• Korean Chemical Engineering Research
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• v.59 no.3
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• pp.326-332
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• 2021

In this study, a spherical carbon composite material containing nano-silicon was synthesized using hydrothermal synthesis, and coated with petroleum pitch to prepare an anode material to investigate the electrochemical characteristics. Hydrothermal synthesis was performed by varying molar concentration, and the pitch was coated using THF as an organic solvent to prepare a composite material. The physical properties of anode materials were analyzed using SEM, EDS, XRD and TGA, and the electrochemical performances were investigated by cycle, C-rate, cyclic voltammetry and electrochemical impedance tests in 1.0 M LiPF₆ electrolyte (EC : DMC : EMC = 1 : 1 : 1 vol%). The pitch-coated silicon/carbon composite (Pitch@Si/C-1.5) with sucrose of 1.5 M showed a spherical shape. In addition, a high initial capacity of 1756 mAh/g, a capacity retention ratio of 82% after 50 cycles, and an excellent rate characteristic of 81% at 2 C/0.1 C were confirmed.

• Economic and Environmental Geology
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• v.12 no.2
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• pp.95-104
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• 1979

The position of any point on the earth's surface can be. represented in the spherical coordinates by surface spherical harmonics. Since geomagnetic field is a function of position on the earth, it can be also expressed by spherical harmonic analysis as spherical harmonics of trigonometric series of $a_m({\theta})$ cos $m{\phi}$ and $b_m({\theta})$ sin $m{\phi}$. Coefficients of surface spherical harmonics, $a_m({\theta})$ and $b_m({\theta})$, can be drawn from the components of the geomagnetic field, declination and inclination, and vice versa. In this paper, components of geomagnetic field, declination and inclination in the Korean peninsula are obtained by spherical harmonic analysis using the Gauss coefficients calculated from the world-wide magnetic charts of 1960. These components correspond to the values of normal geomagnetic field having no disturbances of subsurface mass, structure, and so on. The vertical and total components offer the zero level for the interpretation of geomagnetic data obtained by magnetic measurement in the Korean peninsula. Using this zero level, magnetic anomaly map is obtained from the data of airborne magnetic. prospecting carried out during 1958 to 1960. The conclusions of this study are as follows; (1) The intensity of horizontal component of normal geomagnetic field in Korean peninsula ranges from $2{\times}10^4$ gammas to $2.45{\times}10^4$ gammas. It decreases about 500 with the increment of $1^{\circ}$ in latitude. Along the same. latitude, it increases 250 gammas with the increment of $1^{\circ}$ in longitude. (2) Intensity of vertical component ranges from $3.85{\times}10^4$ gammas to $5.15{\times}10^4$ gammas. It increases. about 1000 gammas with the increment of $1^{\circ}$ in latitude. Along the same latitude, it decreases. 150~240 gammas with the increment of $1^{\circ}$ in longitude. Decreasing rate is considerably larger in higher latitude than in lower latitude. (3) Total intensity ranges from $4.55{\times}10^4$ gammas to $5.15{\times}10^4$ gammas. It increases 600~700 gammas with the increament of $1^{\circ}$ in latitude. Along the same latitude, it decreases 10~90 gammas. with the increment of $1^{\circ}$ in longitude. Decreasing rate is considerably larger in higher latitude as the case of vertical component. (4) The declination ranges from $-3.8^{\circ}$ to $-11.5^{\circ}$. It increases $0.6^{\circ}$ with the increment of $1^{\circ}$ in latitude. Along the same latutude, it increases $0.6^{\circ}$ with the increment of l O in longitude. Unlike the cases of vertical and total component, the rate of change is considerably larger in lower latitude than in higher latitude. (5) The inclination ranges from $57.8^{\circ}$ to $66.8^{\circ}$. It increases about $1^{\circ}$ with 'the increment of $1^{\circ}$ in latitude Along the same latitude, it dereases $0.4^{\circ}$ with the increment of $1^{\circ}$ in longitude. (6) The Boundaries of 5 anomaly zones classified on the basis of the trend and shape of anomaly curves correspond to the geologic boundaries. (7) The trend of anomaly curves in each anomaly zone is closely related to the geologic structure developed in the corresponding zone. That is, it relates to the fault in the 3rd zone, the intrusion. of granite in the 1st and 5th zones, and mountains in the 2nd and 4th zones.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.9
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• pp.1139-1150
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• 1999

