• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.6
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• pp.472-482
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• 2019

This paper describes the stabilization of underwater TAS winch system Deploy/Recover operation performance. TAS winch installed on the stern of submarine performs to deploy/recover sensor, towing cable and rope tail which is deployed from the stern and separated from submarine itself. Also TAS winch provides transmission path of power to the sensor and data transmitting/receiving path which data are acquired from underwater environment like sound, depth and temperature. At the step of TAS winch evaluation test, sporadic standstill and rotating speed oscillation phenomenon were occurred. Winch motor provides the available torque to deploy/recover TAS and root cause analysis to the winch motor was done to find exact reason to sporadic malfunction. When winch motor was disassembled, eccentricity of rotor, slip-ring and the other composition part for winch motor were found. These might cause magnetic field distortion. To make TAS winch system more stable and block magnetic field distortion, this paper suggests methods to enhance fixing status installed in winch motor. For reliable data acquisition for TAS winch operation, the deploy/recover function of the improved type of TAS winch was verified in LBTS making similar condition with sea status. At the end of stage, improved type of TAS winch was tested on some functions not only deploy/recover function, but sustainability of TAS operation on specific velocity, steering angle of submarine in the sea trial. Improved type of TAS winch was verified in accordance with design requirement. Also, validity of suggested methods were verified by the sea trial.

• Korean Chemical Engineering Research
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• v.59 no.1
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• pp.94-99
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• 2021

It was found that mixing patterns suddenly changed at an impeller rotation speed in a dished bottom vessel with dual Rushton turbines. Two isolated mixing regions like doughnuts rings generated at a low rotational speed and three isolated mixing regions generated at a higher speed. This phenomenon was observed at the mixing condition in transition area, where the power number with baffle was the same as that without baffle. We found a phenomenon in which the flow state in a dish-bottom agitation tank equipped with a two-stage Rushton turbine blade changes at a certain rotational speed. In the laminar flow region, the isolated stable donut rings were formed even when the rotational speed was changed, and no specific variation in the mixing pattern was observed. In the transition region, the two isolated thick unmixed donut rings do not change even if the rotation speed is changed in the flat bottom vessel, whereas in the dished bottom vessel, when the rotation speed is 450 rpm, the two isolated thick unmixed donut rings are changed to three isolated thin donut rings and then improved mixing. In the dished bottom vessel, in the range of Re=138~178, the isolated ring-shaped unmixed region appeared in three places and the size was also large. But in the flat bottom vessel, the isolated thick ring-shaped unmixed region appeared in two places in Re=116~176 and the size was also small. It appeared in two places, and the size was also small. The condition in which this phenomenon is observed is a transition region, and it was found that when the baffle plate is attached, the power number starts to increase compared to when the baffle plate is not present. In addition, when the mixing Reynolds number exceeded 300 and a slight turbulence was mixed in the flow state, the disconnection of these flow pattern was resolved and the mixture was completely mixed.

• Bulletin of the Korean Chemical Society
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• v.33 no.8
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• pp.2517-2522
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• 2012

New polynuclear poly(hexaaza macrocyclic) copper(II) complexes $[1](ClO_4)_{2n}{\cdot}(H_2O)_{2n}$, $[2](ClO_4)_{2n}{\cdot}(H_2O)_{2n}$, and $[3](ClO_4)_{2n}{\cdot}(H_2O)_{2n}$ have been prepared by the one-pot reaction of formaldehyde with ethylenediamine and 1,2-bis(2-aminoethoxy)ethane, 1,3-diaminopropane, or 1,6-diaminohexane in the presence of the metal ion. The polymer complexes contain fully saturated 14-membered hexaaza macrocyclic units (1,3,6,8,10,13-hexaazacyclotetradecane) that are linked by $N-(CH_2)_2-O-(CH_2)_2-O-(CH_2)_2-N$, $N-(CH_2)_3-N$, or $N-(CH_2)_6-N$ chains. The mononuclear complex $[Cu(H_2L^5)](ClO_4)_4$ ($H_2L^5$ = a protonated form of $L^5$) bearing two $N-(CH_2)_2-O-(CH_2)_2-O-(CH_2)_2-NH_2$ pendant arms has also been prepared by the metal-directed reaction of ethylenediamine, 1,2-bis(2-aminoethoxy)ethane, and formaldehyde. The polymer complexes were characterized employing elemental analyses, FT-IR and electronic absorption spectra, molar conductance, X-ray diffraction (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and scanning electron micrograph (SEM). Electronic absorption spectra of the complexes show that each macrocyclic unit of them has square-planar coordination geometry with a 5-6-5-6 chelate ring sequence. The polymer complexes as well as $[Cu(H_2L^5)]^{4+}$ are quite stable even in concentrated $HClO_4$ solutions. Synthesis and characterization of the polynuclear and mononuclear copper(II) complexes are reported.

