• 한국산학기술학회논문지
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• 제20권6호
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• pp.472-482
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• 2019

본 논문은 수중용 TAS윈치 전개/회수 성능 안정화 방안에 대한 내용을 서술하고 있다. TAS윈치는 함미에 장착되어 자함과 이격되어 운용되는 센서, 예인케이블 및 꼬리로프의 전개/회수 기능을 수행하고, TAS에 대한 전원공급 경로, 수중환경 정보 및 수신된 음향신호 송/수신을 위한 데이터 전송 경로 제공 역할을 수행한다. TAS윈치 시험평가 과정에서 간헐적으로 TAS 전개 중 멈춤현상 및 회전속도 변동현상이 식별되었다. TAS 전개/회수에 필요한 토크를 제공하는 구성요소인 윈치모터에 대한 고장분석 결과, 구성품 중 회전자의 정렬 틀어짐으로 인한 편심현상에 따른 자기장 왜곡이 발생한 것을 확인하였다. 자기장 왜곡 발생 방지를 위해 윈치모터 회전자 및 슬립링 등 윈치모터 구성품의 고정성 향상 방안을 제안하였다. 제안된 방안에 대한 신뢰성 확보를 위해 LBTS 환경에서 TAS윈치 운용환경을 모사하여 TAS윈치 전개/회수 성능을 검증하였다. 최종적으로 TAS윈치 전개/회수 성능 뿐만 아니라 해상에서 TAS윈치를 운용할 경우 요구되는 함 속력 및 타각별 TAS 지속 운용능력과 같은 여러 가지 항목에 대한 해상 시험평가를 수행함으로써 설계 요구조건 만족 및 제안 방안에 대한 타당성을 검증하였다.

• Korean Chemical Engineering Research
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• 제59권1호
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• pp.94-99
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• 2021

2단 Rushton turbine 날개를 장착한 접시바닥형 교반조 내의 유동 상태가 어떤 회전수에서 변화하는 현상을 찾아냈다. 층류 영역에서는 회전수를 변화시켜도 안정적인 도넛 링이 형성되어 혼합 패턴에 특이한 변동은 관찰되지 않았다. 전이영역에서의 평바닥형 교반조에서는 회전수에 변화를 주어도 두꺼운 2개의 미혼합 도넛 링에 변화가 없는 반면, 접시바닥형 교반조에서는 회전수가 450 rpm이 되면 두꺼운 2개의 미혼합 도넛 링이 아주 얇은 3개의 도넛 링으로 바뀌어 혼합이 개선되었다. 접시바닷형 교반조에서는 Re=138~178의 영역에서 링 모양의 미혼합 영역이 3곳에서 나타났고 그 크기도 컸지만, 평바닥형 교반조에서는 Re=116~176에서 링모양의 미혼합 영역은 2곳에서 나타났으며 그 크기도 작았다. 이러한 현상이 관찰되는 조건은 전이영역으로, 방해판을 부착하였을 때가 방해판이 없을 때와 비교하여 동력수가 커지기 시작하는 영역임을 알 수 있었다. 또한 교반 레이놀즈수가 300을 넘어 유동 상태에 약간의 난류가 섞이게 되면, 이 같은 흐름 양상의 단절이 해소되어 완전히 혼합되었다.

• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2517-2522
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• 2012

New polynuclear poly(hexaaza macrocyclic) copper(II) complexes $[1](ClO_4)_{2n}{\cdot}(H_2O)_{2n}$, $[2](ClO_4)_{2n}{\cdot}(H_2O)_{2n}$, and $[3](ClO_4)_{2n}{\cdot}(H_2O)_{2n}$ have been prepared by the one-pot reaction of formaldehyde with ethylenediamine and 1,2-bis(2-aminoethoxy)ethane, 1,3-diaminopropane, or 1,6-diaminohexane in the presence of the metal ion. The polymer complexes contain fully saturated 14-membered hexaaza macrocyclic units (1,3,6,8,10,13-hexaazacyclotetradecane) that are linked by $N-(CH_2)_2-O-(CH_2)_2-O-(CH_2)_2-N$, $N-(CH_2)_3-N$, or $N-(CH_2)_6-N$ chains. The mononuclear complex $[Cu(H_2L^5)](ClO_4)_4$ ($H_2L^5$ = a protonated form of $L^5$) bearing two $N-(CH_2)_2-O-(CH_2)_2-O-(CH_2)_2-NH_2$ pendant arms has also been prepared by the metal-directed reaction of ethylenediamine, 1,2-bis(2-aminoethoxy)ethane, and formaldehyde. The polymer complexes were characterized employing elemental analyses, FT-IR and electronic absorption spectra, molar conductance, X-ray diffraction (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and scanning electron micrograph (SEM). Electronic absorption spectra of the complexes show that each macrocyclic unit of them has square-planar coordination geometry with a 5-6-5-6 chelate ring sequence. The polymer complexes as well as $[Cu(H_2L^5)]^{4+}$ are quite stable even in concentrated $HClO_4$ solutions. Synthesis and characterization of the polynuclear and mononuclear copper(II) complexes are reported.