The evolution of silica aggregate particles in coflow diffusion flames has been studied experimentally using light scattering and thermophoretic sampling techniques. The measurements of scattering cross section from $90^{\circ}$ light scattering have been utilized to calculate the aggregate number density and volume fraction using with combination of measuring the particle size and morphology through the localized sampling and a TEM image analysis. Aggregate or particle number densities and volume fractions were calculated using Rayleigh-Debye-Gans and Mie theory for fractal aggregates and spherical particles, respectively. Of particular interests are the effects of flame temperature on the evolution of silica aggregate particles. As the flow rate of $H_2$ increases, the primary particle diameters of silica aggregates have been first decreased, but, further increase of $H_2$ flow rate causes the diameter of primary particles to increase and for sufficiently larger flow rates, the fractal aggregates finally become spherical particles. The variation of primary particle size along the upward jet centerline and the effect of burner configuration have also been studied.

• Journal of the Korean earth science society
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• v.38 no.3
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• pp.173-181
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• 2017

The stability of the steady Rossby-Haurwitz wave (R-H wave) in the nondivergent barotropic model (NBM) on the sphere was investigated with the normal mode method. The linearized NBM equation with respect to the R-H wave was formulated into the eigenvalue-eigenvector problem consisting of the huge sparse matrix by expanding the variables with the spherical harmonic functions. It was shown that the definite threshold R-H wave amplitude for instability could be obtained by the normal mode method. It was revealed that some unstable modes were stationary, which tend to amplify without the time change of the spatial structure. The maximum growth rate of the most unstable mode turned out to be in almost linear proportion to the R-H wave amplitude. As a whole, the growth rate of the unstable mode was found to increase with the zonal- and total-wavenumber. The most unstable mode turned out to consist of more-than-one zonal wavenumber, and in some cases, the mode exhibited a discontinuity over the local domain of weak or vanishing flow. The normal mode method developed here could be readily extended to the basic state comprised of multiple zonalwavenumber components as far as the same total wavenumber is given.

• Journal of the Korea Concrete Institute
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• v.12 no.4
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• pp.103-111
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• 2000

The influence of the improvement of grain shape of the coarse aggregate to the unit powder content of concrete and the fine aggregate ratio for the increase of the flowability and segregation resistance of high performance concrete was examined. According to the experimental results, flowability and compacting of concrete presents best states in the S/a which has the smallest 패야 ratio. The coarse aggregate after improvement of grain shape, that has changed from the 0.68 of spherical rate of disk shape to 0.73, led fine aggregate ratio to be down 6% (i.e from 47% to 41%). The improvement of grain shape of the coarse aggregate also led the lowest unit powder content to be down 60kg/㎥ (ie from 530kg/㎥ to 470kg/㎥). And approximate 10% of unit water content has been reduced as unit powder content was down. However, the compressive strength after the improvement of grain shape of the coarse aggregate decreased to 5% due to decrease of adhesiveness of the aggregate and cement paste.

• Korean Journal of Materials Research
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• v.11 no.9
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• pp.763-768
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• 2001

Molybdenum-based thermal spray powder is widely used for coating the moving parts of the internal combustion engines due to its excellent wear resistance. A composite powder of the $Mo_{40}(Al_{1-x}Si_x)_{60}$ system was synthesized using the SHS method. The synthesized bulk was pulverized and specially treated to produce thermal spray powder. It was found that the synthesis reaction consisted of two-steps: the formation of $Al_8/Mo_3$ and the formation of Mo(Al,Si)$_2$. Both the temperature and the rate of the SHS reaction linearly increased with the increase of the value of x in $Mo_{40}(Al_{1-x}Si_x)_{60}$, The temperature and the rate of the reaction were also affected by the compacting density of the specimens, exhibiting the maximum valves at 62% and 60%, respectively. Since spherical shape is advantageous to the thermal spraying process, shape-control of the powder was attempted with PVA as a binding additive, resulting in the successful production of almost perfectly spherical powder of 80 $\mu\textrm{m}$ Ø$(d_{50})$ mean particle size.