• The Journal of Advanced Prosthodontics
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• v.9 no.3
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• pp.182-187
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• 2017

PURPOSE. Vinyl polyether silicone (VPES) has a different composition from other elastomeric impression materials as it combines vinyl polysiloxane (VPS) and polyether (PE). Therefore, it is important to study its properties and behavior under different test conditions. This study investigated the dimensional stability of 5 VPES consistencies when stored for up to 2 weeks, with and without using a standard disinfection procedure. MATERIALS AND METHODS. 40 discs of each VPES consistency (total 200) were made using a stainless steel die and ring as described by ANSI /ADA specification No. 19. 20 discs of each material were immersed in a 2.5% buffered glutaraldehyde solution for 30 minutes. Dimensional stability measurements were calculated immediately after fabrication and repeated on the same discs after 7 and 14 days of storage. The data was analyzed using two-way ANOVA with a significance level set at ${\alpha}=0.05$. RESULTS. The discs mean contraction was below 0.5% at all test times ranging from $0.200{\pm}0.014$ to $0.325{\pm}0.007$. Repeated measures ANOVA showed a statistically significant difference after 2-week storage between the disinfected and non-disinfected groups (P < .001). Although there was no statistically significant difference between the materials at the time of fabrication, the contraction of the materials increased with storage for 1 and 2 weeks. CONCLUSION. The dimensional changes of VPES impression discs after disinfection and prolonged storage complied with ANSI/ADA standard. The tested VPES impression materials were dimensionally stable for clinical use after disinfection for 30 minutes in glutaraldehyde and storage for up to 2 weeks.

• Journal of the Korea Furniture Society
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• v.25 no.4
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• pp.345-352
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• 2014

This study was carried out to develop eco-friendly wood street lamp (EFWSL) by using wood resources stacked in the forests after tree tending operations which were mostly abandoned, but economical as renewable wood resources for developing the wood coated street lamps with the effects of cost reduction and their attractive appearances. This study has led to the development of key compact structures of street-lighting wood poles (shaft) using laminated timber. The core technique in this study is related with producing the more stable wood poles (shaft) with the hole inside than wood poles exposed under the natural environment through applicable process to protect the wood from bursting and splitting. We also comprehensively developed the method to conserve the timber durability of wood shaft and connect the wood shaft with groove, race way to be located in the groove, locking ring, current stabilizer connected to the groove and luminaire support arm, base and hand-hole which was partly used in combination with steel materials and wood. Also we increased the utilization of abandoned and stacked woods after thinning in the forests such as Pinus densiflora, Larix leptolepis, and Pinus koraiensis plantations by maximizing the value of these natural wood resources as main materials of eco-friendly street lightings with the effects of cost reduction and attractive appearances and also the expectation of advertising effects of street lightings developed in this study.

• Bulletin of the Korean Chemical Society
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• v.32 no.6
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• pp.1884-1890
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• 2011

A series of Ni(II) and Pd(II) complexes bearing N4-type tetradentate ligands, [Ni($X^1X^2$-6-$Me_2bpb$) 1] and [Pd($X^1X^2$-6-$Me_2bpb$) 2]; 6-$Me_2bpb$ = N,N'-(o-phenylene)bis(6-methylpyridine-2-carboxamidate), $X^1$ = Cl, H, or $CH_3$, $X^2$ = $NO_2$, Cl, F, H, $CH_3$, or $OCH_3$) were designed, synthesized, and characterized to investigate electronic and steric effects of ligand on the norbornene polymerization catalysts. Using modified methylaluminoxanes as an activator, the complexes exhibited high catalytic activities for the polymerization of norbornene and the nickel complexes exhibited better catalytic activity the palladium complexes. Ni complex 1a with $NO_2$ group on the benzene ring showed the highest catalytic activity of $4.9{\times}10^6$ g of PNBEs/$mol_{Ni}{\cdot}h$ and molecular weight of $15.28{\times}10^5$ g/mol with PDI < 2.30. Complexes with electron-withdrawing groups are more thermally stable (> 100 $^{\circ}C$), and tend to afford higher polymerization productivities than the ones having electron-donating groups. Amorphous polynorbornenes were obtained with good solubility in halogenated aromatic solvents. A vinyl addition mechanism has been proposed for the catalytic polymerization.