• The Journal of Advanced Prosthodontics
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• 제9권3호
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• pp.182-187
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• 2017

PURPOSE. Vinyl polyether silicone (VPES) has a different composition from other elastomeric impression materials as it combines vinyl polysiloxane (VPS) and polyether (PE). Therefore, it is important to study its properties and behavior under different test conditions. This study investigated the dimensional stability of 5 VPES consistencies when stored for up to 2 weeks, with and without using a standard disinfection procedure. MATERIALS AND METHODS. 40 discs of each VPES consistency (total 200) were made using a stainless steel die and ring as described by ANSI /ADA specification No. 19. 20 discs of each material were immersed in a 2.5% buffered glutaraldehyde solution for 30 minutes. Dimensional stability measurements were calculated immediately after fabrication and repeated on the same discs after 7 and 14 days of storage. The data was analyzed using two-way ANOVA with a significance level set at ${\alpha}=0.05$. RESULTS. The discs mean contraction was below 0.5% at all test times ranging from $0.200{\pm}0.014$ to $0.325{\pm}0.007$. Repeated measures ANOVA showed a statistically significant difference after 2-week storage between the disinfected and non-disinfected groups (P < .001). Although there was no statistically significant difference between the materials at the time of fabrication, the contraction of the materials increased with storage for 1 and 2 weeks. CONCLUSION. The dimensional changes of VPES impression discs after disinfection and prolonged storage complied with ANSI/ADA standard. The tested VPES impression materials were dimensionally stable for clinical use after disinfection for 30 minutes in glutaraldehyde and storage for up to 2 weeks.

• 한국가구학회지
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• 제25권4호
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• pp.345-352
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• 2014

This study was carried out to develop eco-friendly wood street lamp (EFWSL) by using wood resources stacked in the forests after tree tending operations which were mostly abandoned, but economical as renewable wood resources for developing the wood coated street lamps with the effects of cost reduction and their attractive appearances. This study has led to the development of key compact structures of street-lighting wood poles (shaft) using laminated timber. The core technique in this study is related with producing the more stable wood poles (shaft) with the hole inside than wood poles exposed under the natural environment through applicable process to protect the wood from bursting and splitting. We also comprehensively developed the method to conserve the timber durability of wood shaft and connect the wood shaft with groove, race way to be located in the groove, locking ring, current stabilizer connected to the groove and luminaire support arm, base and hand-hole which was partly used in combination with steel materials and wood. Also we increased the utilization of abandoned and stacked woods after thinning in the forests such as Pinus densiflora, Larix leptolepis, and Pinus koraiensis plantations by maximizing the value of these natural wood resources as main materials of eco-friendly street lightings with the effects of cost reduction and attractive appearances and also the expectation of advertising effects of street lightings developed in this study.

• Bulletin of the Korean Chemical Society
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• 제32권6호
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• pp.1884-1890
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• 2011

A series of Ni(II) and Pd(II) complexes bearing N4-type tetradentate ligands, [Ni($X^1X^2$-6-$Me_2bpb$) 1] and [Pd($X^1X^2$-6-$Me_2bpb$) 2]; 6-$Me_2bpb$ = N,N'-(o-phenylene)bis(6-methylpyridine-2-carboxamidate), $X^1$ = Cl, H, or $CH_3$, $X^2$ = $NO_2$, Cl, F, H, $CH_3$, or $OCH_3$) were designed, synthesized, and characterized to investigate electronic and steric effects of ligand on the norbornene polymerization catalysts. Using modified methylaluminoxanes as an activator, the complexes exhibited high catalytic activities for the polymerization of norbornene and the nickel complexes exhibited better catalytic activity the palladium complexes. Ni complex 1a with $NO_2$ group on the benzene ring showed the highest catalytic activity of $4.9{\times}10^6$ g of PNBEs/$mol_{Ni}{\cdot}h$ and molecular weight of $15.28{\times}10^5$ g/mol with PDI < 2.30. Complexes with electron-withdrawing groups are more thermally stable (> 100 $^{\circ}C$), and tend to afford higher polymerization productivities than the ones having electron-donating groups. Amorphous polynorbornenes were obtained with good solubility in halogenated aromatic solvents. A vinyl addition mechanism has been proposed for the catalytic polymerization.

• 한국응용과학기술학회지
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• 제15권2호
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• pp.11-24
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• 1998

All the surface activities including surface tension, foaming power, foam stability, emulsifying power, dispersion effect, and detergency were measured and critical micelle concentration(cmc) was evaluated in dilute aqueous solution. The cmc evaluated by the Ring method was $10^{-3}{\sim}10^{-4}mol/L$ in case of monoesters, and $10^{-3}{\sim}5.0{\times}10^{-5}mol/L$ in case of diesters, respectively. Surface tension of the aqueous solution was decreased to $45{\sim}50dyne/cm$, showing the tendency that the ability of lowering the surface tension was dependent on increasing of carbon atom number in alkyl chain. Foaming power of all the monoesters was better than that of diesters. while foam stability of diesters was to the contrary. Emulsifying power of soybean oil or benzene was specially expected to be good for emulsifiers in industrial application fields. HLB values of monoesters and diesters evaluated by Griffin's method were in the range of 8 to 12. Dispersion property of ferric oxide was stable in the range of $4.5{\times}10^{-5}{\sim}5.0{\times}^{-4}mol/L$ in case of monoesters, and $10^{-5}{\sim}10^{-4}mol/L$ in case of diesters.

