• Title/Summary/Keyword: stainless steel coating

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Effect of Coating Materials for Steel on the Threshold of Corrosive Amount of Airborne Chlorides and the Evaluation of Their Corrosion Speeds (강재마감별 부식개시 임계 비래염분량 및 부식속도 평가)

  • Cho, Gyu-Hwan;Lim, Myung-Hyun;Park, Dong-Cheon
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.2
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    • pp.143-151
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    • 2015
  • Many studies have investigated the airborne chlorides that can weaken the overall durability of the concrete structures due to the corrosion of steel materials, but most of the studies have aimed to examine weathering by exposing various construction materials to the actual oceanic environment. However, with the exposure test, it was difficult to find the threshold of precise corrosive amount of airborne chlorides due to diverse deteriorating environmental factors such as ultraviolet ray, acid rain, floating material from industrial pollution as well as airborne chlorides. Therefore, in this study, an airborne chloride simulator was set up, in oder to conduct a corrosion accelerating test for steels coated by five different finishing materials. As results, it was found that the corrosion began to be observed at $0.58{\sim}0.73mg/dm^2$ for no-coated steel, at $7.89{\sim}8.46mg/dm^2$for urethane-coated steel, at $57.95{\sim}69.48mg/dm^2$ for red lead-coated steel, and at $80.73{\sim}89.35mg/dm^2$ for stainless-coated steel, respectively. Hence, these specific data can be considered as the threshold ranges of corrosion for each coating material for steel.

Chemical Evaluation of Corrosion Resistance for Stainless-Steel Plate Wet-Coated by Alumina-Fluoro Composite Coatings (알루미나-불소 복합 코팅제로 습식코팅된 스텐레스 강판의 화학 내식성 평가)

  • Jung, Ha-Young;Kim, Dae Sung;Lee, Seung-Ho;Lim, Hyung Mi;Kim, Kun;Jung, Min-Kyu
    • Korean Journal of Materials Research
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    • v.22 no.12
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    • pp.643-649
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    • 2012
  • Coatings composited with alumina and Perfluoro alkoxyalkane (PFA) resin were deposited on stainless steel plate (SUS304) to further improve corrosion resistance. Plate (ca. $10{\mu}m$) and/or nanosize (27~43 nm) alumina used as inorganic additives were mixed in PFA resin to make alumina-fluoro composite coatings. These coatings were deposited on SUS304 plate with wet spray coating and then the film was cured thermally. According to the amount and ratio of the two kinds of alumina having plate morphology and nano size, corrosion resistance of the film was evaluated under strong acids (HF, HCl) and a strong base (NaOH). The film prepared with the addition of 5~10 wt% alumina powders in PFA resin showed corrosion resistance superior to that of pure PFA resin film. However, for the film prepared with alumina content above 10 wt%, the corrosion resistance did not improve with the physical properties, such as surface hardness and adhesion. The film prepared with plate/nanosize (weight ratio = 1/2) alumina especially enhanced the surface hardness and corrosion resistance. This can be explained as showing that the plate and the nanosize alumina dispersed in PFA resin effectively suppressed the penetration of cations and anions due to the long penetration length and fewer defects that accompany the improved surface hardness under a serious environment of 10% HF solution for over 120 hrs.

An Electro-Fenton System Using Magnetite Coated One-body Catalyst as an Electrode (일체형 산화철 촉매를 전극으로 하는 전기펜톤산화법)

  • Choe, Yun Jeong;Ju, Jeh Beck;Kim, Sang Hoon
    • Applied Chemistry for Engineering
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    • v.29 no.1
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    • pp.117-121
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    • 2018
  • A stainless steel mesh was applied to the cathode of an electro-Fenton system. Methylene blue (MB) solution was chosen as the model waste water with non-biodegradable pollutants. For the model waste water, the degradation efficiency was compared among various SUS mesh cathodes with different surface treatments and magnetite coatings on them. With increasing amount of the magnetite coating on SUS mesh, the degradation efficiency also increased. The improved electro-catalytic characteristic was explained by the increased amount of in situ generated hydrogen peroxide near the cathode surface. Cyclic voltammetry data also showed improved electro-catalytic performance for SUS mesh with more magnetite coatings on them.

