• Title/Summary/Keyword: spectroscopic method

검색결과 527건 처리시간 0.028초

Effective Characterization Methods of Polycrystalline Silicon Films Fabricated by Ni Induced Crystallization

  • Koo, Hyun-Woo;Maidanchuk, Ivan;Jung, Jae-Wan;Lee, Ki-Yong;Berkeley, Brian H.;Kim, Sang-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.250-253
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    • 2009
  • Effective methods for monitoring the quality of polycrystalline silicon (poly-Si) films are discussed. Raman spectroscopy is typically used to determine crystallinity of poly-Si, but this method has limitations for data gathering on large substrates for mass production of poly-Si TFT backplanes. Spectroscopic ellipsometry is proposed as an alternative for fast and simple estimation of poly-Si quality on large substrates. By using both ellipsometry and Raman spectroscopy, it is possible to determine whether the quality and uniformity of the poly-Si films meet the criteria required for mass production of TFT backplanes for AMOLED panels.

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고분자물질과 접촉한 자기조립단분자막 전극 물질의 기계화학 현상 분광학적 연구 (Mechanochemistry on Self-Assembled Monolayer(SAM) /Electrodes after Contacting with Polymeric Stamp)

  • 윤창석
    • 한국표면공학회지
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    • 제53권5호
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    • pp.265-270
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    • 2020
  • We investigated mechanochemical radical, which is concomitant with chemical lift-off lithography(CLL), on the self-assembled monolayer(SAM)/electrodes and a polydimethylsiloxane(PDMS) using a colorimetric and a spectroscopic method. The 11-mercaptoundecanol(MUO)/Au or the 11-hydroxyundecylphosphonic acid (HUPA)/ITO were contacted with bare or activated PDMS. After contact, the each of SAM/substrates and the PDMS were immersed in a 2,2 Diphenyl-1-picrylhydrazyl(DPPH) radical scavenger. The color of the DPPH exposed to the PDMS was changed from purple to yellow and the absorbance decreased definitely at 515 nm wavelength. The SAM/substrates, however, have caused small changes in spectroscopic property, indicating no existence of radical species. We concluded that mechanochemical radicals were formed by homolytic cleavage of PDMS molecules upon external force and hardly transferred on the SAM/substrates.

Spectroscopic Analysis of Gain Bandwidth in Raman Amplifier with Multiwavelength Pumping Scheme Using Actual Band Model

  • Felinskyi, Georgii;Han, Young-Geun;Lee, Sang-Bae
    • Journal of the Optical Society of Korea
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    • 제8권4호
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    • pp.156-162
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    • 2004
  • The spectroscopic model is proposed to analyze the gain bandwidth of a fiber Raman amplifier (FRA) with a multiple wavelength pumping scheme based on Raman gain theory. The oscillatory lineshape, which is the analytic function to analyze Raman gain spectra, allows us to estimate the gain bandwidth of the FRA. Based on the proposed theoretical modeling, we design and analyze the characteristics of the FRA using the combined multiwavelength pumping sources. We achieved the extended gain bandwidth of the FRA over 80 nm with the small gain ripple less than 0.5 dB. Threshold pumping power and effective noise figure for the FRA can be also analyzed by using the proposed model, which is also applicable for versatile fibers with other doping materials. The proposed analysis method can be useful for the design of FRA with the multiwavelength pumping scheme.

레이저 국소증착에 의한 탄소 미세 구조물 제조 및 분광분석 (Fabrication of micro carbon structures using laser-induced chemical vapor deposition and Raman spectroscopic analysis)

  • 한성일;김진범;;정성호
    • 한국레이저가공학회지
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    • 제5권2호
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    • pp.17-22
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    • 2002
  • Characteristics of micro carbon structures fabricated with laser-induced chemical vapor deposition (LCVD) are investigated. An argon ion laser (λ=514.5nm) and ethylene gas were utilized as the energy source and precursor, respectively. The laser beam was focused onto a graphite substrate to produce carbon deposit through thermal decomposition of the precursor. Average growth rate of a carbon rod increased for increasing laser power and pressure. Micro carbon rods with good surface quality were obtained at near the threshold condition. Micro carbon rods with aspect ratio of about 100 and micro tubular structures were fabricated to demonstrate the possible application of this method to the fabrication of three-dimensional microstructures. Laser Raman spectroscopic analysis of the micro carbon structures revealed that the carbon rods are consisting of amorphous carbon.

