• 한국산학기술학회논문지
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• 제9권5호
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• pp.1368-1373
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• 2008

본 연구는 내분비계 장애물질로써 페놀 및 비스페놀A이 포함된 용액에 대해 전기분해 실험을 수행하였다. 불용성 DSA 양극을 사용하여 오염물질의 전기산화 변화를 확인하였으며 이때 운전인자는 전류밀도, 전도도, 극간거리 등을 변수로 하여 행하였다. 페놀 및 비스페놀A 제거율인 경우 전류밀도가 증가에 비례하여 오염물 제거가 향상되었으며 전도도가 높을수록 비스페놀A 처리율이 증가하였다. 반면 극간거리 변화에 따른 오염물질 제거에는 큰 영향을 보이지 않았다.

• 반도체디스플레이기술학회지
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• 제19권1호
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• pp.49-54
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• 2020

The voltage drop due to the thin cathode film at the large size top emission OLED panel was successfully compensated with making electrical contact between thin cathode and anode auxiliary electrode by 355nm wavelength of laser. It was found that the luminance uniformity dramatically increased from around 15% to more than 80% through this electrical compensation between thin cathode and anode auxiliary electrode. Moreover, the removing process for EL materials on the anode auxiliary electrode process by laser was very reliable and stable. Therefore, it is thought that the EL removal method using laser to make electrical contacts is very appropriate to mass production for such a large size top emission OLEDs to obtain high uniformity of luminance.

• Bulletin of the Korean Chemical Society
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• 제30권3호
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• pp.657-660
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• 2009

The surface of $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ cathode particle was modified by lanthanum based oxide to improve electrochemical property and thermal stability. The XRD pattern of surface layer was indexed with that of $La_4NiLiO_8$. The discharge capacity of modified electrode was higher than that of pristine sample, specially at fast charge-discharge rate and high cut-off voltage. In the DSC profile of the charged sample, the generation of heat by exothermic reaction was decreased by surface modification. Such enhancement may by attributed to the presence of stable lanthanum based oxide, which effectively suppressd the reaction between electrode and electrolyte on the surface of $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ electrode.

• 한국전기전자재료학회논문지
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• 제19권1호
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• pp.64-70
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• 2006

In this study, the $LiCoO_2/LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ mixed cathode electrodes were prepared and their electrochemical performances were measured in a high cut-off voltage. As the content of $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ increased in a mixed cathode, the reversible specific capacity and cycleability of the electrode enhanced, but the rate capability was deteriorated. On the contrary the rate capability of the cathode enhanced, but the reversible specific capacity and cycleability were deteriorated, increasing the content of $LiCoO_2$ in the mixed cathode. The cell of $LiCoO_2/LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ ($50:50 wt\%$) mixed cathode delivered a discharge capacity of ca. 168 mAh/g at a 0.2 C rate. The capacity of the cell decreased with the current rate and a useful capacity of ca. 152 mAh/g was obtained at a 2.0 C rate. However, the cell showed very stable cycleability: the discharge capacity of the cell after 20th charge/discharge cycling maintains ca. 163 mAh/g.

• 한국환경과학회지
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• 제5권4호
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• pp.535-544
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• 1996

In the development of Molten Carbonate Fuel Cell, one of the serious problems is the dissolution of cathode material. Therefore, the development of the alternative cathode which is stable in molten carbonate is needed. In this research, the licoo, was chosen as alternative cathode material. $LiCoO_2$ powder was synthesized by high temperature calcination method and by citrate sol-gel method. And its structure and physical iharacteristics were analyzed by XRD, 1 R, TCA and porosimeter. The conductivity and solubility of $LiCoO_2$ electrode were also measured. Homogeneous $LiCoO_2$ Powder was obtained by citrate sol-Rel method at 445$^{\circ}C$, however, obtained above 75$0^{\circ}C$ by high temperature calcination method. Homogeneous particle size distribution and fine powder were obtained by the citrate sol-Rel method. $LiCoO_2$ electrode showed higher electric conductivity ($1.7 $\Omega$^{-1}cm^{-1}$) than NiO (0.1 $\Omega$^{-9} cm^{-1}) at $650^{\circ}C$. The solubilities of $LiCoO_2$ electrode in electrolyte were varies 0.6 to 1.0 ppm during 200 hours. So, the solubilities of $LiCoO_2$ were much lower than that of NiO.

