• 한국의류산업학회지
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• 제3권2호
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• pp.174-179
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• 2001

This study investigated the effect of aftertreatments such as using the softener or starch on the mechanical properties of knitted fabrics. The mechanical properties of fabrics, hand value(HV) and total hand value(THV) were measured and calculated by the KES-F system. The main results are as follows: The values of tensile energy(WT), coefficient of friction(MIU) and geometrical roughness(SMD) were increased by softener but decreased by starch treatment. However, the values of tensile linearity(LT), bending(B, 2HB), thickness(T) and weight(W) were increased by starch but decreased by softener treatment. Tensile resilience(RT) was increased not only by softener but also by starch treatment. It showed that the levels of FUKURAMI, NUMERI and SOFUTOSA were increased by the treatment of softener and the levels of KOSHI and SHARI were increased by the treatment of starch. Total hand value(THV) was lower in fabric with starch treatment than fabric with none treatment.

• 한국식품위생안전성학회지
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• 제14권1호
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• pp.84-89
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• 1999

Octenylscuccinated corn starches prepared by reaction of corn starch with 1-octenylsuccinic anhydride(OSAn) and their degree of substitution (DS), reaction efficiency(RE), residual octenylsuccinic acid (OSA), and physicochemical properties were compared with those of the native corn starch. DS increased with increase of OSAn and RE was much nearly the same regardless of increased of OSAn. The content of residual of residual OSA was significantly lower than that of regulation of food additives. And as washing frequency of dispersion of the reactant was increased, the content of residual OSA of octenylsuccinated starch was decreased. Raid Visco-Analyzer initial pasting temperature and setback of octenylsuccinated starches decreased whereas peak viscosity and breakdown increased. When DS of octenylsuccinated starches increased, temperature of initial gelatinization of octenylscuccinated starches drastically decreased. The octenylsuccinated starches also formed clearer pastes. The solubility was much nearly the same regardless of increase of DS at 7$0^{\circ}C$ but the swelling power increased 1.2~1.7 times higher than that of native corn starch at 7$0^{\circ}C$. The water binding capacity of octenylsuccinated starches also decreased.

• 펄프종이기술
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• 제39권3호
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• pp.12-23
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• 2007

Frequently spraying of natural starch slurry onto the formed wet web has been adopted to improve properties of paperboards. This conventional starch spraying technique, however, becomes less effective in strength improvement. In this study the effects of various factors including wet web dryness, quantity of starch slurry sprayed, and drying temperature on paperboard properties were investigated. Migration of starch granules into the webs appeared to cause a reduction in plybond strength when the web dryness was lower than this level. Wet webs should contain enough water to swell the starch granules, and at the same time they should be heated to a temperature high enough for complete cooking of the sprayed starches to occur. This suggested that preheating of the wet web can be employed to improve the plybond strength.

• Composites Research
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• 제35권6호
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• pp.419-424
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• 2022

Using non-biodegradable polymers is a severe environmental problem as they are not recyclable and generate a large amount of waste. Biopolymers, such as starch-based composites, have been considered one of the most promising replacement materials. These eco-friendly materials have the advantage of being low-cost, biodegradable, and obtained from renewable sources. However, as starch tends to be brittle and hydrophilic, it can make these materials unusable when exposed to water and limit its processability for further applications. In this work, a biobased modified starch was grafted using two bioderived materials, lauryl methacrylate (LMA) and tetrahydrofurfuryl methacrylate (THFMA), by radical polymerization. A polylactic acid (PLA) composite based on the modified starch (m-St) was fabricated to enhance its toughness. These samples were characterized by Fourier transform infrared, ¹H NMR and ¹³C NMR analysis, optical and scanning electron microscopy. The starch was successfully grafted, thus improving the compatibility with the PLA matrix. The mechanical properties of these films were also studied. Results from mechanical tests showed a slight enhancement of the mechanical performance of these composites when m-St was added to the PLA matrix. Such behavior is related to the improved dispersion of m-St 1:2 on PLA, confirmed by SEM images showing enhanced compatibility between modified starch and PLA matrix. This indicated excellent properties of the produced composite film for further eco-friendly applications.

• Journal of Ginseng Research
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• 제9권2호
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• pp.270-284
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• 1985

In order to investigate the change of physicochemical properties of ginseng root starch during storage and heat treatment, the roots were stored for 15 days at 5 $^{\circ}C$, 15 $^{\circ}C$, 3$0^{\circ}C$ and 45$^{\circ}C$, and heated for 15 hours at 6$0^{\circ}C$, 7$0^{\circ}C$, 8$0^{\circ}C$, 9$0^{\circ}C$, respectively. The starch content was decreased from about 40% to 23-26% and sucrose content was increased from 4% to 12-16% during storage for 15 days at 5-45$^{\circ}C$. Maltose, which was not detected in fresh samples, was increased up to 8.5% during storage or heat treatment. Granular size of the starch was decreased and some of the granules were broken during storage. Amylose content in the starch was decreased from 33% to 20%, and blue value and alkali number of the starch were increased slightly, and solubility and swelling power of the starch were decreased during storage. 3 The higher storage temperature and the longer storage time, the starch was more susceptible to gelatinize, and the viscosity of the starch was lowered with the susceptibility of gelatinization. The susceptibility of degradation of the starch by the amylase was increased and amylolytic activities in ginseng root were, also, increased during storage.

