• Title/Summary/Keyword: standard calibration

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Development of Calibration Model for Firmness Evaluation of Apple Fruit using Near-infrared Reflectance Spectroscopy (사과 경도의 비파괴측정을 위한 검량식 개발 및 정확도 향상을 위한 연구)

  • 손미령;조래광
    • Food Science and Preservation
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    • v.6 no.1
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    • pp.29-36
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    • 1999
  • Using Fuji apple fruits cultivated in Kyungpook prefecture, the calibration model for firmness evaluation of fruits by near infrared(NIR) reflectance spectroscopy was developed, and the various influence factors such as instrument variety, measuring method, sample group, apple peel and selection of firmness point were investigated. Spectra of sample were recorded in wavelength range of 1100∼2500nm using NIR spectrometer (InfraAlyzer 500), and data were analyzed by stepwise multiple linear regression of IDAS program. The accuracy of calibration model was the highest when using sample group with wide range, and the firmness mean values obtained in graph by texture analyser(TA) were used as standard data. Chemometrics models were developed using a calibration set of 324 samples and an independent validation set of 216 samples to evaluate the predictive ability of the models. The correlation coefficients and standard error of prediction were 0.84 and 0.094kg, respectively. Using developed calibration model, it was possible to monitor the firmness change of fruits during storage frequently. Time, which was reached to firmness high value in graph by TA, is possible to use as new parameter for freshness of fruit surface during storage.

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Color Calibration Method for Improvement of Reliability on Image Analysis of Rock (암석영상분석의 신뢰도 향상을 위한 컬러보정기법 연구)

  • 장윤섭;박형동
    • Tunnel and Underground Space
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    • v.12 no.1
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    • pp.1-9
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    • 2002
  • Recently, the use of image analysis methods and commercial equipments has been extensively increased in the field of rock engineering. However the problem of errors involved in the image acquisition and subsequent analysis procedure has been frequently neglected. In addition there has been few studies dealing with this problem. So proper color calibration method is needed to be developed for the objectivity and improvement of reliability on image analysis of rock. Color calibration method using standard color rendition chart was adopted on this study. Color calibration and error analysis were carried out for the image acquired from granite rock samples. As a result, comparison among other rock images and improvement of reliability on whole analysis were possible.

Quantification of Naproxen in Pharmaceutical Formulation using Near-Infrared Spectrometry (근적외 분광분석법을 이용한 나프록센 정제의 정량분석)

  • Kim Do Hyung;Woo Young Ah;Kim Hyo Jin
    • YAKHAK HOEJI
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    • v.49 no.1
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    • pp.1-5
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    • 2005
  • Near-infrared (NIR) spectroscopy has been widely applied in various field, since it is nondestructive and no sample preparation is required. In this paper, NIR spectroscopy was used for the determination of naproxen in a commercial pharmaceutical preparation. NIR spectroscopy was used to determine the content of naproxen in intact naproxen tablets containing 250 mg ($65.8\%$ nominal concentration) by collecting NIR spectra in the range of $1100{\sim}1750nm$. The laboratory-made samples had $46.1{\sim}85.5\%$ nominal naproxen concentration. The measurements were made by reflection using a fiber-optic probe and calibration was carried out by partial least square regression (PLSR). Model validation was performed by randomly splitting the data set into calibration and validation data set (63 samples as a calibration data set and 42 samples as a validation data set). The developed NIR calibration gave results comparable to the known values of tablets in a laboratorial manufacturing process with standard error of calibration (SEC) and standard error of prediction (SEP) of $1.06\%\;and\;1.04\%$, respectively. The NIR method showed good accuracy and repeatability. NIR spectroscopic determination in intact tablets allowed the potential use of real time monitoring for a running production process.

