• 제목/요약/키워드: stable cathode

검색결과 164건 처리시간 0.037초

Advances in Materials for Proton Exchange Membrane based Fuel Cells

  • McGrath James E.
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.58-59
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    • 2006
  • Less than a decade ago, most alternate membrane materials for fuel cells relied upon a post-sulfonation process to generate ionic groups capable of transporting protons from the anode to the cathode. These random post sulfonations showed some promise, but in general they produced materials that were not sufficiently stable or protonically conductive at ion exchange capacities where aqueous swelling could be restricted. Our group began to synthesize disulfonated monomers that could be used to incorporate into random copolymer proton exchange membranes. The expected limitation was that the aromatic polymers might not be stable enough to withstand fuel cell conditions. However, this was mostly based upon an accelerated test known was the Fenton's Reagent Test, which did not seem to this author as being a reliable predictor of performance. A much better approach has been to evaluate the open circuit voltage (OCV) for alternate membranes, as well as the benchmark perfluorosulfonic acid systems. When this is done, the aromatic ionomers of this study, primarily based upon disulfonated polyarylene ether sulfones, show up quite well. Real time 3000 hours DMFC results have also been generated. Obtaining conductive materials at low humidities is another major issue where alternate membranes have not been particularly successful. In order to address this problem, multiblock copolymers with relatively high water diffusion coefficients have been designed, which show promise for conductivity at lowered humidity.

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타켓 종류에 따른 대향타겟 스퍼터링 장치의 방전 특성 (Discharge Characteristics of Facing Targets Sputtering Apparatus with Targets Species)

  • 금민종;손인환;신성권;가출현;박용서;김경환
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.620-623
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    • 2004
  • In this study, the discharge characteristic of FTS (Facing Targets Sputtering) apparatus was investigated using metal target paramagnetic and ceramic targets such as Zn, Al, $ZnO:Al(Al_2O_3)$, ITO. Threshold voltage and stable stage of discharge show different with target species. Compare with commercial sputtering apparatus, the FTS apparatus is a high-speed sputter method that promotes ionization of sputter gas by screw and reciprocate moving high-speed ${\gamma}$electrons which arrays two targets facing each other, inserts plasma arresting magnetic field to the parallel direction of the center axis of both targets, discharged from targets and accelerated at the cathode falling area. Especially, we notice that the FTS method using ceramic target has stable discharge characteristic even by DC power source.

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알카라인 연료전지 가스확산층 내구성 향상을 위한 초발수 코팅 최적화 연구 (Study on the Optimization of Superhydrophobic Coating for the Durability of Gas Diffusion Layer in Alkaline Fuel Cells)

  • 김숭연;서민혜;엄성현
    • 공업화학
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    • 제28권6호
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    • pp.691-695
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    • 2017
  • 본 연구에서는 알카라인 연료전지 환원극 가스확산층에 내열화학성이 우수한 초발수 성능을 부여하기 위하여 PDMS 코팅 공정을 최적화하였다. 성격이 상이한 두 개의 상용 가스확산층을 선택하였으며, 소재의 열적 안정성을 검토하여 코팅 온도를 최적화하고, PDMS 점도를 제어하여 코팅 균일성을 확보하고자 하였다. PDMS 전구체의 점도와 관계없이 $200^{\circ}C$ 부근에서 코팅하게 되면 모든 확산층 표면에서 높은 초발수 성능을 나타내었다. 가혹실험 조건에서 초발수 성능변화를 측정한 결과 1000 CS PDMS를 이용하여 28BC 가스확산층에 코팅한 경우가 가장 높은 내구성을 나타내었다.

리튬이차전지용 바나듐계 양극의 제초 특성 (The Preparation Characteristics of Vanadium-based Cathode for Lithium Secondary Battery)

  • 박수길;김종진;;이주성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.395-398
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    • 1998
  • Lithium insertion has been studied in a number of vanadium oxides with special regard to their application as the active materials in rechargeable lithium cells. Very high stoichiometric energy densities for lithium insertion are found for several of these materials. Some vanadium oxides, e.g. V$_2$ $O_{5}$ and V$_{6}$ $O_{13}$, are now being used in commercially developed rechargeable Li batteries. Another material which is receiving remarkable attention for this kind of cells is LiV$_3$ $O_{8}$. In variety of ternary lithium-vanadium oxides, the lithium content can be varied between certain limits without major changes in the vanadium oxygen lattice. In our worts, the oxides which do net form these thermodynamically stable bronzes can still accommodate large amounts of lithium at ambient temperature, forming kinetically stable insertion compounds. These compounds owe their existence to the whereas lithium is easily introduced into these open structures. The oxides investigated are rather poor electronic conductors; the conductivity decrease with increase in the lithium content. Improvements in the electrode fabrication technique are needed to alleviate this Problem.oblem.