• Journal of Electrochemical Science and Technology
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• 제5권2호
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• pp.37-44
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• 2014

The $Li-O_2$ battery has been attracting much attention recently, due to its very high theoretical capacity compared with Li-ion chemistries. Nevertheless, several studies within the last few years revealed that Li-ion derived electrolytes based on alkyl carbonate solvents, which have been commonly used in the last 27 years, are irreversibly consumed at the $O_2$ electrode. Accordingly, more stable electrolytes are required capable to operate with both the Li metal anode and the $O_2$ cathode. Thus, due to their favorable properties such as non volatility, chemical inertia, and favorable behavior toward the Li metal electrode, ionic liquid-based electrolytes have gathered increasing attention from the scientific community for its application in $Li-O_2$ batteries. However, the scale-up of Li-$O_2$ technology to real application requires solving the mass transport limitation, especially for supplying oxygen to the cathode. Hence, the 'LABOHR' project proposes the introduction of a flooded cathode configuration and the circulation of the electrolyte, which is then used as an oxygen carrier from an external $O_2$ harvesting device to the cathode for freeing the system from diffusion limitation.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2016년도 추계학술대회 논문집
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• pp.97-97
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• 2016

Development of advanced Li-ion battery cells with high durability is critical for safe operation, especially in applications to electric vehicles and portable electronic devices. Understanding fundamental mechanism on the formation of a solid-electrolyte interphase (SEI) layer, which plays a substantial role in the electrochemical stability of the Li-ion battery, in a cathode was rarely reported unlike in an anode. Using first-principles density functional theory (DFT) calculations and ab-initio molecular dynamic (AIMD) simulations we demonstrate atomic-level process on the generation of the SEI layer at the interface of a carbonate-based electrolyte and a spinel $LiMn_2O_4$ cathode. To accomplish the object we calculate the energy band alignment between the work function of the cathode and frontier orbitals of the electrolyte. We figure out that a proton abstraction from the carbonate-based electrolyte is a critical step for the initiation of an SEI layer formation. Our results can provide a design concept for stable Li-ion batteries by optimizing electrolytes to form proper SEI layers.

• 한국세라믹학회지
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• 제47권1호
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• pp.75-81
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• 2010

The feasibility of using the thin film technology in utilizing lanthanum strontium manganite (LSM) for a solid oxide fuel cell (SOFC) cathode in a low-temperature regime is investigated in this study. Thin film LSM cathodes were fabricated using pulsed laser deposition (PLD) on anode-supported SOFCs with yttria-stabilized zirconia (YSZ) electrolytes. Although cells with a 1 ${\mu}m$-thick LSM cathode showed poor low-temperature cell performance compared to that of a cell with a bulk-processed cathode due to the lack of a triple-phase boundary length, the cell with 200 nm-thick gadolinia-doped ceria (GDC) inserted between the LSM and YSZ showed enhanced performance and more stable operation characteristics in a comparison of a cell without a GDC layer. We postulate that the GDC layer likely improved the cathode adhesion, therefore contributing to the improvement of the cell performance instead of serving as an interfacial reaction buffer.

• 한국재료학회지
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• 제9권9호
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• pp.861-864
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• 1999

다중 음극 전자빔을 이용한 새로운 플라즈마 소스를 설계하고 제작하였다. 대면적의 플라즈마를 발생시키기 위해 다중 음극을 채택하였다. 다중 음극 전자빔 플라즈마 소스(multi-cathode electron beam plasma source, MCEBPS)를 이용하여 300mm 또는 그 이상의 직경을 가진 웨이퍼에 안정한 플라즈마를 생성시킬 수 있었다. 텅스텐 필라멘트를 음극으로 사용하였다. 직경 320mm의 넓이에서, plasma potential $V_p$와 floating potential $V_f$ 모두 균일하게 유지되었고 $V_p와 V_f$의 차이도 낮은 값으로 나타났다. 플라즈마 밀도는 약 $10^{10} cm^{-3}$ 정도로 측정되었고 반경걸에 따른 편차는 작게 나타났다.

• 한국재료학회지
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• 제32권4호
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• pp.216-222
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• 2022

The capacity of high nickel Li(Ni_xCo_yMn_1-x-y)O₂ (NCM, x ≥ 0.8) cathodes is known to rapidly decline, a serious problem that needs to be solved in a timely manner. It was reported that cathode materials with the {010} plane exposed toward the outside, i.e., a radial structure, can provide facile Li⁺ diffusion paths and stress buffer during repeated cycles. In addition, cathodes with a core-shell composition gradient are of great interest. For example, a stable surface structure can be achieved using relatively low nickel content on the surface. In this study, precursors of the high-nickel NCM were synthesized by coprecipitation in ambient atmosphere. Then, a transition metal solution for coprecipitation was replaced with a low nickel content and the coprecipitation reaction proceeded for the desired time. The electrochemical analysis of the core-shell cathode showed a capacity retention of 94 % after 100 cycles, compared to the initial discharge capacity of 184.74 mA h/g. The rate capability test also confirmed that the core-shell cathode had enhanced kinetics during charging and discharging at 1 A/g.