Application of BASIN 4.0 and WinHSPF to a Small Stream in Total Water Pollution Load Management Area and Calibration of Model Parameter using Genetic Algorithm (오염총량관리지역내 소하천에 대한 BASINS 4.0 및 WinHSPF의 적용과 유전알고리즘을 이용한 매개변수의 보정)

  • Cho, Jae-Heon;Yun, Seoung-Jin
    • Journal of Environmental Impact Assessment
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    • v.21 no.1
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    • pp.161-169
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    • 2012
  • Recently various attempts have been made to apply HSPF model to calculate runoff and diffuse pollution loads of stream and reservoir watersheds. Because the role of standard flow is very important in the water quality modelling of Total Water Pollution Load Management, HSPF was used as a means of estimating standard flow. In this study, BASINS 4.0 and WinHSPF was applied to the Gomakwoncheon watershed, genetic algorithm(GA) and influence coefficient algorithm were used to calibrate the runoff parameters of the WinHSPF. The objective function is the sum of the squares of the normalized residuals of the observed and calculated flow and it is optimized using GA. Estimates of the optimum runoff parameters are made at each iteration of the influence coefficient algorithm. The calibration results showed a relatively good correspondence between the observed and the calculated values. The standard flow(Q275) of the Gomakwoncheon watershed was estimated using the ten years of weather data.

Uncertainty of Total Alkaloids and Reducing Sugar Determination in Flue-cured Tobacco (황색종 담배중 전알카로이드와 환원당 분석에 대한 불확도 측정)

  • 백순옥;장기철;이운철;한상빈
    • Journal of the Korean Society of Tobacco Science
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    • v.23 no.1
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    • pp.45-52
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    • 2001
  • This study was carried out to evaluate the uncertainty in the analysis of total alkaloids and reducing sugar content in flue-cured tobacco. The sources of uncertainty associated with the analysis of total alkaloids and reducing sugar were the weighing of sample, the preparation of extracting solution, the addition of extracting solution into the sample, the preparation of standard solution, the precision of calibration curve for standard solution, the reproducibility of analysis, and the determination of water content in tobacco, etc. For the calculating uncertainties, Type A of uncertainty was evaluated by the statistical analysis of a series of observation, and Type B by the information based on supplier’s catalogue and/or certificated of calibration. It was shown that the main source of uncertainty was caused by the calibration curve of standard solution, the reproducibility of analysis, the volume measurement of 1$m\ell$, and the purity of nicotine reference material in the preparation of standard solution. The uncertainty in the addition of extracting solution, the sample weighing, the volume measurement of 100$m\ell$, and the determination of water content of tobacco contributed relatively little to the overall uncertainty. The expanded uncertainty of total alkaloids and reducing sugar in flue-cured tobacco at 95% level of confidence was $\pm$0.12% and $\pm$0.54%, respectively.

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Phase-Locked Loops using Digital Calibration Technique with counter (카운터 기반 디지털 보상 기법을 이용한 위상 고정 루프)

  • Jeong, Chan-Hui;Abdullah, Ammar;Lee, Kwan-Joo;Kim, Hoon-Ki;Kim, Soo-Won
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.2
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    • pp.320-324
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    • 2011
  • A digital technique is adopted to calibrate the current mismatch of the charge pump (CP) in phase-locked loops. A 2 GHz charge pump PLL (CPPLL) is used to justify the proposed calibration technique. The proposed digital calibration technique is implemented simply using a counter. The proposed calibration technique reduces the calibration time by up to a maximum of 50% compared other with techniques. Also by using a dual-mode CP, good current matching characteristics can be achieved to compensate $0.5{\mu}A$ current mismatch in CP. It was designed in a standard $0.13{\mu}m$ CMOS technology. The maximum calibration time is $33.6{\mu}s$ and the average power is 18.38mW with 1.5V power supply and effective area is $0.1804mm^2$.

