• Title/Summary/Keyword: starch pulp

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A Study on the Accumulation Phenomena of Oxidized Starch in White Water of closed Fine Papermaking Process (Part 2) -Effect of broke use ratio and surface sizing pick up- (백상지 공정 폐쇄화에 따른 백수 내 산화전분의 축적 현상에 관한 연구 (제2보) -파지혼합비율 및 표면사이징 픽업량 변화의 영향-)

  • Ahn, Hyun-Kyun;Lee, Hak-Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.3
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    • pp.35-43
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    • 2004
  • Reduction of fresh water consumption and effluent discharge provide diverse advantages in raw materials and energy savings. Papermaking system closure, however, reduces the efficiency of additives, decreases retention and dewatering, and causes many other Problems in papermaking. Accumulation of inorganic and organic substances in the process white water is the prime cause of these problems. Understanding of the accumulation phenomena of the detrimental substances in the papermaking process is of great importance for papermaking system closure. In this study a process simulation method was employed to analyze the accumulation phenomena of anionic starch in the process white water as the reuse rate of dry broke and pick up of surface sizing agent is increased. Steady state simulation studies were carried out based on the model developed in previous study. The variation of dissolved starch concentration in each process unit was monitored as a function of reuse rate of dry broke and surface sizing agent pick up rate. The result showed that dissolved starch concentration Increased as reuse rate of dry broke and surface sizing agent pick up rate was increased.

Characteristics of Cationic Starches and Esterified Starches for ASA Sizing (ASA 유화용 양성전분과 에스테르화전분의 특성 평가)

  • Kim, Jong-Soo;Lee, Hak-Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.4
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    • pp.16-26
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    • 2008
  • It is of great importance to decrease sheet break at the size press to enhance the runnability of today's high speed paper machines. To achieve this purpose it is required to control the penetration of the starch solutions at the size press. Use of ASA sizing system provides diverse advantages in improving machine runnability since it allows us to get rapid sizing development at the size press. Domestic paper industries, however, has not enjoyed these benefits of ASA sizing system mainly because of the poor efficiency of domestic corn starches used for ASA emulsification. To improve the emulsion stability and ASA sizing efficiency, it has been pointed out that new cationic starches are needed. In this study two methods of starch modifications, i.e. esterfication of cationic corn starch with OSA (Octenyl Succinic Anhydride), and acid hydrolysis by sulfuric acid were employed as methods to improve ASA sizing efficiency. The effect of these modification was compared with conventional cationic starches.

Modification of Starch for Surface Sizing via Etherification and Esterification (에테르화 및 에스테르화를 통한 표면사이징용 변성 전분의 제조)

  • Jeong, Young Bin;Lee, Hak Lae;Youn, Hye Jung;Ji, Kyoung Rak;Kim, Young Seok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.6
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    • pp.50-55
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    • 2014
  • An oxidized starch was modified for surface sizing via etherification and esterification. Propylene oxide (PO), sodium monochloroacetate (SMCA), and acrylonitrile (AN) were used as etherification, and vinyl acetate monomer (VAM), maleic anhydride (MA), fumaric acid (FA), and itaconic acid (ITA) were used for esterification. Esterification and etherification of starch decreased both Brookfield viscosity and Brabender viscosity substantially even though the solids level was increased by 2% from 14 to 16%. Surface sizing performance of starches in tensile strength, stiffness and compressive strength was improved by esterification and etherification of the oxidized starch. Especially, SMCA etherification was found to be the most effective modification method.

Use of Waste Woods for Developing Environment-friendly Shock-absorbing Materials

  • Kim, Chul-Hwan;Song, Dae-Bin;Lee, Young-Min;Kim, Jae-Ok;Kim, Gyeong-Yun;Shin, Tae-Gi;Park, Chong-Yawl
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.475-478
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    • 2006
  • Environment-friendly shock-absorbing materials were made using a vacuum forming method from waste wood collected from local mountains in Korea. The waste wood was pulped by thermomechanical pulping. The TMP cushions showed superior shock-absorbing properties with lower elastic moduli compared to EPS and pulp mold. Even though the TMP cushions made using different suction times had many free voids in their inner fiber structure, their apparent densities were a little higher than EPS and much lower than pulp mold. The addition of cationic starch improved the elastic modulus of the TMP cushions without increasing the apparent density, which was different from surface sizing with starch. The porosity of the TMP cushions was a little greater than EPS and much less than pulp mold. Finally, the TMP cushions have great potential to endure external impacts occurring during goods distribution.

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Adsorption Behavior of Cationic Starches onto Deinked Pulp and Thermomechnical Pulp (탈묵펄프와 열기계펄프에 대한 양성전분 흡착 거동)

  • 허동명;이학래
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.2
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    • pp.42-49
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    • 1999
  • Although many researches have been made on the adsorption of cationic starches onto chemical pulp fibers, only limited studies have been reported for deinked pulp(DIP) and thermomechanical pulpI(TMP). In this experiment, the adsorption behavior of the cationic starches onto DIP and TMP fibers investigated. Almost complete adsorption of cationic starches onto the pulp fibers were observed when the addition rate of starch was low. Adsorption ratio decreased abruptly when 3.5% and 4.0% of cationic starches were adsorbed onto deinked pulp and thermomechanical pulp, respectively. Adsorption of cationic starches increased as the degree of substitution decreased and as the pH of the pulp slurry increased. TMP fibers adsorbed more cationic starches than DIP because of its greater charge density, and this led to greater improvement in strength properties for the TMP sheets.