Vapor Permeation Characteristics of TiO2 Composite Membranes Prepared on Porous Stainless Steel Support by Sol-Gel Method

  • Lee, Yoon-Gyu;Lee, Dong-Wook;Kim, Sang-Kyoon;Sea, Bong-Kuk;Youn, Min-Young;Lee, Kwan-Young;Lee, Kew-Ho
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.687-693
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    • 2004
  • Composite membranes with a titania layer were prepared by soaking-rolling method with the titania sol of nanoparticles formed in the sol-gel process and investigated regarding the vapor permeation of various organic mixtures. The support modification was conducted by pressing $SiO_2$ xerogel of 500 nm in particle size under 10 MPa on the surface of a porous stainless steel (SUS) substrate and designed the multi-layered structure by coating the intermediate layer of ${\gamma}-Al_2O_3$. Microstructure of titania membrane was affected by heat-treatment and synthesis conditions of precursor sol, and titania formed at calcination temperature of 300$^{\circ}C$ with sol of [$H^+$]/[TIP]=0.3 possessed surface area of 210 $m^2$/g, average pore size of 1.25 nm. The titania composite membrane showed high $H_2/N_2$ selectivity and water/ethanol selectivity as 25-30 and 50-100, respectively. As a result of vapor permeation for water-alcohol and alcohol-alcohol mixture, titania composite membrane showed water-permselective and molecular-sieve permeation behavior. However, water/methanol selectivity of the membrane was very low because of chemical affinity of permeants for the membrane by similar physicochemical properties of water and methanol.

Fabrication of Laminated Multi-layer Flexible Substrate with Cu/Sn Via (Cu/Sn 비아를 적용한 일괄적층 방법에 의한 다층연성기판의 제조)

  • Lee H. J.;Yu Jin
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.4 s.33
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    • pp.1-5
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    • 2004
  • A multi-layer flexible substrate is composed of copper(Cu)/polyimide that are known as good electrical conductivity, and low dielectric constant, respectively. In this study. conductor line of $5{\mu}m$-pitch was successfully fabricated without non-uniform pattern shape by electroplating copper and coating polyimide on patterned stainless steel. For multi-layer flexible substrate, via holes were drilled by UV laser and filled with electroplating copper and tin. And then, the PI layer with vias and conductor lines was stripped from stainless steel substrate. The PI layers were laminated at once with careful alignment between layers. Solid state reaction between tin and copper during lamination formed the intermetallic compounds of $Cu_6Sn_5$($\eta$-phase) and $Cu_3Sn$($\epsilon$-Phase) and achieved a complete inter-connection by vertically positioning the plugged via holes on via pad. The via formation process has several advantages; such as better electrical property and lower cost than V type via and paste via.

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The Effects of Hot Corrosion on the Creep Rupture Properties of Boiler Tube Material (보일러 管材料의 크리프破斷特性에 미치는 고온부식의 影響)

  • 오세욱;박인석;강상훈
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.2
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    • pp.236-242
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    • 1989
  • In order to investigate the effects of hot corrosion on the creep rupture properties and creep life of 304 stainless steel being used as tube materials of heavy oil fired boiler, the creep rupture tests were carried out at temperature 630.deg.C, 690.deg.C and 750.deg.C in static air for the specimens with or without coating of double layer corrosives according to the new hot corrosion test method simulating the situation commonly observed on superheater tubes of the actual boiler. The double layer corrosives are 85% V$_{2}$O$_{5}$ + 10% Na$_{2}$So$_{4}$ + 5% Fe$_{2}$O$_{3}$ as the inner layer corrosive being once melted at 900.deg. C and crushed to powder, and 10% V$_{2}$O$_{5}$ + 85% Na$_{2}$SO$_{4}$ +5% Fe$_{2}$O$_{3}$ as the outer layer corrosive. As results, in the specimen coated with the double layer corrosives, the rupture strength was extremely lowered and showed a large difference each other. The rupture ductility also lowered remarkably as a result of the brittle fracture mode due to hot corrosion. These results indicate that hot corrosion could essentially alter the creep fracture mechanism. From the metallographic observation, it was clarified that the rupture life of 304 stainless steel subjected to hot corrosion was chiefly determined by the behavior of the aggressive intergranular penetration of sulfides.des.

