• Title/Summary/Keyword: static contact angle

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Improvement on Interfacial, Thermal, and Water Resistance Properties of Wood Sandwich Composites for Stone Bed using CNT-Animal Glue Adhesive (탄소나노튜브/아교 접착제를 이용한 돌침대용 목재 샌드위치 복합재의 계면, 열적 및 방수특성 증가)

  • Kim, Jong-Hyun;Kwon, Dong-Jun;Shin, Pyeong-Su;Baek, Yeong-Min;Park, Ha-Seung;Moon, Sun-Ok;Park, Joung-Man
    • Composites Research
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    • v.30 no.4
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    • pp.235-240
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    • 2017
  • Animal glue, a water-soluble adhesive, has been used historically for high-performance traditional furniture despite the disadvantage of weakness against moisture. Many scientists studied the ways to improve water resistance of animal glue. Improvements on the interfacial, thermal, and water resistance properties of wood sandwich composites (WSC) was studied with carbon nanotube (CNT) wt% in animal glue. Real-time temperature of WSC was measured after WSC was heated with increasing CNT wt%. Lap shear test was performed to determine the interfacial properties of wood and animal glue with CNTs. Water resistance properties of animal glue were determined by lap shear test using specimens dipped in water and the results were compared with the dry case. Hydrophobicity of animal glue by static contact angle was correlated with the variation of lap shear test. Interfacial, thermal, and water resistance properties for animal glue were improved with properly added CNTs.

Manufacturing and Mechanical Properties of Epoxy Fibers Spinning using Anhydride and Amine Hardeners (산 무수물계 및 아민계 경화제를 이용한 열경화성 에폭시 섬유 제조 및 물성)

  • Shin, Pyeong-Su;Kim, Jong-Hyun;Park, Ha-Seung;Baek, Yeong-Min;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.29 no.6
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    • pp.408-413
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    • 2016
  • Commonly-used polymers are manufactured as versatile forms. Furthermore, continuous polymer fibers are recently manufactured using nylon or aramid fiber. One of common epoxy was also used to make polymer fibers. Bisphenol-A type was used as base epoxy whereas amine and anhydride were used as hardeners. Epoxy fibers was cured by stepping up the temperature to maintain the shape of epoxy fiber. Surface energy was measured to confirm the degree of interfacial adhesion by modified static contact angle method. After mechanical properties were measured via fiber tensile test, the evaluation of fiber fracture was proceeded. Tensile strength of epoxy fiber using amine type hardener was higher as 138 MPa than anhydride case as 70 MPa. Fractured surface exhibited different failure patterns at the cross-section.

Cell Patterning on Various Substrates Using Polyelectrolyte Multilayer and Microstructure of Poly(Ethylene Glycol) (다양한 기판 위에서 고분자 전해질 다층 막과 폴리에틸렌글리콜 미세 구조물을 이용한 세포 패터닝 방법)

  • Shim, Hyun-Woo;Lee, Ji-Hye;Choi, Ho-Suk;Lee, Chang-Soo
    • Korean Chemical Engineering Research
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    • v.46 no.6
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    • pp.1100-1106
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    • 2008
  • In this study, we presented rapid and simple fabrication method of functionalized surface on various substrates as a universal platform for the selective immobilization of cells. The functionalized surface was achieved by using deposition of polyelectrolyte such as poly(allyamine hydrochloride) (PAH), poly(diallyldimethyl ammonium chloride) (PDAC), poly(4-ammonium styrene sulfonic acid) (PSS), poly(acrylic acid) (PAA) and fabrication of poly(ethylene glycol) (PEG) microstructure through micro-molding in capillaries (MIMIC) technique on each glass, poly(methyl methacrylate) (PMMA), polystyrene (PS) and poly(dimethyl siloxane) (PDMS) substrate. The polyelectrolyte multilayer provides adhesion force via strong electrostatic attraction between cell and surface. On the other hand, PEG microstructures also lead to prevent non-specific binding of cells because of physical and biological barrier. The characteristic of each modified surface was examined by using static contact angle measurement. The modified surface onto several substrates provides appropriate environment for cellular adhesion, which is essential technology for cell patterning with high yield and viability in the micropatterning technology. The proposed method is reproducible, convenient and rapid. In addition, the fabrication process is environmentally friendly process due to the no use of harsh solvent. It can be applied to the fabrication of biological sensor, biomolecules patterning, microelectronics devices, screening system, and study of cell-surface interaction.