• Journal of the Korean Applied Science and Technology
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• v.15 no.2
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• pp.11-24
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• 1998

All the surface activities including surface tension, foaming power, foam stability, emulsifying power, dispersion effect, and detergency were measured and critical micelle concentration(cmc) was evaluated in dilute aqueous solution. The cmc evaluated by the Ring method was $10^{-3}{\sim}10^{-4}mol/L$ in case of monoesters, and $10^{-3}{\sim}5.0{\times}10^{-5}mol/L$ in case of diesters, respectively. Surface tension of the aqueous solution was decreased to $45{\sim}50dyne/cm$, showing the tendency that the ability of lowering the surface tension was dependent on increasing of carbon atom number in alkyl chain. Foaming power of all the monoesters was better than that of diesters. while foam stability of diesters was to the contrary. Emulsifying power of soybean oil or benzene was specially expected to be good for emulsifiers in industrial application fields. HLB values of monoesters and diesters evaluated by Griffin's method were in the range of 8 to 12. Dispersion property of ferric oxide was stable in the range of $4.5{\times}10^{-5}{\sim}5.0{\times}^{-4}mol/L$ in case of monoesters, and $10^{-5}{\sim}10^{-4}mol/L$ in case of diesters.

• Proceedings of the Korean Vacuum Society Conference
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• 1996.06a
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• pp.40-41
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• 1996

Nitridation technique has been receiving much attention for the formation of a thin nitrided buffer layer on which high quality nitride films can be formedl. Particularly, gallium nitride (GaN) has been considered as a promising material for blue-and ultraviolet-emitting devices. It can also be used for in situ formed and stable passivation layers for selective growth of $GaAs_2$. In this work, formation of a thin nitrided layer is investigated. Nitrogen electron cyclotron resonance(ECR)-plasma is employed for the formation of thin nitrided layer. The plasma source used in this work is a compact ECR plasma gun3 which is specifically designed to enhance control, and to provide in-situ monitoring of plasma parameters during plasma-assisted processing. Microwave power of 100-200 W was used to excite the plasma which was emitted from an orifice of 25 rnm in diameter. The substrate were positioned 15 em away from the orifice of plasma source. Prior to nitridation is performed, the surface of n-type (001)GaAs was exposed to hydrogen plasma for 20 min at $300{\;}^{\circ}C$ in order to eliminate a native oxide formed on GaAs surface. Change from ring to streak in RHEED pattern can be obtained through the irradiation of hydrogen plasma, indicating a clean surface. Nitridation was carried out for 5-40 min at $RT-600{\;}^{\circ}C$ in a ECR plasma-assisted molecular beam epitaxy system. Typical chamber pressure was $7.5{\times}lO^{-4}$ Torr during the nitridations at $N_2$ flow rate of 10 seem.(omitted)mitted)

• Journal of the Korean Chemical Society
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• v.26 no.5
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• pp.274-281
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• 1982

Ultraviolet spectrophotometric investigation have been carried out on the systems of pentamethylbenzene and hexamethylbenzene with iodine and iodine monochloride in carbon tetrachloride. The results reveal the formation of the one to one molecular complexes. The equilibrium constants were obtained in consideration of that absorption maxima due to the formation of the charge transfer complexes shift to blue with the increasing temperature. Thermodynamic parameters for the formation of the charge transfer complexes were calculated from these values. These results indicate that the complex formed between polymethylbenzene and iodine monochloride is more stable than that in the case of iodine. This may be a measure of their relative acidities toward polymethylbenzene, which is explained in terms of the relative electronegativities of halogen atoms. These results combined with previous studies of this series indicated that ${\lambda}_{max}$ shift to red with the increasing number of methyl groups on benezene ring and that the relative stabilities of these complexes increase in the order, Benzene < Toluene < Xylene < Durene < Mesitylene < Pentamethylbenzene < Hexamethylbenzene. The reason for the order found is thus additionally discussed.

• Journal of the Institute of Convergence Signal Processing
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• v.8 no.2
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• pp.98-105
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• 2007

In this paper, we propose the method and system which determines the condition for safe and unsafe lane changing. To determine the condition, first, the system sets up the Region of Interest(ROI) on the neighboring lane. Second, a dangerous vehicle is extracted during the line changing. Third, the condition is determined to wm or not by calculating the moving direction, relative distance md relative velocity. To set up the ROI, the only one side lane is detected and the interested region is expanded. Using the coordinate transformation method, the accuracy of the ROI raised. To correctly extract the vehicle on the neighboring lane, the Adaptive Background Update method and Image Segmentation method which uses the feature of the travelling road are used. The object which is extracted by the dangerous vehicle is calculated the relative distance, the relative velocity and the moving average. And then in order to ring, the direction of the vehicle and the condition for safe and unsafe is determined. As minimizes the interested region and uses the feature of the travelling road, the computational quantity is reduced and the accuracy is raised and a stable result on a travelling road images which demands a high speed calculation is showed.