• 제목/요약/키워드: spectroscopic change

검색결과 136건 처리시간 0.075초

Rotating Compensator Spectroscopic Ellipsometer의 개발 및 응용 (Development and Application of Rotating Compensator Spectroscopic Ellipsometer)

  • 이재호;방경윤;박준택;오혜근;안일신
    • 반도체디스플레이기술학회지
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    • 제2권2호
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    • pp.1-4
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    • 2003
  • We have developed a rotating compensator spectroscopic ellipsometer (RCSE). As the ellipsometry measures a change in the polarization state of a light wave upon non-normal reflection from surface, the degree of sensitivity is enhanced greatly through the detection of relative phase change. RCSE acquires additional information from the non-ideal surface of sample and operates over the photon energy range from 1.5 to 4.5 eV. We applied RCSE to measure the optical properties of films and the line-width of patterned PR films on crystalline silicon.

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A NEW ALTERNATIVE ELLIPTIC PDE IN EIT IMAGING

  • Kim, Sungwhan
    • 대한수학회보
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    • 제49권6호
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    • pp.1291-1302
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    • 2012
  • In this paper, we introduce a new elliptic PDE: $$\{{\nabla}{\cdot}\(\frac{|{\gamma}^{\omega}(r)|^2}{\sigma}{\nabla}v_{\omega}(r)\)=0,\;r{\in}{\Omega},\\v_{\omega}(r)=f(r),\;r{\in}{\partial}{\Omega},$$ where ${\gamma}^{\omega}={\sigma}+i{\omega}{\epsilon}$ is the admittivity distribution of the conducting material ${\Omega}$ and it is shown that the introduced elliptic PDE can replace the standard elliptic PDE with conductivity coefficient in EIT imaging. Indeed, letting $v_0$ be the solution to the standard elliptic PDE with conductivity coefficient, the solution $v_{\omega}$ is quite close to the solution $v_0$ and can show spectroscopic properties of the conducting object ${\Omega}$ unlike $v_0$. In particular, the potential $v_{\omega}$ can be used in detecting a thin low-conducting anomaly located in ${\Omega}$ since the spectroscopic change of the Neumann data of $v_{\omega}$ is inversely proportional to thickness of the thin anomaly.

수소화된 비정질 실리콘의 타원편광분광분석 측정 및 모델링 (Spectroscopic Ellipsometry Measurement and Modeling of Hydrogenated Amorphous Silicon)

  • 김가현
    • 한국태양에너지학회 논문집
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    • 제39권1호
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    • pp.11-19
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    • 2019
  • Spectroscopic ellipsometry is a powerful tool for analyzing optical properties of material. Ellipsometry measurement results is usually given by change of polarization state of probe light, so the measured result should be properly treated and transformed to meaningful parameters by transformation and modeling of the measurement result. In case of hydrogenated amorphous silicon, Tauc-Lorentz dispersion is usually used to model the measured ellipsometry spectrum. In this paper, modeling of spectroscopic ellipsometry result of hydrogenated amorphous silicon using Tauc-Lorentz dispersion is discussed.

RGB 화상테이터를 이용한 CRT 표현색의 CIELab 표색계로의 변화에 관한 연구 (CRT Color Transform to CIELab Color System using RGB Image Data)

  • 안석출
    • 한국인쇄학회지
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    • 제13권1호
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    • pp.73-91
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    • 1995
  • Spectroscopic and Photoelectric Characteristics in the Cyanine and Merocyanine Dye according to systematically change of their structures were experimentally discussed. As result, in solution, Hetero atoms(X) of Cyanine and Merocyanine dye were participated in resonance X of d obital rather than X of pobital,effected in resonance and contributed in extension of conjugated system. in solid film,new spectra,called eximer-fluorenscence,were appeared in 3-dimensional fluorenscence of high density of Cyanine dye but not of Merocyanine. The activational energy of conductivity in Merocyanine dye was lower than in cyanine, an the contrary,the drift mobility was higher and the former in photoelectric characteristics was more effec-tive than the latter. In this paper,authors invertigated the changes of dye structure by molecular obital method to confirm the results of spectroscopic and photoelectric characteristics in the Cyanine and Merocyanine Dye acco-rding to systematically cally change of their structure, and counted total energy on dihedral angle and dipol miments if dyes in S0 and S1.