Influence of the homogenizing grade and meathematical treatment on the determination of ground beef components with near infrared reflectance spectroscopy (식품의 근적외선 반사분광분석법에서 균질의 정도가 흡광도에 미치는 영향 및 수학적 처리방법에 관한 연구)

  • Oh, Eun-Kyong;Grossklaus, Dieter
    • Korean Journal of Food Science and Technology
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    • v.24 no.5
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    • pp.408-413
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    • 1992
  • This study was conducted to determine the effect of the homogenizing grade of sample on absorbance of near infrared reflectance spectrophotometer with which chemical compositions of food were rapidly and effectively analyzed. By the mathematical treatment of absorbance values standard error of prediction was reduced as follows. 1. The absorbance values of various samples ground for the same periods of time were calibrated before or after treatment with first or second derivative in an attempt to accurately predict the components of samples ground for the different periods of time. The standard error of prediction for moisture content were 1.478%, 0.658% and 0.580%, respectively, those for fat content 0.949%, 0.637% and 0.527%, respectively, and those for protein content 0.514%, 0.493% and 0.394%, respectively. Calibration of absorbance values after second derivative treatment showed the highest accuracy in predicting sample components. 2. The absorbance values of various samples ground for the different periods of time were calibrated before or after treatment with first or second derivative in order to accurately predict the components of samples ground for the different periods of time. The standard error of prediction for moisture content were 1.026%, 0.589% and 0.568%, respectively, and those for protein content 0.860%, 0.557% and 0.399%, respectively. The standard error of prediction were lower in the order of calibrations before and after first and second derivative treatments. As a result, calibration of absorbance values after second derivative treatment showed higher accuracy regardless of grinding time of samples.

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Absolute Radiometric Calibration for KOMPSAT-3 AEISS and Cross Calibration Using Landsat-8 OLI

  • Ahn, Hoyong;Shin, Dongyoon;Lee, Sungu;Choi, Chuluong
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.35 no.4
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    • pp.291-302
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    • 2017
  • Radiometric calibration is a prerequisite to quantitative remote sensing, and its accuracy has a direct impact on the reliability and accuracy of the quantitative application of remotely sensed data. This paper presents absolute radiometric calibration of the KOMPSAT-3 (KOrea Multi Purpose SATellite-3) and cross calibration using the Landsat-8 OLI (Operational Land Imager). Absolute radiometric calibration was performed using a reflectance-based method. Correlations between TOA (Top Of Atmosphere) radiances and the spectral band responses of the KOMPSAT-3 sensors in Goheung, South Korea, were significant for multispectral bands. A cross calibration method based on the Landsat-8 OLI was also used to assess the two sensors using near simultaneous image pairs over the Libya-4 PICS (Pseudo Invariant Calibration Sites). The spectral profile of the target was obtained from EO-1 (Earth Observing-1) Hyperion data over the Libya-4 PICS to derive the SBAF (Spectral Band Adjustment Factor). The results revealed that the TOA radiance of the KOMPSAT-3 agree with Landsat-8 within 5.14% for all bands after applying the SBAF. The radiometric coefficient presented here appears to be a good standard for maintaining the optical quality of the KOMPSAT-3.

Radiometric Calibration of FTIR Spectrometer For Passive Remote Sensing Application (수동형 원격탐지 FTIR 분광계의 Radiometric Calibration)

  • Kim, Dae-Sung;Park, Do-Hyun;Choi, Seung-Ki;Ra, Sung-Woong
    • Korean Journal of Optics and Photonics
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    • v.17 no.5
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    • pp.391-395
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    • 2006
  • In this paper, radiometric calibration of a FTIR spectrometer for passive remote sensing application was introduced and verified. Radiometric calibration is a significant signal processing procedure to retrieve the object radiance from the measured spectrum. The object radiance is measured and registered distorted by the detector's responsivity dependent on wavelength and instrument self-emission. Radiance of two temperature points, hot temperature and cold temperature, from a well-controlled blackbody was measured and used to obtain the scale factor and offset factor which are required for radiometric calibration. For gas phase C2H5OH. radiometric calibration was done and verified through comparison of its emission line width and intensity with the standard spectrum.