• Title/Summary/Keyword: stability of oxidation

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Effects of Residual Phosphorus Content on color Reversion and Storage Stability of Corn Germ Oil (잔류 인함량이 옥배유의 변색및 저장안정성에 미치는 영향)

  • 김종승;이근보;이미숙
    • Journal of Food Hygiene and Safety
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    • v.12 no.2
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    • pp.107-110
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    • 1997
  • To examine the effects of residual phosphorus content on color reversion and storage stability of corn germ oil, the changes of Lovibond total color and stability of oxidation were determined according to the different storage periods at room and incubating temperature, respectively. The residual phosphorus content and storage temperature had the synergistic effect on color reversion during short time storage. The extent of color change was the greatest when oils were stored for 1.0∼1.5 years at room temperature and thereafter gradually tended to reverse color reversion. It is supposed that the double bonds of carotenoids in oils were oxidized and then turned to the volatiles such as epoxide, ionone, and etc. In contrast, the residual phosphorus content increased oxidation stability of oils. The residual phosphorus content was closely correlated with the color reversion and storage stability, respectively.

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Oxidation Behaviors of Porous Ferritic Stainless Steel Support for Metal-supported SOFC

  • Moon, I.J.;Lee, J.W.;Cho, H.J.;Choi, G.M.;Sohn, H.K.
    • Corrosion Science and Technology
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    • v.9 no.5
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    • pp.196-200
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    • 2010
  • Recently porous metal has been used as supporting metal in planar type SOFC. In order to search optimum alloys for porous metal support and estimate the stability of metal-supported SOFC at high temperature, it is necessary to investigate the oxidation behaviors of porous material for metal support in comparison with dense material. Oxidation tests of porous and dense stainless steels were conducted at $600^{\circ}C$ and $800^{\circ}C$. Since the specific surface area of porous material is much larger than that of dense material, surface area should be considered in order to compare the oxidation rate of porous stainless steel with that of dense stainless steel. The specific surface area of porous body was measured using image analyzer. The weight gain of porous stainless steel was much greater than those of dense stainless steels due to its larger specific surface area. considering the specific surface area, the oxidation rate of porous stainless steel is likely to be the same as that of dense stainless steel with the same surface area. The change in chromium content in stainless steel during oxidation was also investigated. The experimental result in chromium content in stainless steel during oxidation corresponded with the calculated value. While the change in chromium content in dense stainless steel during oxidation is negligible, chromium content in porous stainless steel rapidly decreases with oxidation time due to its large specific surface area. The significant decrease in chromium content in porous stainless steel during oxidation may affect the oxidation resistance of porous stainless steel support and long term stability of metal-supported SOFC.

Oxidation Behavior and Property Changes of Nuclear Graphite (원자로급 흑연의 산화거동 및 산화에 따른 물성변화)

  • Cho, Kwang-Youn;Kim, Kyong-Ja;Lim, Yun-Soo;Chung, Yun-Joong;Chi, Se-Hwan
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.833-838
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    • 2006
  • Graphite is suitable for high temperature structural materials because of chemical stability as well as unique crystal structure. Especially, graphite can be used as a part of a nuclear reactor due to high tolerance at the extreme conditions of high temperature and neutron irradiations. Although study of oxidation properties or behaviors of graphite are very important and essential for the life and stability of the nuclear reactor, most of studies treat this theme lightly. This work focuses on the oxidation characteristics of several grade isotropic graphite of the nuclear reactor.

Review on the oxidation stability of biodiesel (바이오디젤의 산화 안정성 특성에 관한 고찰)

  • Lee, Mi-Eun;Hwang, In-Ha;Kim, Jae-Kon;Na, Byung-Ki
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1013-1030
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    • 2018
  • Biodiesel is a fuel produced in the form of a fatty acid methyl ester by using raw materials such as animal fat, vegetable oil and its by-products, and is being seen as a biofuel that can replace petroleum energy. However unsaturated fatty acid methyl esters in biodiesel causes to oxidize during storage and distribution, resulting in poor fuel quality and corrosion of vehicle engine components. In this study, the influence of quality and oxidation characteristics of biodiesel on the oxidation stability is investigated and the evaluation method related it is described. We also propose a method to improve the drawback of oxidation stability in biodiesel.