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알칼리 수전해에서 전극재질에 따른 수소생산 특성 (The Characteristics of Hydrogen Production According to Electrode Materials in Alkaline Water Electrolysis)

  • 문광석;박대원
    • 에너지공학
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    • 제24권2호
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    • pp.34-39
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    • 2015
  • 본 연구에서는 중온에서 수소생산이 가능한 무격막형 알칼리수전해 장치를 제작하여 전극재질에 따른 수소생산 특성을 확인하였다. 전극재질($IrO_2/Ti$, $RuO_2/Ti$, Ti)별 전기화학적 특성을 확인한 결과 $RuO_2/Ti$에서 가장 높은 효율을 나타내었고, 전해질 농도별 수소생산량 실험 결과, 전해질 농도와 수소생산량은 비례하는 경향을 보였으며 30% KOH 조건에서 $118.9m^3/m^3/day$로 가장 높은 수소생산량을 확인할 수 있었다. 전극재질별 수소생산량을 확인한 실험에서는 anode($IrO_2/Ti$)와 cathode($RuO_2/Ti$)로 조합 시 $157.55m^3/m^3/day$$IrO_2/Ti$를 cathode로 조합한 결과에 비해 약 6.97% 높은 수소생산량을 보였다. 이는 DSA전극의 전기화학적 활성도 향상에 의한 수소생산량 증대와 기존 전극에 비해 내구성이 향상되어 안정적인 알칼리 수전해가 가능한 것으로 사료된다.

LCD용 백라이트의 CCFL 구동을 위한 특성해석 (Characteristic Analysis for CCFL drive of LCD backlight)

  • 주경돈;윤신용;김철진;백수현
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 추계학술대회 논문집 전기기기 및 에너지변환시스템부문
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    • pp.199-202
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    • 2004
  • CCFL(Cold Cathode Fluorescent Lamp) are used to backlight of LCD(Liquid Crystal Display). This paper presents analysis of half-bridge type resonant inverter of CCFL drive in order to stable characteristics, and fluorescent lamp operation frequency is higher than resonant frequency for safe operation. Besides, The Piezoelectric ceramic transformer (PZT) is electro-mechanical device that transfers electrical energy through a mechanical vibration. The modified equivalent circuit model of the PZT considering the operating current level is derived to design the CCFL. The validity of this study was confirmed from the simulation and experiential result.

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DCJTB를 Doping한 적색 유기 발광소자의 특성 (Characteristics of the red organic electroluminescect devices doped with DCJTB)

  • 최완지;임민수;정득영;이정구;임기조
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.1034-1037
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    • 2002
  • In this study, we fabricated red organic electrolu-minescent device with a doping material (DCJTB), and The cell structure used ITO:indium tin oxide $[20{\Omega}]$/CuPc:Hole injection layer 20nm/NPB: Hole transfer layer 40nm/$Alq_3$ (host) + DCJTB(1% or 3%) (guest) Emitting layer 40nm/$Alq_3$ : Electron transfer layer 30nm/Al :Cathode layer 150nm. the luminescent layer consisted of a host material. 8-hydrozyquinoline aluminum $(Alq_3)$, and DCJTB dye as the dopant. a stable red emission (chromaticity coordinates : x=0.64, y=0.36) was obtained in this cell with the luminance range of $100-600cd/m^2$. we study the electrical and optical properties of devices.

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Low cost, printed P-OLED displays for entry into the flexible display market

  • MacKenzie, J.Devin;Breeden, J.J.;Carter, S.A.;Chen, J.P.;Hinkle, P.;Jones, E.;Kreger, M.A.;Nakazawa, Y.;Roeloffs, R.;Vo, Vung;Wilkinson, M.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.641-643
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    • 2006
  • Add-Vision has developed a low-cost print technology for P-OLED displays on flexible substrates that meets several essentials for a new technology including: (1) Functionality including low DC voltage and wide color gamut; (2) Utilization of inexpensive tools; (3) Performance matching entry applications and markets. AVI's process is based on large-area printing of a combination of doped emissive and air-stable cathode inks utilizing truly low-cost tools to create printed P-OLEDs.

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고분자 전해질의 전도도 특성 (Poly(ethylene oxide)/Poly(vinylidene fluoride) Blend)

  • 김종욱;성창호;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.109-112
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    • 1996
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for all-stolid-state lithium battery. We investigated conductivity, electrochemical properites and impedence spectroscopy of poly(ethylene oxide)[PEO]/poly(vinylidene fluoride)[PVOF] blend electrolytes and charge/discharge cycling of LiCoO$_2$/SPE/Li cell. By adding PVDF and plasticizer to PEO-LICIO$_4$electrolyte, its condustivity was higher than that of PEO-LiCIO$_4$electrolyte. Also PEO$_4$PVDF$_4$LiClO$_4$PC$_{5}$EC$_{5}$ remains stable up to 4.4V vs Li/Li. The discharge capacity of the LiCoO$_2$composite cathode was 92mAh/g based on LiCoO$_2$.EX>.

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Emission Behavior of Screen Printed CNT Field Emitters for Advanced Lamp Application

  • Leer, Myoung-Bok;Kim, Dae-Jun;Song, Yoon-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.691-692
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    • 2009
  • Screen printable CNT pastes were formulated including conductive nano particles (CNPs) and their properties were investigated with an expectation of stable cold cathodes for advanced lamp application. CNT cathodes showed a turn-on field of 1~1.5V/um, a life time of ~100 hours at an emission current density of 10uA/$cm^2$ for DC-bias. Detailed analysis of measured I-V was carried out by applying Fowler-Nordheim model to trace down the origin of emission property degradation.

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