• 펄프종이기술
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• 제41권5호
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• pp.1-7
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• 2009

Oxidized acetate starch was synthesized from corn oxidized starch and vinyl acetate. The sizing concentration and degree of substitution of modified starch on surface strength, smoothness and water resistance of the paper have been studied. The results showed that the surface strength, smoothness and other properties of paper sized by oxidized acetate starch is better than that of oxidized starch. When the degree of substitution of modified starch is from 0.04 to 0.14, the properties of paper sized by oxidized acetate starch have been improved more effectively.

• 펄프종이기술
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• 제45권4호
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• pp.52-64
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• 2013

This study was carried out to investigate the characteristics of starch paste which was used for the conservation of paper properties. Three kinds of commercial corn starch and five kinds of fermented wheat starch were examined on the contents of amylose and amylopectin, shapes of particles, and viscosity and pH of paste. And adhesive strength on the drying, accelerated aging, and wetting treatments were measured. The contents of amylopectin of oxidized corn starch were higher those of cationic corn starch, unmodified corn starch, and fermented wheat flour. In case of fermented wheat flour, increasing of a fermentation period was resulted in increasing of amylopectin contents. The particle shapes of commercial corn starch showed with a uniform polygon, but fermented wheat flour showed with a mixture of small and large oval types. The viscosity of oxidized corn starch were very lower those of cationic corn starch and unmodified corn starch. And increasing of a fermentation period of wheat flour was resulted in increasing of viscosity. The pH of commercial corn starch were 3.6-7.5 and fermented wheat flour were 3.6-5.2. Through the examination on the nature and adhesive strength of starch paste, the oxidized corn starch 60 cps which is the name of products and wheat flour which had fermented for 5 years were considered that most suitable for conservation of paper properties.

• 한국포장학회지
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• 제16권2_3호
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• pp.59-65
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• 2010

Starch was modified with epichlorohydrin(ECH) to improve the miscibility with LDPE and LLDPE. Native starch or epichlorohydrin treated starch was mixed with grycerol and LDPE/LLDPE resin using a kneader and extruded using a single screw extruder to make pallets. The pallets were compression-molded at 145 into composite boards to evaluate their color, oxygen permeation, mechanical and thermal properties, and degradability under UV irradiation. Sheets with epichlorohydrin treated starch generally showed higher L-value than that of native starch blend sheets. The hunter b-values in both native starch blends and epichlorohydrin treated starch blends increased with Increasing starch contents. Tensile strength and percent elongation of sheets decreased with increasing starch contents. Tensile strength and percent elongation of sheets decreased with increasing starch contents. The degradability of blends under UV radiation increased with increasing starch contents in both blend types. The results represents that crosslinking of starch with epichlorohydrin may be a good method to improve miscibility of starch with petroleum-based materials.

• 한국식품과학회지
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• 제34권6호
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• pp.1023-1029
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• 2002

본 연구는 천연전분과 hydroxypropyl화 전분에 가소제를 0, 16, 33, 50, 66% 비율로 첨가하여 RVA점도를 측정하고 필름을 제조한 후 물성을 측정하여 두 물성 사이의 상관관계를 알아보고자 행하였다. 필름의 인장강도는 가소제의 함량이 높아질수록 감소하였고 신장율과 수증기투과도는 증가하였으며 glycerol이 sorbitol보다 큰 변화를 보이는 것으로 나타났다. Hydroxypropyl화 전분이 천연전분에 비해 강도는 떨어지나 신장율은 높아지는 것으로 나타났고 수증기투과도는 2배 큰 것으로 나타났다. 가소제를 혼합하여 필름의 물성을 측정한 결과 sorbitol은 유연성보다는 필름의 강도를 유지하는 역할을 그리고 glycerol은 필름의 신장율을 증가시키는 역할을 하는 것으로 나타났다. RVA물성과 필름 물성의 관계에서 가장 연관성이 높은 것은 peak viscosity, 인장강도, 수증기투과도인 것으로 판명되었고 peak viscosity와 인장강도, peak viscosity와 수증기투과도의 관계는 각각 직선적인 것으로 나타났다. 따라서 RVA 물성 중 peak viscosity를 활용하여 필름의 인장강도, 수증기투과도를 예측할 수 있다고 판단되었다.

• Elastomers and Composites
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• 제49권2호
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• pp.117-126
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• 2014

메틸렌 디이소시아네이트(MDI)가 폴리(메틸 메타크릴레이트)-개질된 전분/스티렌-부타디엔 고무(PMMA-modified starch/SBR) 복합체의 물성을 향상시키기 위하여 새로운 개질제로 조사되었다. 한쪽에는 우레탄 결합의 형성으로 인해 다른 한쪽에는 ${\pi}-{\pi}$ 접착 때문에 MDI는 PMMA-modified starch/SBR 계면에서 중간 결합 역할을 하는 것이 형태학적, 기계적, 동역학적 그리고 열적 분해 연구에 의하여 증명되었다. 결과적으로, MDI의 존재는 PMMA-modified starch/SBR 복합체의 기계적 물성과 열적 안정성을 괄목할만하게 개선하였다. 게다가, 생성된 MDI/PMMA-modified starch/SBR 복합체의 여러 가지 물성에 대한 전분 함량의 효과가 형태학, 가황 특성, 기계적 물성, 톨루엔 팽윤 거동, 그리고 열적 안정성에서 조사되었고 자세하게 논의되었다. MDI/PMMA-modified starch/SBR 복합체는 carbon black/SBR(CB/SBR) 복합체보다 우수한 물성을 보였고, 고무 배합물에서 CB의 대체물로서 재생 가능한 전분의 유력한 사용을 보여주었다.