The Optimization of Ozone Solubility and Half Life Time in Ultra Pure Water and Alkaline Solution on Semiconductor Wet Cleaning Process (반도체 습식 세정 공정 중 상온의 초순수와 염기성 수용액 내에서 오존의 용해도 최적화)

  • Lee Sang-Ho;Lee Seung-Ho;Kim Kyu-Chae;Kwon Tae-Young;Park Jin-Goo;Bae So-Ik;Lee Gun-Ho;Kim In-Jung
    • Journal of the Semiconductor & Display Technology
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    • v.4 no.4 s.13
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    • pp.19-26
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    • 2005
  • The process optimization of ozone concentration and half life time was investigated in ultra pure water and alkaline solutions for the wet cleaning of silicon wafer surface at room temperature. In the ultra pure water,. the maximum concentration (35 ppm) of ozone was measured at oxygen flow rate of 3 liters/min and ozone generator power over 60%. The half life time of ozone increased at lower power of ozone generator. Additive gases such as $N_2$ and $CO_2$ were added to increase the concentration and half life time of ozone. Although the maximum ozone concentration was higher with the addition of $N_2$ gas, a longer half life time was observed with the addition of $CO_2$. When $NH_4OH$ of 0.05 or 0.10 vol% was added in DI water, the pH of the solution was around 10. The addition of ozone resulted in the half life time less than 1 min. In order to maintain high pH and ozone concentration, ozone was continuously supplied in 0.05 vol% ammonia solutions. 3 ppm of ozone was dissolved in ammonia solutions. The static contact angle of silicon wafer surface became hydrophilic. The particle removal was possible alkaline ozone solutions. The organic contamination can be removed by ozonated ultra pure water and then alkaline solution containing ozone can remove the particles on silicon surface at room temperature.

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Hydrophobicity and Adhesion of SiO2/Polyurethane Nanocomposites Topcoat for Aircraft De-icing with Different Pre-curing Time (선경화 시간에 따른 항공기 De-icing용 나노실리카/폴리우레탄 복합재료 탑코트의 소수성 및 접착특성 평가)

  • Kim, Jong-Hyun;Shin, Pyeong-Su;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.33 no.6
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    • pp.365-370
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    • 2020
  • The icing formation at aircraft occur problems such as increasing weight of the body, fuel efficiency reduction, drag reduction, the error of sensor, and etc. The viscosity of polyurethane (PU) topcoat was measured at 60℃ in real time to set the pre-curing time. SiO2 nanoparticles were dispersed in ethanol using ultra-sonication method. The SiO2/ethanol solution was sprayed on PU topcoat that was not cured fully with different pre-curing conditions. Surface roughness of SiO2/PU nanocomposites were measured using surface roughness tester and the surface roughness data was visualized using 3D mapping. The adhesion property between SiO2 and PU topcoat was evaluated using adhesion pull-off test. The static contact angle was measured using distilled water to evaluate the hydrophobicity. Finally, the pre-curing time of PU topcoat was optimized to exhibit the hydrophobicity of SiO2/PU topcoat.

Interfacial Properties of Propylene Oxide Adducted Sodium Laureth Sulfate Anionic Surfactant (프로필렌 옥사이드를 부가한 소듐 라우레스 설페이트 음이온 계면활성제의 계면 특성에 관한 연구)

  • Jeong Min Lee;Ki Ho Park;Hee Dong Shin;Woo Jin Jeong;Jong Choo Lim
    • Applied Chemistry for Engineering
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    • v.34 no.3
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    • pp.264-271
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    • 2023
  • In this study, ASCO SLES-430 surfactant was synthesized by adducting 3 moles of ethylene oxide and 1 mole of propylene oxide to lauryl alcohol followed by a sulfation process, and the structure of the synthesized ASCO SLES-430 was elucidated by performing FT-IR, 1H-NMR and 13C-NMR analyses. Interfacial properties such as critical micelle concentration, static surface tension, emulsification index, and contact angle were measured, and environmental compatibility indices such as oral toxicity and skin irritation were also estimated for ASCO SLES-430. Both results were compared with ASCO SLES-226 and ASCO SLES-328 SLES surfactants possessing 2 moles and 3 moles of ethylene oxide, respectively. In particular, both foaming ability and foam stability were evaluated for ASCO SLES-430 and compared with ASCO SLES-226 and ASCO SLES-328, which have been widely used in detergent products, in order to test the potential applicability of ASCO SLES-430 in detergent product formulation for a small capacity built-in washing machine.