• 한국진공학회:학술대회논문집
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• 한국진공학회 1996년도 제11회 학술발표회 논문개요집
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• pp.40-41
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• 1996

Nitridation technique has been receiving much attention for the formation of a thin nitrided buffer layer on which high quality nitride films can be formedl. Particularly, gallium nitride (GaN) has been considered as a promising material for blue-and ultraviolet-emitting devices. It can also be used for in situ formed and stable passivation layers for selective growth of $GaAs_2$. In this work, formation of a thin nitrided layer is investigated. Nitrogen electron cyclotron resonance(ECR)-plasma is employed for the formation of thin nitrided layer. The plasma source used in this work is a compact ECR plasma gun3 which is specifically designed to enhance control, and to provide in-situ monitoring of plasma parameters during plasma-assisted processing. Microwave power of 100-200 W was used to excite the plasma which was emitted from an orifice of 25 rnm in diameter. The substrate were positioned 15 em away from the orifice of plasma source. Prior to nitridation is performed, the surface of n-type (001)GaAs was exposed to hydrogen plasma for 20 min at $300{\;}^{\circ}C$ in order to eliminate a native oxide formed on GaAs surface. Change from ring to streak in RHEED pattern can be obtained through the irradiation of hydrogen plasma, indicating a clean surface. Nitridation was carried out for 5-40 min at $RT-600{\;}^{\circ}C$ in a ECR plasma-assisted molecular beam epitaxy system. Typical chamber pressure was $7.5{\times}lO^{-4}$ Torr during the nitridations at $N_2$ flow rate of 10 seem.(omitted)mitted)

• 대한화학회지
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• 제26권5호
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• pp.274-281
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• 1982

펜타메틸벤젠 및 헥사메틸벤젠과 요오드 및 일염화요오드와의 각계를 사염화 탄소용액에서 자외선 분광광도법에 의하여 연구한 결과 1:1 분자 착물이 형성됨을 알았다. 이들 착물 생성에 의한 흡수최대는 온도가 상승함에 따라 blue shift 되므로 이에 따른 각 온도에서의 평형상수를 구하였다. 이 값으로 부터 이들 착물 생성에 대한 열역학적 파라미터를 산출한 결과 각 온도에서 폴리메틸벤젠과 요오드 및 일염화요오드 사이에 생성된 착물의 상대적 안정도는 ICl이 $I_2$보다 크다는 것을 알 수 있다. 이 사실은 폴리메틸벤젠에 대한 그들의 상대적 산성도를 나타내며 할로겐 원자의 전기 음성도의 차이에 의하여 설명할 수 있다. 그리고 이 계열의 연구결과를 종합하면 벤젠에 치환된 메틸기의 수가 증가함에 따라 ${\lambda}_{max}$는 red shift 하였고 이들 착물의 상대적 안정도가 다음 순서로 증가함을 알 수 있었다.Benzene < Toluene < Xylene < Durene < Mesitylene < Pentamethylbenzene < Hexamethylbenzene. 이에 따른 결과에 대하여 고찰하였다.

• 융합신호처리학회논문지
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• 제8권2호
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• pp.98-105
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• 2007

본 논문은 주행 차량의 차선 변경 시, 위험 여부를 판단하는 방법을 제안하고 시스템을 구현한다. 차선 변경의 위험 여부를 판단하기 위해서 첫째, 변경하고자 하는 차선에 관심 영역(ROI)을 설정해야 하고 둘째, 변경할 차선으로 자차가 이동할 때 자차에 위험이 될 차량을 정확하게 추출해야 하며 셋째, 추출된 차량의 방향과 상대 속도, 상대 거리를 계산하여 운전자에게 위험 경보를 울릴지에 대한 여부를 판단해야 한다. ROI를 설정하기 위해서 영역의 한 축이 되는 차선을 잡고 이를 기준으로 영역을 확장시켰는데 좌표 변환 기법을 이용하여 정확성을 높였다. 변경 차선의 정확한 차량 추출을 위하여 적응 배경화면 갱신 모델 기법과 주행 도로의 특징을 이용한 영상의 영상 분할 방법을 이용하였다. 위험 차량으로 추출된 물체는 자차(自車)와의 상대거리, 상대 속도를 계산하고 픽셀 좌표 이동을 일정시간 평균을 내어 방향을 알아내어 위험으로 판단 시 경보를 울리도록 하였다. 제안한 알고리즘은 영역을 최소화하고 도로와 차량의 특징을 이용함으로써 정확도를 높이고 계산량을 줄여 빠른 연산을 요구하는 주행 차량의 영상에서 안정적인 결과를 얻을 수 있었다.