• 제목/요약/키워드: stability of membrane

검색결과 694건 처리시간 0.031초

스핀코터를 이용한 박막의 기계적 안정성 평가 (Mechanical Stability Evaluation of Thin Film with Spin-coater)

  • 김지은;김정환;홍성철;조한구;안진호
    • 반도체디스플레이기술학회지
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    • 제15권1호
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    • pp.6-11
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    • 2016
  • For high volume manufacturing using extreme ultraviolet (EUV) lithography, mask protection from contamination during lithography process must be solved, and EUV pellicle is the strongest solution. Based on the technical requirements of EUV pellicle, EUV pellicle should have large membrane area ($110{\times}140mm^2$) with film transmittance over 90% and mechanical stability. Even though pellicle that satisfies size standard with high transmittance has been reported, its mechanical stability has not been confirmed, nor is there a standard to evaluate the mechanical stability. In this study, we suggest a rather simple method evaluating mechanical stability of pellicle membrane using spin-coater which can emulate the linear accelerated motion. The test conditions were designed by simulating the acceleration distribution inside pellicle membrane through correlating the linear acceleration and centripetal acceleration, which occurs during linear movement and rotation movement, respectively. By these simulation results, we confirmed the possibility of using spin-coater to evaluate the mechanical stability of EUV pellicle.

Dynamic Stability of Liquid in a Spherical Tank Covered with Membrane under Vertical Harmonic Excitation

  • Chiba, Masakatsu;Murase, Ryo;Nambu, Yohsuke;Komatsu, Keiji
    • International Journal of Aerospace System Engineering
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    • 제2권2호
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    • pp.34-39
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    • 2015
  • Experimental studies were conducted on the liquid sloshing characteristics in a spherical tank covered with a flexible membrane. A spherical acrylic tank with 145.2 mm in radius was used as a test tank, and it was half-filled with water. Silicon membranes with 0.2 mm thickness were used as a test membrane with plane or hemispherical types. The test tank was harmonically excited in a vertical direction by an electro-dynamic exciter. In this case, a parametric instability vibration comes up when the excitation frequency is twice the natural frequency. Parametric instability regions of natural modes were measured for three cases, i.e. liquid surface is free, covered with plane membrane and hemi-spherical membrane.

Development of nano-and meso- inorganic membrances for the environmental applications

  • Yi, Jong-Heop
    • 한국막학회:학술대회논문집
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    • 한국막학회 2004년도 첨단 분리막 연구동향
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    • pp.37-59
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    • 2004
  • Advantages : - Multi-functionality of inorganic surface ㆍMetal chelating ligand $\longrightarrow$ metal recovery .Alkylation $\longrightarrow$ hydrophobicity control - Enhanced stability ㆍThermal, mechanical and chemical stability ㆍSeparation in high temperature and pressure (omitted)

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유세포 분석기와 Neutral Red Retention Assay를 이용한 자연산 참굴(Crassostrea gigas)의 면역력 측정 (Assessment of Immune Parameters of the Wild Pacific Oyster (Crassostrea gigas) using a Flow Cytometry and Neutral Red Retention Assay)

  • 홍현기;강현실;김영옥;최광식
    • Ocean and Polar Research
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    • 제34권2호
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    • pp.137-149
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    • 2012
  • 남해의 광양만과 진해만에 서식하는 자연산 참굴의 건강성 평가를 위해 세포성 면역을 담당하는 혈구의 기능들을 유세포 분석기와 Neutral Red Retention(NRR) assay를 이용하여 신속, 정확하게 측정하였다. 광양만과 진해만의 안쪽과 바깥쪽에 서식하는 자연산 참굴의 혈구를 유세포 분석기를 이용하여 형태학적 특성에 따라 혈구의 종류를 분류하고, 혈구 종류별 수, 사멸률, DNA 손상도, 식세포능을 측정하였다. 또한 NRR assay를 이용하여 혈구의 lysosomal membrane stability를 측정하였다. 참굴의 혈구는 granulocytes, hyalinocytes, blast-like cells의 세 가지 종류로 분류되었다. 조사 지역 간의 혈구의 수, 사멸률, DNA 손상도는 유의적 차이가 없었지만, 식세포율과 lysosomal membrane stability와 같은 면역 관련 기능들은 유의적 차이가 있었다. 진해만은 내만과 외만 지역에 서식하는 참굴의 혈구 면역인자들 간에는 유의적 차이가 관찰되지 않았다. 이에 반해, 광양만에 서식하는 참굴은 내만 지역의 섬진대교가 외만 지역의 평산리 지역에 서식하는 참굴보다 낮은 식세포율과 낮은 lysosomal membrane stability를 보여 면역력이 저하되어 있는 것으로 추정된다. 하지만, 해양환경 변화와 시료의 면역력과의 상관관계를 이해하기 위해서는 조사지역의 환경적 특성이나 오염정도, 그리고 시료 내의 오염물질 축적량 등의 객관적인 분석 결과와의 종합적인 고찰이 필요할 것이다. 유세포 분석기와 NRR assay를 이용한 참굴 혈구 집단의 형태 변화 및 면역능 측정 기술은 시료의 전처리 없이 빠른 시간 내에 세포의 특성을 분석할 수 있는 유용한 분석 tool로 활용될 수 있음을 확인하였다.

