• Title/Summary/Keyword: spectral peak

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The Compensation of the Energy Dependence of TLD (열형광선량계(熱螢光線量計)의 에너지의존성(依存性) 보상(補償))

  • Park, Myeong-Hwan;Lee, Joon-Il;Kwon, Duk-Moon
    • Journal of radiological science and technology
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    • v.16 no.2
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    • pp.51-60
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    • 1993
  • The $CaSO_4$ : Tm-PTFE TLDs have been prepared and their energy dependences of TL intensity to X-rays have been investigated. The dose dependence of the prepared $CaSO_4$ : Tm-PTFE TLDs is linear within the range of $100{\mu}Gy-10Gy$ for X-rays and gamma rays. The spectral peaks of TL emission spectrum are at about 350nm and 475nm. The fading rate of the main peak has been found to be about 2% for 30days when $CaSO_4$ : Tm-PTFE TLDs stored in the dark room at room temperature. The energy dependence of $CaSO_4$ : Tm-PTFE TLD has been compensated by combining the TL responses of one bare TLD and five TLDs filtered with 1.0mm Al, 0.2mm Cu, 0.5mm Cu, 1.5mm Cu, 2.0mm Pb respectively. The determined correction coefficients for filter combination are $a_0=0.078,\;a_1=-0.009,\;a_2=-0.235,\;a_3=0.588,\;a_4=0.568\;and\;a_5=0.180$ respectively. From the results of these studies, the prepared TLD badge of six dosimeter combination may be useful as a radiation dosimeter for personal and environmental monitoring.

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Toxin Produced by Colletotrichum falcatum Causing Red Rot of Sugarcane

  • Saikia, R.;Azad, P.;Arora, D.K.
    • Mycobiology
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    • v.32 no.4
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    • pp.149-154
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    • 2004
  • Toxin produced by Colletotrichum falcatum Went, the incitant of red rot of sugarcane was isolated, purified and assayed to determine host specificity and identify its chemical nature. The toxin was found to be not host specific as it inhibited germination of various seeds(gram, greengram, blackgram, pea, cowpea, rice and sugarcane) as well as different seedlings viz. tomato, coriander, pea and rice. The toxin consists of two distinct fraction-one fraction having $R_f$, value at 0.36 producing identical red rot lesion when inoculated at leaf midrib of sugarcane, and the other having $R_f$, value at 0.72 not showing any red rot lesion. Chromatogram of high performance liquid chromatography(HPLC) of the red rot lesion causing fraction showed a sharp peak at 1.62 min of retention time(RT), and spectral analysis indicated the presence of following chemical $CH_3$ - groups-C-H, C=O, C-N, $-CH_3,\;-CH_2$ -CH and molecular mass of the compound was 203. - ($M^+,\;C_{11}H_{11}N_2O_2$).

Synthesis and Application of the Novel Azomethine Metal Complexes for the Organic Electroluminescent Devices

  • Kim, Seong Min;Kim, Jin Sun;Sin, Dong Myeong;Kim, Yeong Gwan;Ha, Yun Gyeong
    • Bulletin of the Korean Chemical Society
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    • v.22 no.7
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    • pp.743-747
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    • 2001
  • New azomethine metal complexes were synthesized systematically and characterized. Beryllium, magnesium, or zinc ions were used as a central metal cation and aromatic azomethines (L1-L4) were employed as a chelating anionic ligand. Emission peaks o f the complexes in both solution and solid states were observed mostly at the region of 400-500 nm in the luminescence spectra, where blue light was emitted. Three of them (BeL1 (Ⅰ), ZnL2 (Ⅱ), and ZnL3 (Ⅲ)) were sublimable and thus were applied to the organic light-emitting devices (OLED) as an emitting layer, respectively. The device including the emitting layer of Ⅰ exhibited white emission with the broad luminescence spectral range. The device with the emitting layer of Ⅱ showed blue luminescence with the maximum emission peak at 460 nm. Their ionization potentials, electron affinities, and electrochemical band gaps were investigated with cyclic voltammetry. The electrochemical gaps of 2.98 for I, 2.70 for Ⅱ, and 2.63 eV for Ⅲ were found to be consistent with their respective optical band gaps of 3.01, 2.95 and 2.61 eV within an experimental error. The structure of OLED manufactured in this study reveals that these complexes can work as electron transporting materials as well.