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Studies in Remote Functionalization (Ⅰ). Synthesis and Spectroscopic Studies of 3$\alpha$, 5$\alpha$-Cyclosteroidal Substrates

  • Lee, Eun;Park, Sang-Kyu;Lee, Hee-Yoon;Kim, Wan-Joo
    • Bulletin of the Korean Chemical Society
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    • 제2권3호
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    • pp.105-112
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    • 1981
  • Various $3{\alpha}$, $5{\alpha}$-cyclocholestan-6${\beta}-yl$ ethers were synthesized from solvolysis reactions of cholesteryl tosylate. ${3\alpha}$, $5{\alpha}$-Cyclocholestan-6${\beta}-yl$ sulfides were the sole products when cholesteryl tosylate was solvolyzed in thiol solvents. Diol solvolysis products were derivatized to aromatic esters, and nuclear magnetic resonance spectroscopic method was used to show that aromatic rings can approach C-18 methyl group and the side chain.

Synthesis and spectroscopic characterization of zinc ferrite nanoparticles

  • Arora, Shefali;Nandy, Subhajit;Latwal, Mamta;Pandey, Ganesh;Singh, Jitendra P.;Chae, Keun H.
    • Advances in nano research
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    • 제13권5호
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    • pp.437-451
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    • 2022
  • Synthesis approaches usually affect the physical and chemical properties of ferrites. This helps ferrite materials to design them for desired applications. Some of these methods are mechanical milling, ultrasonic method, micro-emulsion, co-precipitation, thermal decomposition, hydrothermal, microwave-assisted, sol-gel, etc. These methods are extensively reviewed by taking example of ZnFe2O4. These methods also affect the microstructure and local structure of ferrite which ultimately affect the physical and chemical properties of ferrites. Various spectroscopic techniques such as Raman spectroscopy, Fourier Transform Infrared spectroscopy, Ultra Violet-Visible spectroscopy, Mossbauer spectroscopy, extended x-ray absorption fine structure, and electron paramagnetic resonance are found helpful to reveal this information. Hence, the basic principle and the usefulness of these techniques to find out appropriate information in ZnFe2O4 nanoparticles is elaborated in this review.

니코틴의 미량 정량법 (Determination of Microquantities of Nicotine)

  • 김찬호;김신일
    • 한국연초학회지
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    • 제3권2호
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    • pp.77-81
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    • 1981
  • A flew spectroscopic method was developed to determine microquantities of nicotine with cyanogen chloride and pyrazolon. Absorption maximum of tile derivative solution appeared at 520nm. The color formed in the proposed method was stable for at least 30 min. at pH 7.5, and followed the Lambert-Beer's law between tile limits of 1 and 5 micrograms of nicotine. The relative errors in burley and flue-cured tobacco leaves were $\pm5%$ in comparison with the Griffith method.

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부분최소제곱회귀(Partial Least Squares Regression) 이론과 분광학적 혈중 헤모글로빈 진단에의 응용 (Partial least squares regression theory and application in spectroscopic diagnosis of total hemoglobin in whole blood)

  • 김선우;김연주;김종원;윤길원
    • 응용통계연구
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    • 제10권2호
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    • pp.227-239
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    • 1997
  • 분광학분야에서 측정되는 자료는 여러 파장에서 측정된 스펙트럼 행렬과 이 스펙트럼을 통하여 알고자하는 어떤 반응치들의 행렬 또는 벡터로 주어진다. 이 경우 측정 자료에의 많은 잡음(noise)과 파장간의 상관관계가 내재한다. 부분최소제곱회귀 방법은 여러 개의 파장에서 측정된 자료를 모두 이용하는데 자료축약과정을 통하여 자료의 잡음 문제와 상관관계 문제를 해결하는 다변량통계방법이다. 본 연구에서는 이러한 자료에 적합한 부분최소제곱회귀의 이론을 알아보고 실제로 측정된 자료를 통하여 주어진 스펙트럼에 대한 반응치의 예측을 부분최소제곱회귀 방법을 이용하여 고찰하였다.

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