알칼리 수전해를 위한 상용 음이온교환막에 관한 연구 (Study on Commercially Available Anion Exchange Membrane for Alkaline Water Eectrolysis)

  • 박주왕;유철휘;황갑진
    • 멤브레인
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    • 제31권4호
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    • pp.275-281
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    • 2021
  • 알칼리 수전해용 격막으로 사용가능성을 평가하기 위해 5종류의 상용 음이온교환막의 열적안정성, 이온전도도, 내구성을 평가하였다. TGA (thermo-gravimetric analysis)로 분석한 열적안정성은 FAAM-PK-75와 FAAM-40 막이 다른 3종류의 AEM, AHO, AHA 막과 비교하여 좋은 성능을 보였다. 25℃와 80℃, 7 M KOH 수용액에서의 이온전도도는 AEM막이 다른 막과 비교하여 약 4~17배 높은 값을 보였다. 25℃, 7 M KOH 수용액에서 측정한 내구성은 FAAM-PK-75막이 다른 막과 비교하여 안정하였다.

A Review of Strategies to Improve the Stability of Carbon-supported PtNi Octahedral for Cathode Electrocatalysts in Polymer Electrolyte Membrane Fuel Cells

  • In Gyeom Kim;Sung Jong Yoo;Jin Young Kim;Hyun S. Park;So Young Lee;Bora Seo;Kwan-Young Lee;Jong Hyun Jang;Hee-Young Park
    • Journal of Electrochemical Science and Technology
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    • 제15권1호
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    • pp.96-110
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    • 2024
  • Polymer electrolyte membrane fuel cells (PEMFCs) are green energy conversion devices, for which commercial markets have been established, owing to their application in fuel cell vehicles (FCVs). Development of cathode electrocatalysts, replacing commercial Pt/C, plays a crucial role in factors such as cost reduction, high performance, and durability in FCVs. PtNi octahedral catalysts are promising for oxygen reduction reactions owing to their significantly higher mass activity (10-15 times) than that of Pt/C; however, their application in membrane electrode assemblies (MEAs) is challenged by their low stability. To overcome this durability issue, various approaches, such as third-metal doping, composition control, halide treatment, formation of a Pt layer, annealing treatment, and size control, have been explored and have shown promising improvements in stability in rotating disk electrode (RDE) testing. In this review, we aimed to compare the features of each strategy in terms of enhancing stability by introducing a stability improvement factor for a direct and reasonable comparison. The limitations of each strategy for enhancing stability of PtNi octahedral are also described. This review can serve as a valuable guide for the development of strategies to enhance the durability of octahedral PtNi.

Separation of Hydrogen-Nitrogen Gas Mixture by PTMSP/PDMS-PEI Composite Membrane

  • Lee, Hyun-Kyung;Kang, Tae-Beom
    • 한국막학회:학술대회논문집
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    • 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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    • pp.148-151
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    • 2004
  • The development of the gas separation processes using polymeric membranes has attracted a great deal of interest during the last two decades. Membrane in this application has to offer an excellent thermal stability, chemical/solvent resistance, and mechanical strength under operating conditions.(omitted)

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유연한 전기변색 소자를 위한 세공충진 고분자 전해질 멤브레인의 개발 (Development of Pore-filled Polymer Electrolyte Membranes for Flexible Electrochromic Devices)