Ionic Passivation and Oxidation Dynamics for Enhanced Viability of Copper-Based On-Skin Bioelectrodes in Biological Environments

  • Jungho Lee;Gaeun Yun;Juhyeong Jeon;Phuong Thao Le;Seung Whan Kim;Geunbae Lim
    • Journal of Sensor Science and Technology
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    • v.32 no.6
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    • pp.352-356
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    • 2023
  • The integration of bioelectronic devices with the skin is a promising strategy for personalized healthcare monitoring and diagnostics. On-skin bioelectrodes hold great potential for the real-time tracking of physiological parameters. However, persistent challenges of stability and reliability have instigated exploration beyond conventional noble metals. This study focuses on the ionic passivation and oxidation dynamics of copper-based on-skin thin-film bioelectrodes. Through parylene chemical vapor deposition, we harness a controlled thin film of parylene insulation to counter the intrinsic susceptibility of copper to oxidation in the ionic environment. The results represent the relationship among the parylene insulation thickness, copper oxidation, and electrode impedance over temporal intervals. Comparative analyses indicate that the short-term stability of the copper electrode is comparable to that of the gold electrode. Therefore, we propose a cost-effective strategy for fabricating copper-based on-skin bioelectrodes by introducing enhanced ionic stability within a discernible operational timeframe. This study enriches our understanding of on-skin bioelectronics and affordable material choices for practical use in wearable healthcare devices.

Effects of oil refining processes on oil characteristics and oxidation stability of sesame oil (정제공정이 참기름의 유지특성과 산화안정성에 미치는 영향)

  • Han, Jin-Suk;Ahn, Seung-Yo
    • Applied Biological Chemistry
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    • v.36 no.4
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    • pp.284-289
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    • 1993
  • The effect of oil refining processes-degumming, alkali-refining, bleaching and deodorizing-on oil characteristics and oxidation stability of sesame oil were investigated. The colors(L, a, b) of samples were markedly changed and their peroxide and acid values were decreased, while the other characteristics of samples were not changed during refining stages. The L values of alkali-refined, bleached and deodorized sesame oils were largely decreased and their a values were increased due to browning reaction during the storage at $70^{\circ}C$. The colors of crude and degmmed sesame oils were very stable and their peroxide, free fatty acid and conjugated dienoic acid values were slowly increased. Volatile carbonyl compounds formed by oxidation were increased during the storage at $70^{\circ}C$. The results indicated that refining processes did not affect the sesame oil characteristics but decreased the oxidation stability of sesame oil.

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Effect of Temperature Deviation on the Water-holding Capacity, Tenderness, Lipid Oxidation, and Color Stability of Korean Hanwoo (韓牛) Beef during Long-term Aging (온도편차가 한우고기의 장기간 숙성 중 보수력, 연도, 지방산화 및 육색안전성에 미치는 영향)

  • Kang, Sun Moon;Ahn, Dalrae;Seong, Pil-Nam;Kim, Jin-Hyoung;Cho, Soohyun;Park, Beom-Young;Kim, Yunseok
    • Journal of the Korean Society of Food Culture
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    • v.34 no.6
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    • pp.771-778
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    • 2019
  • This study investigated the effect of temperature deviation on the water-holding capacity, tenderness, lipid oxidation, and color stability of Korean Hanwoo (韓牛) beef during long-term aging. The striploins (M. longissimus lumborum) were aged for 56 days at 2±1℃ (T1), 2±2℃ (T2), or 2±3℃ (T3). Drip loss and cooking loss were higher (p<0.05) in T3 than in T1 on day 56. The Warner-Bratzler shear force value was similar for all treatments during aging times. On day 56, the content of 2-thiobarbituric acid reactive substances was higher (p<0.05) in T3 as compared to T1. The CIE L* and b* values were similar for all treatments, but the a* value was lower (p<0.05) in T3 than in T1 on the last day. These findings indicate that high temperature deviation adversely affects the water-holding capacity, lipid oxidation stability, and color stability of Hanwoo beef during long-term aging.