• Journal of the Korean Electrochemical Society
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• v.10 no.4
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• pp.252-256
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• 2007

A series of spherical porous carbons were prepared via resorcinol-formaldehyde (RF) sol-gel polymerization in the presence of cationic surfactant (CTAB, cetyltrimethylammonium bromide), wherein the carbon sphere size was controlled by varying the CTAB introduction time after a pre-determined period of addition reaction (termed as "pre-curing"). The sphere size gradually decreases with an increase in the pre-curing time within the range of 30-150 nm. The carbons possess two types of pores; one inside carbon spheres (intra-particle pores) and the other at the interstitial sites made by carbon spheres (inter-particle pores). Of the two, the surface exposed on the former was dominant to determine the electric double-layer capacitor (EDLC) performance of porous carbons. As the intra-particle pores were generated inside RF gel spheres by gasification, the pore diameter was similar for all these carbons, thereby the pore length turned out to be a decisive factor controlling the EDLC performance. The charge-discharge voltage profiles and complex capacitance analysis consistently illustrate that the smaller-sized RF carbons deliver a better rate capability, which must be the direct result of facilitated ion penetration into shorter pores.

• Geomechanics and Engineering
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• v.31 no.3
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• pp.281-289
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• 2022

Bio-CaCO₃ is a blowout environment-friendly materials for soil improvement and sealing of rock fissures. To evaluate the chemical characteristics, shape, size and productivity of soybean urease induced CaCO₃ precipitates (SUICP), experimental studies were conducted via EDS, XRD, FT-IR, TGA, BET, and SEM. Also, the conversion rate of SUICP reaction at different time were determined and analyzed. The Bio-CaCO₃ product obtained by SUICP is comprehensively judged as calcite based on the results of EDS, XRD and FT-IR. The SUICP calcite precipitates are detected as spherical or ellipsoidal particles 3-6 ㎛ in diameter with nanoscale pores on their surface, and this morphology is novel. The median secondary particle size d₅₀ is 39-88 ㎛, indicating the agglomeration of the primary calcite particles. The Bio-calcite decomposes at 650-780℃, representing a medium thermal stability. The conversion rate of SUICP reaction can reach 80% in 24h, which is much more efficient than microbially induced CaCO₃ precipitation. These results reveal the knowledges of SUICP, and further direct its engineering applications. Moreover, we show an economic channel to obtain porous spherical calcite.

• Journal of the Korean earth science society
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• v.37 no.2
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• pp.107-116
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• 2016

Stability of the barotropic Rossby-Haurwitz wave is investigated using the numerical models on the global domain. The Rossby-Haurwitz wave under investigation is composed of the basic zonal flow of super-rotation and a finite amplitude spherical harmonic wave. The Rossby-Haurwitz wave is given as either steady or unsteady wave by adjusting the strength of the super-rotating zonal flow. Stability as well as the growth rate of the wave in the numerical simulation is determined by comparing the perturbation amplitude at two different time stages. Unstable modes of the Rossby-Haurwitz wave exhibited a horizontal structure composing of various zonal-wavenumber components. The vorticity perturbation for some modes showed a discontinuity around the area of weak flow, which was found robust regardless of the horizontal resolution of the model. Fourier finite element model was shown to generate the unstable mode in earlier stage of the time integration due to less accuracy compared to the spherical harmonic spectral model. Taking the overall accuracy of the models into consideration, the time by which the unstable mode begin to dominate over the spherical harmonic wave was estimated.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.10
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• pp.1229-1237
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• 2013

In this study, the theory of spherical indentation based on incremental plasticity is extended to an indentation method for evaluating creep properties. Through finite element analysis (FEA), the point where the elastic strain effect is negligible and the creep strain gradient constant is taken as the optimum point for obtaining the equivalent strain rate and stress. Based on FE results for spherical indentation with various values of creep exponent and creep coefficient, we derive by regression an equation to calculate creep properties using two normalized variables. Finally a program is generated to calculate creep exponent and creep coefficient. With this method, we obtain from the load-depth curve creep exponents with an average error of less than 1.5 % and creep coefficients with an average error of less than 1.0 %.