  • 박현정;이지현;강문성
    • 멤브레인
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    • 제31권5호
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    • pp.333-342
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    • 2021
  • 유연한 전기변색 소자(electrochromic device, ECD)는 스마트 윈도우 등 다양한 분야에서 응용이 기대되는 유망한 기술이다. 고분자 전해질은 유연한 ECD의 탈-변색 성능 및 물리적 안정성을 결정하는 중요한 구성요소이다. 본 연구에서는 효과적인 유연한 ECD 제조 및 내구성 향상을 위해 치수안정성이 우수한 세공충진 고분자 전해질 멤브레인(PFPEM)을 개발하였다. 저렴하며 물리적 및 화학적 안정성이 우수한 폴리에틸렌 재질의 다공성 지지체의 세공에 접착력이 우수한 polyvinyl acetate와 이온전도도를 향상시킬 수 있는 polyethylene glycol을 사용하여 제조한 고분자 전해질을 충진하였다. 제조된 PFPEM의 최적 리튬 염(LiTFSI) 함량은 약 27 wt%에서 결정되었으며 우수한 치수안정성와 접착 강도 그리고 종래의 고분자 전해질에 근접하는 이온전도 특성을 가지고 있음을 확인하였다. 다공성 지지체의 사용으로 가시광 투과율이 저하되었으나 변색 상태에서는 오히려 장점으로 작용할 것으로 전망되었다.

화학적으로 유도한 랫드 간세포 암화과정에서 단백질 식이가 간의 조직학적 변화와 생체막 안정도에 미치는 영향 (The Effects of Dietary Proteins on Hepatic Histological Changes and Membrane Stability in Chemically Induced Rat Hepatocarcinogenesis)

  • 박경애;김현덕;최혜미
    • Journal of Nutrition and Health
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    • 제34권8호
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    • pp.833-842
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    • 2001
  • The purpose of this study is to determine the effect of dietary proteins and fats on the hepatic histological changes, membrane stability, and drug-metabolizing enzyme activities during chemically induced rat hepatocarcinogenesis. Weanling Sprague-Dawley rats were fed the diet containing 20% casein or soy protein isolate and 15% perilla or corn oil for 10 weeks. Hepatocarcinogensis was initiated with diethylnitrosamine(DEN), and the rats were fed diets containing 0.02% 2-acetylaminofluorene(AAF) followed by 0.05% phenobarbital (PB). The scores of histological changes were decreased in treated rats fed soy protein diet compared to those find casein diet. Liver weights were significantly increased by AAF and PB treatment in rats fed casein diets in both oil groups. Glucose 6-phosphatase(G6Pase) activities, an index of membrane stability, were significantly reduced by AAF and PB treatment in rats find casein diets, and were lower in casein diet compared to soy protein diet groups. Especially, the activities were the highest in the rats fed soy protein-perilla oil diet. Lipid peroxide values also were increased by AAF and PB treatment in rats fed casein diet. Aniline hydroxylase activities were not influenced by protein and fat sources. Glutathione-dependent enzyme activities were increased by AAF and PB treatment. Linoleic and arachidonic acid content were increased in rats fed corn oil diet, and linolenic and eicosapentaenoic acid contents were increased in rats fed perilla oil diet. Our results suggest that soy protein isolate inhibit the abnormal histological changes in liver, possibly by maintaining the membrane stability during chemically induced rat hepatocarcinogenesis. Soy protein may be protective against the hepatocarcinogenesis induced by chemical carcinogen.

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Ionic Liquid as a solvent and Long-Term Separation Performance in Polymer/Silver Salt Complex Membrane

  • Kang, Sang-Wook;Kim, Jong-Hak;Char, Kook-Heon;Kang, Yong-Soo
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.307-307
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    • 2006
  • The reduction behavior of silver ions to silver nanoparticles is an important research topic in polymer/silver salt complex membranes for facilitated olefin transport, because it has a significant effect on the long-term stability of membrane performance. In this study, the effects of solvent on the formation of silver nanoparticles and long-term membrane performance in polymer/silver salt complex membrane were investigated. This effect was assessed for the complexes of poly(N-vinyl pyrrolidone) $(PVP)/AgBF_{4}$ with the use of ionic liquid (IL), acetonitrile (ACN) and water as a solvent. Membrane performance test shows that long-term stability is strongly dependent on the kind of solvent and arranged: IL > ACN >> water.

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