Production system influences color stability and lipid oxidation in gluteus medius muscle

  • Ana Paula Amaral de Alcantara Salim;Micheli da Silva Ferreira;Maria Lucia Guerra Monteiro;Loise Caroline Santos de Lima;Isabelle Trezze Marins Magalhaes;Carlos Adam Conte-Junior;Sergio Borges Mano
    • Animal Bioscience
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    • v.36 no.5
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    • pp.785-796
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    • 2023
  • Objective: We aimed to evaluate the color and oxidative stability of beef gluteus medius (GM) from cattle raised in organic and non-organic production systems. Methods: The GM samples (n = 10) were obtained from organic (ORG; n = 5) or nonorganic (NORG; n = 5) beef samples, sliced into 2.54-cm steaks, packaged in aerobic conditions, and stored for nine days at 4℃. ORG and NORG steaks were compared regarding myoglobin concentration, pH, instrumental color, delta E (ΔE), metmyoglobin reducing activity (MRA), and lipid oxidation on days 0, 5, and 9. Results: Feeding system did not influence (p>0.05) the myoglobin concentration. ORG steaks exhibited greater (p<0.05) meat pH, yellowness, and MRA, whereas NORG steaks exhibited greater (p<0.05) redness, chroma, R630/580, delta E, and lipid oxidation. ORG and NORG steaks exhibited similar (p>0.05) lightness and hue angle. During storage, ORG and NORG exhibited an increase in muscle pH, hue angle, and lipid oxidation; and a decrease (p<0.05) in redness, yellowness, chroma, and color stability (R630/580). Both samples exhibited a stable (p>0.05) pattern for lightness and MRA. Conclusion: Therefore, the production system can affect beef color and lipid stability during storage.

New Application of Clay Filler for Carbon/Carbon Composites and Improvement of Filler Effect by Clay Size Reduction

  • Jeong, Eui-Gyung;Kim, Jin-Hoon;Lee, Young-Seak
    • Carbon letters
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    • v.11 no.4
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    • pp.293-297
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    • 2010
  • To investigate new potential application of a clay material for C/C composites, illite added C/C composites were prepared with various illite contents. The improvement of filler effect by illite size reduction was also investigated using wet ballmilling by evaluating illite/phenolic resin infiltration using bulk density and porosity measurements, chemical structural changes of the composites using XRD, and thermal oxidation stability in air of the composites using TGA. The size reduction of illite resulted in narrower particle size distribution and improved illite infiltration into carbon preform. And the resultant C/C composites prepared with illite had even more improved thermal oxidation stability in air, showing more increased IDTs up to $100^{\circ}C$, compared to those of the C/C composites with pristine illite, due to the SiC formation through carbothermal reduction between illite and carbon materials. The illite induced delay in oxidation of the illite-C/C composites was also observed and the delayed oxidation behavior was attributed to the layered structure of illite, which improved illite/phenol resin infiltration. Therefore, the potential use of illite as filler to improve oxidation stability of C/C composite can be promising. And the size reduction of illite can improve its effect on the desired properties of illite-C/C composites even more.

Oxidation Stability of Regenerated Lubricating Oils (Ⅰ). Properties of Regenerated Oils (潤滑再生油의 酸化安定性能 (第1報) 再生油의 性能)

  • Yun Ho Nha
    • Journal of the Korean Chemical Society
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    • v.18 no.6
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    • pp.443-446
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    • 1974
  • The regenerated lubricating oils for an internal combustion engine, obtained from the sulfuric acid and clay treatment, showed an improved thermal oxidation stability regardless of additives, especially anti-oxidant, originally presented in the oils. It is believed that such improvement is due to the formation of anti-oxidant materials, which is observed by the in crease of 25 % of aromatic compounds.

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