Synthesis of Silica Membranes on a Porous Stainless Steel by Sol-Gel Method and Effect of Preparation Conditions on Their Permselectivity

  • Lee, Dong-Wook;Nam, Seung-Eun;Sea, Bong-Kuk;Ihm, Son-Ki;Lee, Kew-Ho
    • Bulletin of the Korean Chemical Society
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    • v.25 no.9
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    • pp.1371-1378
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    • 2004
  • A porous stainless steel (SUS) as a substrate of silica composite membranes for hydrogen purification was used to improve mechanical strength of the membranes for industrial application. The SUS support was successfully modified by using submicron Ni powder, $SiO_2$ sols with particle size of 500 nm and 150 nm in turns. Silica top layer was coated on the modified supports under various preparation conditions such as calcination temperature, dipping time and repeating number of dipping-drying process. The calcination temperature for proper sintering was between H ttig temperature and Tamman temperature of the coating materials. Maximum hydrogen selectivity was investigated by changing dipping time. As repeating number of dipping-drying process increased, permeances of nitrogen and hydrogen were decreased and $H_2/N_2$ selectivity was increased due to the reduction of non-selective pinholes and mesopores. For the silica membrane prepared under optimized conditions, permeance of hydrogen was about $3\;{\times}\;10^{-5}\;cm^3{\cdot}cm^{-2}{\cdot}s^{-1}{\cdot}cmHg^{-1}$ combined with $H_2/N_2$ seletivity of about 20.

Effect of additional gases on the Color of TixN Coated Film (TixN Coating층의 색상에 미치는 첨가원소의 영향)

  • 김학동;조성석
    • Journal of the Korean Vacuum Society
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    • v.7 no.2
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    • pp.127-134
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    • 1998
  • Stainless steel is being used widely for various purposes due to its good corrosion resistance. There has been much research to produce a colored and corrosion-resistant stainless steel by several methods to use in decorating. In this experiment, we coated TiN(C,O,H)films on the SUS304 substrates with the DC magnetron sputtering system and then studied the texture and color of the films as a function of additional gases being inserted into the system. A (220) texture of TixN film changed to (200) by the addition of either hydrogen or the acetylene and changed further to (111) with an increase of the additional acetylene content. The addition of oxygen gas changed from the texture(220) to (111) to (200). The color of the TixN film changed from gold to gray to green with the increase of the content by the addition of oxygen gas, while it changed to pink and finally to gray with the increased of the content by the addition of acetylene gas. Reflectance increased in the region of short wavelength by the addition of hydrogen, but decreased with the increase of the oxygen and the acetylene content.

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A Study on the TiC Coating Using Hollow Cathode Discharge Ion Plating (HCD 이온 플레이팅 방법을 이용한 TiC 코팅에 관한 연구)

  • Kim, In-Cheol;Seo, Yong-Woon;Whang, Ki-Whoong
    • Proceedings of the KIEE Conference
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    • 1991.11a
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    • pp.261-264
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    • 1991
  • Titanium carbide(TiC) films were deposited on stainless-steel sheets using HCD(Hollow Cathode Discharge) reactive ion plating. Acetylene gas was used as the reactant gas. The characteristics of TiC films were examined by X-Ray diffraction, $\alpha$-step, ESCA(Electron Spectroscopy for Chemical Analysis), and, AES(Auger Electron Spectroscopy). The results were discussed with regard to various deposition conditions(bias voltage, acetylene flow rate, temperature).

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Synthesis and Absorption Spectra of 1,4-Diketo-3,6-Diphenyl-Pyrrolo-[3,4c]-Pyrrole (1,4-Diketo-3,6-Diphenyl-Pyrrolo-[3,4c]-Pyrrole(DPP)계 유기안료의 합성 및 흡수스펙트라)

  • 김성훈
    • Journal of the Korean Graphic Arts Communication Society
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    • v.14 no.1
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    • pp.1-15
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    • 1996
  • In this paper, the preparation of lead zirconium titanate(PZT) thin film by sol-gel processing was descried. Thin film coated with thickness of 4${\mu}{\textrm}{m}$ on the stainless steel substrates using the multiple spin-coating process. The crystalline phases of PZT powder and film were investigated by X-ray diffraction pattern and PZT thin film has perovskite structure over 600 C annealing temperature. Corona charging characteristics of the ferroelectric PZT thin film at 600 C were investigated by electrophotographic measurement. A difference in the charging characteristics between positive and negative corona charging was found. The charge acceptance depended in the polarity of corona and the poling of film. According to the D-E hysteresis measurment, PZT thin film can be poled by corona charging without use of top electrode. The remnant polarization in the PZT thin film is generally in the order of 48$\mu$C/$\textrm{cm}^2$. From this results, the ferroelectric PZT thin film will be possible to apply for the add-on type imaging formation.

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