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Investigation on the Interaction of Gabapentin with Bovine Serum Albumin by Spectroscopic Techniques

  • Ashoka, S.;Seetharamappa, J.;Kandagal, P.B.;Shaikh, S.M.T.
    • Journal of Photoscience
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    • 제12권3호
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    • pp.113-117
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    • 2005
  • Spectroscopic investigations on the interaction of gabapentin (GBP) with bovine serum albumin (BSA) were reported. The association constant of GBP-BSA system was determined at different temperatures (298, 302, 306 and 311 K) based on the fluorescence quenching results. The GBP was found to quench the fluorescence of BSA through static mechanism. Thermodynamic parameters, the standard enthalpy change, $({\Delta}H^o)$ and the standard entropy change $({\Delta}S^o)$ were observed to be $-9.61{\pm}0.008\;kJ\;mol^{-1}$ and $3.58{\pm}0.011\;Jmol^{-1}K{-1}$ respectively. These indicated that the hydrophobic and electrostatic forces played a role in the interaction of GBP with BSA. The negative value of ${\Delta}G^o$ revealed that the binding reaction is spontaneous. The circular dichroism studies indicated the conformational changes in BSA upon interaction with GBP. The effect of some metal ions on the binding constant was also investigated.

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분광분석을 통한 지르콘의 메타믹상태와 색상 변화 분석 (A study on the metamictization and color change in zircon by spectroscopic analysis)

  • 김성기;안용길;서진교;김종근;박종완
    • 한국결정성장학회지
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    • 제20권1호
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    • pp.12-20
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    • 2010
  • 캄보디아와 탄자니아산 지르콘을 대상으로 메타믹상태와 색상변화에 대한 연구를 하였다. 이를 위해 U, Th 등의 방사성원소 검출을 위한 원소분석과 분광분석(UV-VIS 분광기, FTIR분광기)을 하였다. UV-VIS 분광분석 결과 청색과 무색에서는 고온형의 특징인 많은 흡수 피크들과 세기가 높게 나타났으며 우라늄이 검출된 녹색과 황색 시료에서는 흡수 피크들의 수가 현저히 적게 나타나 메타믹화가 진행되었음을 알 수 있었다. 열처리 후에는 반대의 결과가 나왔다. FTIR 분광 분석 결과 3100~3400 $cm^{-1}$ 영역에서 $[SiO_4]^{4-}$ 내부 진동의 3-포논 조합 모드 밴드들이 메타믹화된 녹색과 황색의 지르콘에서는 완만하며 없어진 밴드들도 있으나 열처리 후에는 다시 결정격자가 원상태로 회복되어 사라졌던 밴드들이 나타났다. 또한 지르콘에 우라늄이 함유되어 있는지를 알 수 있는 4800 $cm^{-1}$ 근처에서 $U^{4+}$의 피크가 녹색과 황색 시료에서 확인 되었다. 연구 결과 분광분석 과 열처리 실험으로 지르콘에 우라늄의 함유가 메타믹상태와 칼라의 변화에 미치는 영향을 확인할 수 있었다.

DETECTION OF PHYSIOLOGICAL PROCESSES IN WHEAT BY NIR

  • Salgo, A.;Gergely, Sz.;Scholz, E.
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1158-1158
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    • 2001
  • Fast and dynamic biochemical, enzymatic and morphological changes occur during the so-called generative development and during the vegetative processes in seeds. The most characteristic biochemical and compositional changes of this period are the formation and decline of storage components or their precursors, the change of their degree in polymerization and an extensive change in water content. The aim of the present study was to detect the maturation processes in seed nondestructively and to verify the applicability of near infrared spectroscopic methods in the measurement of physiological, chemical and biochemical changes in wheat seed. The amount and variation of different water “species” has been changed intensively during maturation. Characteristic changes of three water absorption bands (1920, 1420 and 1150 nm) during maturation were analysed. It was concluded that the free/bound transition of water molecules could be followed sensitively in different region of NIR spectra. Kinetic changes of carbohydrate reserves were characteristic during maturation. An intensive formation and decline of carbohydrate reserves were observed during early stage of maturation (0 -13 days, high energy demand). An accelerated formation of storage carbohydrates (starch) was detected in the second phase of maturation. Five characteristic absorption bands were analysed which were sensitive indicators the changes of carbohydrates occurred during maturation. Precursors of protein synthesis and the synthesis of reserve proteins and their kinetic changes during maturation were followed from NIR spectra qualitative and qualitatively. Dynamic formation of amino acids and the changes of N forms were detected by spectroscopic, chromatographic and by capillary electrophoresis methods. Calibration equations were developed and validated in order to measure the optimal maturation time protein and moisture content of developing wheat seeds. The spectroscopic methods are offering chance and measurement potential in order to detect fine details of physiological processes. The spectra have many hidden details, which can help to understand the biochemical background of processes.

