• Bulletin of the Korean Chemical Society
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• v.22 no.8
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• pp.842-846
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• 2001

Solvolyses of N-methyl-N-phenylcarbamoyl chlorides in aqueous binary mixtures of acetone, ethanol, methanol and in water, D2O, and 50% D2O-CH3OD are investigated at 25.0 $^{\circ}C.$ The Grunwald-Winstein plots of first-ord er rate constants for N-methyl-N-phenylcarbamoyl chlorides with YCl (based on 2-adamantyl chloride) show a dispersion phenomenon. The ring parameter (I) has been shown to give considerable improvement when it is added as an hI term to the original Grunwald-Winstein and extended Grunwald-Winstein correlations for the solvolyses of N-methyl-N-phenylcarbamoyl chlorides. This study has shown that the magnitude of l, m and h values associated with a change of solvent composition is able to predict the dissociative SN2 transition state. The kinetic solvent isotope effects determined in deuterated water are consistent with the proposed mechanism of the general base catalyzed and/or a dissociative SN2 mechanism channel for N-methyl-N-phenylcarbamoyl chlorides solvolyses.

• Nuclear Engineering and Technology
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• v.18 no.2
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• pp.107-116
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• 1986

The steady and unsteady state models were established for the performance analysis and design of heavy water distillation columns packed with corrugated wire mesh. After the steady state model was derived with pressure drops, separated D$_2$O concentration and temperature profiles and pressure gradients in the column were obtained by solving MESH equations with equation tearing method. For the analysis of unsteady state behavior, the equilibrium stage transient model deduced from modifying the Cohen's ideal cascade equation was used to predict the concentration change of heavy water with time. These models were in good agreement with the experimental results of heavy water distillation at total reflux. And the newly developed packing material turned out to be very efficient separation device for very small HETP, pressure drop and holdup.

• Journal of Korea Water Resources Association
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• v.46 no.11
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• pp.1069-1078
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• 2013

The Bangudae Petroglyphs, national treasure No. 285 is located within submerged upper districts of Sayeon dam supplying the main residential water in Ulsan. Of the many ways for the reservation of Petroglyphs located the altitude at 53~57 m, the plan that we take it out of the water lowering the water level from 60 m to 52 m has been examined mainly in case of controlling artificially the water level of the dam. In this paper, we examined expected problems from the loss of dam function and the change of water quality from water deterioration caused by the water level control of the Sayeon dam. Using the model of Vollenweider and CSTR (Continuous Stirred Tank Reactor), we analyzed the density change of BOD and COD, representative water quality index and the TP and TN, the main reason of algae growth. The result showed that the density of COD lowered a little but the density of TP and TN went up over 130% when controlling the water level from 60 m to 52 m. These changes cause a serious algae problem and if doing the water quality management as the density of TN and TP, the water quality would become worse. Water storage and supply residential water decreases, and the water quality becomes worse because of eutrophic state.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.130-137
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• 1997

Intumescent inorganic and organic coatings which dintr one from the other by the type of gas formers and the mechanisms of foam formation have been obtained and investigated. Inorganic intumescent coatings are the compositions based on water glass and mineral additives with different dispersity. Mineral additives contain adsorbed and absorbed water and carbonates which are destructed with the carbon dioxide and water evolution during the flame action on coating. The decreasing of mineral additives particle sizes under the mechanical milling with the fraction precipitation promotes the foam coke formation with less defects. Here the main structure of comparing compositions does not change. In organic coatings based on epoxy-polymers the polyammonium phosphate additive is used. It is the cabonization catalyst and the foam agent. The polyammonium phosphate of various dispersity employed is uniformly distributed on the polymeric matrix. The decreasing of the particle sizes leads to the increasing of the fire resistant properties of the intumescent coa-ting. The fire resistant analysis of the coating during more than an hour: the coating back side the temperature on plastic or wooden materials does not exceed 423K, and on metal-573K.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.251-252
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• 2008

Si-Hwa tidal power station is using difference of the ebb and flow. The active power is dependent on up and down sea water level but if it is drastically changed because of a typhoon or waves the generator terminal voltage and active power is changed that is a chief cause of power station unstability. Therefore this paper arrange a present state of power or frequency fluctuation and generator terminal phase difference in case of occurrence a drastic change of sea water level.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.31 no.2 s.51
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• pp.135-140
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• 2005

A solid state emulsion haying high velocity gradient shows two important transition ranges in the plot of storage modulus(G') as a function of shear strain, when the state is changed from solid to liquid. However, a solid state emulsion having low velocity gradient shows only one apparent transition range when the change from solid to liquid state takes place. The result implies the importance of the surface properties in the solid state emulsion. The addition of water phase in the solid state emulsion reduces the modulus in the modulus in the surface transition range by increasing interfacial friction and weakening the matrix. The addition of pigments increases the modulus in the modulus in the surface transition range by reinforcing the matrix, when there is no wafer phase in the solid state emulsion. When the solid state emulsion has water phase, however, the addition of pigments decreases the modulus in the modulus in the surface transition range.

