tapered design of impeller was evaluated. The trailing edge of the tapered fan is inclined. This reduces the flow interaction between the rotating impeller and the stationary diffuser because of some phase shifts. The static efficiency of the new impeller design is slightly lower than the previous design. However, the overall SPL is reduced by about 4 dB(A). The SPL of the fundamental blade passing frequency (BPF) is reduced by about 6 dB (A) and the 2$\^$nd/ BPF is reduced about 20 dB (A). The vacuum cleaner with the tapered impeller design produces lower noise level than the previous one, and the strong tonal sound was dramatically reduced.

• Structural Engineering and Mechanics
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• 제89권6호
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• pp.617-626
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• 2024

The study investigated the behavior of plain and fibered Ultra-High Performance Concrete (UHPC) beams under varying loading conditions using integrated analysis of the flexure and acoustic emission tests. The loading rate of testing is -0.25 -2 mm/min. It is observed that on increasing loading rate, flexural strength increases, and toughness decreases. The acoustic emission testing revealed that higher loading rates accelerate crack propagation. Fiber effect and matrix cracking are identified as significant contributors to the release of acoustic emission energy, with fiber rupture/failure and matrix cracking showing rate-dependent behavior. Crack classification analysis indicated that the rise angle (RA) value decreased under quasi-static loading. The average frequency (AF) value increased with the loading rate, but this trend reversed under rate-dependent conditions. K-means analysis identified distinct clusters of crack types with unique frequency and duration characteristics at different loading rates. Furthermore, the historic index and signal strength decreased with increasing loading rate after peak capacity, while the severity index increased in the post-peak zone, indicating more severe damage. The sudden rise in the historic index and cumulative signal strength indicates the possibility of several occurrences, such as the emergence of a significant crack, shifts in cracking modes, abrupt failure, or notable fiber debonding/pull-out. Moreover, there is a distinct rise in the number of AE knees corresponding to the increase in loading rate. The crack mapping from acoustic emission testing aligned with observed failure patterns, validating its use in structural health monitoring.

• 지구물리와물리탐사
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• 제19권1호
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• pp.11-19
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• 2016

나머지 정적보정 기법중에서 가장 많이 쓰이는 주행시간 분해기법과 겹쌓기제곱 최대화기법의 적용성을 육상 탄성파자료에서 비교 검토하였다. 모든 발파점과 수신점에 대한 임의의 나머지 정적보정값(시간차이)과 무작위 잡음이 포함된 모델자료에서 겹쌓기제곱 최대화기법은 주행시간 분해기법에 비해 흐트러진 반사 이벤트를 정확히 정렬시키고 보정과정에서 출력된 발파점과 수신점의 정적보정 그래프가 입력된 값과 거의 같은 진폭으로 역전된다는 점에서 신호대잡음이 작은 자료의 반사면 향상에 보다 효과적이었다. 나머지 정적보정에 적합한 입력인자(최대허용 시간차이, 상관창, 반복횟수)들은 공통중간점 자료외에 공통발파점 겹쌓기자료와 공통수신점 겹쌓기자료에 대한 연속 테스트를 거쳐 효과적으로 진단할 수 있었다. 나머지 정적보정에 앞서 송수신점의 높이보정 및 풍화대 깊이보정을 실시하여 장파장 시간차이를 제거하고 진동수-파수 필터링, 예측곱풀기, 시간변화 빛띠흰색화로 잡음을 줄여 교차상관의 오차를 최소화시킨다. 또한 나머지 정적보정후 수직시간차 역보정을 거쳐 속도를 재분석하여 겹쌓기한 결과 저류층을 포함한 반사면들의 향상된 연속성 및 분해능을 확인할 수 있었다.