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Manufacture of Multi-Layer Coated Paper with Eco-Friendly Starch Based Bio-Binder(1) - Application Possibility of Bio-Binder - (친환경 전분계 바이오 바인더를 이용한 다층 도공지 제조(제1보) - 바이오 바인더의 적용 가능성 -)

  • An, Guk Heon;Choi, Ki Soon;Won, Jong Myoung;Lee, Yong Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.5
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    • pp.32-38
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    • 2012
  • This study was carried out to elucidate the potential in substitution of SB latex with eco-friendly starch based bio-binder as a coating binder. The part of SB latex in coating color of pre- and top layer was substituted with starch based bio-binder in order to evaluate the characteristics of coating color and coated paper, and printability. The viscosity and water retention of coating color were increased by substitution of SB latex with starch based bio-binder. Roughness of coated paper was increased by substitution with starch based bio-binder, although there was not significant changes in roughness when SB latex is used as a binder in pre-coating color. Brightness and whiteness of coated paper were not affected, but opacity and print mottle were improved by substitution with starch based bio-binder. The interesting result observed was that dry-pick did not affected significantly, and ink set-off was improved by starch based bio-binder. It is expected that starch based bio-binder can be commercialized if the systematic further research works are carried out.

Retention Efficiency and Flocculation Mechanism of Microparticle Systems Based on Colloidal Silica (콜로이달 실리카에 의한 마이크로 파티클 시스템의 보류 효과 및 응집 기구)

  • 김향수;이학래
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.4
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    • pp.7-15
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    • 2002
  • It is of critical importance to understand the characteristics of papermaking additives and their reaction mechanisms to fully utilize the benefits they provide. Among the papermaking additives, retention aids play critical roles in improving productivity, product quality and process economy. Diverse research efforts to understand the reaction mechanisms between cationic polymers and anionic microparticles have been made since microparticle retention systems were introduced into the market. And it is most commonly accepted that flocs formed by the addition of cationic polymers are dispersed by shear force and the broken flocs are reflocculated instantly with the addition of microparticles. There are still many unanswered questions, however, on the reaction phenomena between cationic polymers and anionic microparticles. In this study, several cationic polymers including waxy maize starch, com starch and guar gum were used to investigate their retention efficiency when they were used along with anionic colloidal silica.

Manufacture of Antimicrobial Paper Using Food Preservative (식품보존제를 이용한 항균지 제조)

  • 이진호;이장호;박종문
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.2
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    • pp.81-86
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    • 2001
  • The functions of food packaging are not only prevention from physical damage and loss during carrying and transportation, but also extension of shelf-life by adding antimicrobial substrate in packaging materials. Consumption of active packaging is gradually increasing. With different dosage of potassium sorbate(P.S.), the food preservative agent, antimicrobial papers were made by internal and external application of starch. The antimicrobial action of the paper was analyzed by the halo test and the shake flask method. The mechanical properties and strength were also measured. Antimicrobial papers adding P.S. showed higher values in tensile index than adding starch. The antimicrobial paper using starch showed similar microbe decreasing rate as that using P.S. Though microbe decreasing rate was 21.9%, it showed possibility to make antimicrobial paper using food preservative.

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Effects of the Contaminants in Papermaking Process Water on Physical Properties of Paper (공정수 내의 오염물질이 종이의 물성에 미치는 영향)

  • 이학래;함충현;이지영
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.1
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    • pp.16-23
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    • 2004
  • Recently the increased concerns about the cost reduction and environmental protection make the paper industry increase the closure level of papermaking system, which results in the buildup of organic and inorganic materials in the papermaking process water. Increase of the system closure causes deterioration of additive performance and provokes diverse problems in papermaking process and product quality. To investigate the effects of process water quality on the physical properties of fine papers handsheets were prepared with process water containing various amounts of inorganic and organic contaminants including calcium or sodium ions and oxidized or cationic starches. Inorgainc and organic materials did not show any significant effect on the physical properties of handsheets. Recycled GCC showed the same trends as inorganic and organic materials. The performance of cationic starch was deteriorated, however, in the recycled white water, which resulted in the reduction of tensile index of handsheets.

Starch Treatment for the Improvement of Physical Properties of Hanji(I) - Effect of Starch Types - (한지의 강도적 성질 개선을 위한 전분류 처리(제1보) - 전분류별 처리효과 -)

  • 백옥례;윤승락
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.3
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    • pp.59-65
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    • 2003
  • This research was conducted to investigate the physical properties of Hanji made using maize, konyaku, and wheat powders at various concentrations. Regardless of the starch types, the most effective concentration to increase the physical properties of Hanji was 2 percent. They were significantly improved even at the treatment conditions of 0.1 percent. All the Hanji treated showed the increase of the breaking length, bust index, and tear index and the decrease of the folding number. The strength properties of the Hanji treated were markedly improved at 8 to 10 percent weight increase. The highest mechanical properties were found in the Hanji treated with konyaku powder.