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박테리오파지 f2에 대한 자외광선의 살균효과 (The Inactivation Effects of UV Light on Bacteriophage f2)

  • Kim, Chi-Kyung;Quae Chae
    • 한국미생물·생명공학회지
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    • 제11권3호
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    • pp.155-161
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    • 1983
  • Bacteriophage f2에 대한 자외광선의 살균효과와 외투막 단백질의 구조에 미치는 영향을 Ray-onet photoreactor PPR-208을 사용하여 300nm의 광선으로 연구하였다. 처음 20분간의 조사에서는 약 4 log의 phage가 감소되고 그후 완만한 살균효과를 보이다가 90분 이상의 조사에서는 생존 바이러스가 발견되지 않았다. Tryptophan residue의 fluorescenve quenching, 자외선으로 조신한 phage에 부착시킨 ANS (8-anilino-1-napht-halene sulfonate)의 fluorescence emission의 감소, tryptophan에서 ANS로의 energy transfer 의 감소 등 spectroscopic technique에 의한 결과와 자외선 조사에 의하여 단백질 외투만이 파손되는 전자현미경 관찰의 결과에 의하여 자외광선은 phage f2의 외투막 단백질의 구조에 변화를 일으킨다는 것이 밝혀졌다.

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Initial Photometric and Spectroscopic Characteristics of 55-inch CCFL and LED Backlights for LCD-TV Applications

  • Ko, Jae-Hyeon;Ryu, Jin-Sun;Yu, Mi-Yeon;Park, Seung-Mi;Kim, Su-Jin
    • 조명전기설비학회논문지
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    • 제24권3호
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    • pp.8-13
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    • 2010
  • For better picture quality in LCD TVs, it is important to reach a steady emitting state within as short a time as possible in the initial stage after the TV is turned on. The initial characteristics of LCD TVs are mainly determined by the properties of the backlight. In the present study, the photometric and spectroscopic properties of a 55-inch Cold Cathode Fluorescent Lamp (CCFL) and Light Emitting Diode (LED) backlights were investigated. The measured properties include time dependence of the spectrum, luminance, and color coordinates. The results show that the change in the spectroscopic properties of the LED backlight is smaller than that of the CCFL backlight. This indicates that the initial picture quality of the LCD TV with the LED backlight is superior to that with the CCFL backlight. The origins of this difference were discussed in relation to the inherent characteristics of the two light sources.

간섭기반 스냅샷 분광편광위상측정의 열 안정성 분석 (Thermal stability analysis of interferometric snapshot spectro-polarimeter)

  • 최인호;뎀베레바마라;제야쿠마르폴마단;최석현;김준호;백병준;김대석
    • 반도체디스플레이기술학회지
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    • 제17권3호
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    • pp.70-74
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    • 2018
  • In typical spectroscopic ellipsometry, the optical and geometrical properties of thin film and nano pattern can be obtained by measuring the polarization state of light reflected/transmitted from the object by rotating a analyzer or a compensator. We proposed a snapshot spectroscopic ellipsometric system based on a modified Michelson interferometer to overcome the time-consuring measurement principle due to rotating part. The proposed system provides spectral ellipsometric parameters (psi, delta) in real time by using a single spectral interference signal generated in the interferometric polarization module. However, it has a long-term stability problem resulting in delta(k) drift. In this paper, it is experimentally proved that the drift problem is caused by anisotropic refractive index change of the beam intersection layer in beam splitter of interferometer.