• Journal of Korean Society of Water and Wastewater
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• v.12 no.4
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• pp.59-69
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• 1998

Biological treatment systems generally can be divided into two main classes of a suspended sludge process and attached one like a fluidized bed reactor. These process are considered to bring remarkable change in species composition of microorganisms, due to difference of a state of biofilm, a concentration and diffusion velocity of dissolved oxygen, a concentration and diffusion velocity of substance or poisonous matter. The change of species composition bring different treatment result for influence factors like F/M ratio, DO concentration, pH or poisonous matter. This study is to investigate the reaction characteristics of both microorganisms, namely, a suspended sludge and attached sludge, through the changes of pH, temperature and substance concentration.

• Journal of The Korean Society of Agricultural Engineers
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• v.63 no.2
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• pp.1-10
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• 2021

Agricultural reservoirs have a great influence on the water circulation in the watershed. It is necessary to evaluate the impact on water circulation by the agricultural reservoir. Therefore, in this study, we simulated the agricultural watershed through linkage of Hydrological Simulation Program Fortran (HSPF) and Module-based hydrologic Analysis for Agricultural watershed (MASA) and evaluated the contribution of the agricultural reservoir to water circulation by watershed water circulation index. As a result of simulating the Idong reservoir watershed through the HSPF-MASA linkage model, the model performance during the validation period was R2 0.74 upstream, 0.78 downstream, and 0.76 reservoir water level, respectively. To evaluate the contribution of agricultural reservoirs, three scenarios (baseline, present state, and present state without reservoir) were simulated, and the water balance differences for each scenario were analyzed. In the evaluation through the agricultural water circulation rate in the watershed, it was found that the water circulation rate increased by 1.1%, and the direct flow rate decreased by 13.6 mm due to the agricultural reservoir. In the evaluation through the Budyko curve, the evaporation index increased by 0.01. Agricultural reservoirs reduce direct runoff and increase evapotranspiration, which has a positive effect on the water circulation.

• Proceedings of the Korea Water Resources Association Conference
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• 2006.05a
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• pp.1176-1181
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• 2006

The purpose of this study was to estimate water supply analysis and reliability indicators by using allocation rule(AR) about Andong Dam and Imha Dam which have parallel reservoirs system. According to the analysis results of allocation rule, for Rule(A) and Rule(B), the contribution of water supply in Andong Dam was 60% more than in Imha Dam, and for Rule(C), the contributions in Andong Dam and Imha Dam were almost equal. In Rule(C), supply is allocated by the ratio which divides the sum of storage and inflow by the mean storage according to the storage state and supply capability state of Andong Dam and Imha Dam. This Rule(C) showed good results in the water supply capability analysis and reliability analysis of parallel reservoirs. In the analysis criteria of water supply in parallel reservoirs system, monthly water change quantity showed better results than monthly constant water quantity in water supply analysis. On the basis of this study, the new technique for water supply analysis was developed to be applied to parallel reservoirs, and this operation rule will establish the efficient operation measures in the application to several kinds of parallel reservoirs system.

• Journal of Korean Society of Water and Wastewater
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• v.29 no.4
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• pp.469-479
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• 2015

This study have been conducted to analyze the feasibility of establishing Contamination Warning System(CWS) that is capable of monitoring early natural or intentional water quality accidents, and providing active and quick responses for domestic C_water supply system. In order to evaluate the water quality data set, pH, turbidity and free residual chlorine concentration data were collected and each statistical value(mean, variation, range) was calculated, then the seasonal variability of those were analyzed using the independent t-test. From the results of analyzing the distribution of outliers in the measurement data using a high-pass filter, it could be confirmed that a lot of lower outliers appeared due to data missing. In addition, linear filter model based on autoregressive model(AR(1) and AR(2)) was applied for the state estimation of each water quality data set. From the results of analyzing the variability of the autocorrelation coefficient structure according to the change of window size(6hours~48hours), at least the window size longer than 12hours should be necessary for estimating the state of water quality data satisfactorily.