Studying the Park-Ang damage index of reinforced concrete structures based on equivalent sinusoidal waves

  • Mazloom, Moosa;Pourhaji, Pardis;Shahveisi, Masoud;Jafari, Seyed Hassan
    • Structural Engineering and Mechanics
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    • v.72 no.1
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    • pp.83-97
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    • 2019
  • In this research, the vulnerability of some reinforced concrete frames with different stories are studied based on the Park-Ang Damage Index. The damages of the frames are investigated under various earthquakes with nonlinear dynamic analysis in IDARC software. By examining the most important characteristics of earthquake parameters, the damage index and vulnerability of these frames are investigated in this software. The intensity of Erias, velocity spectral intensity (VSI) and peak ground velocity (PGV) had the highest correlation, and root mean square of displacement ($D_{rms}$) had the lowest correlation coefficient among the parameters. Then, the particle swarm optimization (PSO) algorithm was used, and the sinusoidal waves were equivalent to the used earthquakes according to the most influential parameters above. The damage index equivalent to these waves is estimated using nonlinear dynamics analysis. The comparison between the damages caused by earthquakes and equivalent sinusoidal waves is done too. The generations of sinusoidal waves equivalent to different earthquakes are generalized in some reinforced concrete frames. The equivalent sinusoidal wave method was exact enough because the greatest difference between the results of the main and artificial accelerator damage index was about 5 percent. Also sinusoidal waves were more consistent with the damage indices of the structures compared to the earthquake parameters.

Effects of Semi-Occluded Vocal Tract Exercise in Patients with Functional Aphonia (반폐쇄성도훈련이 기능적 실성증 환자의 음성 개선에 미치는 효과)

  • Chae, Hye Rim;Kim, Ji sung;Lee, Dong Wook;Choi, Soeng Hee
    • Journal of the Korean Society of Laryngology, Phoniatrics and Logopedics
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    • v.30 no.1
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    • pp.48-52
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    • 2019
  • Background and Objectives : Functional aphonia is characterized by incomplete closure of the vocal folds. Semi-occluded vocal tract exercise (SOVTE) allows smoothly vocal folds collision without damage to the vocal folds tissues to produce normal vocal intensity. The purpose of this study is to report the effect of SOVTE in patients with functional aphonia. Materials and Method : Seven patients diagnosed with functional aphonia were treated with 1-3 voice therapy sessions using voiced lip-trill, humming, Lax Vox in SOVTE. To assess the effectiveness of semi-occluded vocal tract exercise, cepstral analysis and auditory perceptual assessment were performed before and after voice therapy. Results : F0 (fundamental frequency), CPP (cepstral peak prominence) and L/H ratio (low/high spectral ratio) were significantly increased, while CPP Standard deviation, L/H ratio Standard deviation were decreased. In addition, 'Grade', 'Breathiness' and 'Asthenia' were significantly decreased in the GRBAS scale after SOVTE (p<0.05). Conclusion : In our study, SOVTE seemed to be effective to elicit voice quickly and promote vocal folds vibration without muscular effort in patients with functional aphonia.

The effect of the Modified Voiced Lip Trill (MVoLT) training on vocal changes of musical theater students (응용 입술 트릴 훈련이 뮤지컬 전공 학생의 음성 변화에 미치는 효과)

  • Lee, Seung Jin;Choi, Hong-Shik;Lim, Jae-Yol;Lee, Kwang Yong
    • Phonetics and Speech Sciences
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    • v.10 no.4
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    • pp.135-146
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    • 2018
  • The Modified Voiced Lip Trill (MVoLT) training is a variant of voiced lip-till training characterized by increased loudness, lowered laryngeal position, and lip contact facilitated with fingers. The purpose of the current study was to assess the effect of the MVoLT training program on vocal changes of musical singing theater students. A total of 32 musical theater students (17 males and 15 females, age ranging from 18 to 29) participated in the study. For about three months, each participant was tutored using a systematic program focussing on the MVoLT training, accompanied by certain facilitating strategies. Pre- & post-training multi-dimensional vocal characteristics were assesed and compared. Results showed that cepstral peak prominence during vowel phonation increased after training, while its standard deviation and Cepstral Spectral Index of Dysphonia decreased. When an aerodynamic assessment was performed, maximum phonation time, subglottal pressure, mean airflow rate increased, while electroglottographic measures did not change. In addition, decreased psychometric measures, higher maximum pitch, and increased vocal range were noted after training. In conclusion, the MVoLT was proven to have a potential as an effective and safe training method for musical theater singing.

Searching for Spectrally Variable AGNs using Multi-epoch Spectra from SDSS

  • Seong, Jiyeon;Kim, Minjin;Kim, Dong-Chan;Yoon, Il-Sang;Shin, Jaejin
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.71.2-71.2
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    • 2021
  • Using multi-epoch spectra of active galactic nuclei (AGN) obtained from the Sloan Digital Sky Survey, we identify 16 spectrally variable sources, for which the spectral shapes of broad emission lines significantly vary with a time scale of yrs. Out of them, 3 AGNs are already known as changing-look (CL) AGNs by previous studies. 6 AGNs are newly identified as CL AGNs from our study. A majority of these AGNs are relatively faint and their variability in the continuum is small, which may explain their non-detection in the previous studies. 7 sources are known as binary AGN candidates based on the systematic velocity offset between broad emission lines and narrow emission lines. For those sources and 3 CL AGNs, we find that the peak of broad emission lines had been shifted up to a few thousands km/s for ~10 years, implying that those can be promising candidates for pc-scale binary AGNs or recoiling black holes. We plan to conduct multiwavelength follow-up studies to nail down the physical origin of the velocity shift.

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Surface-Engineered Graphene surface-enhanced Raman scattering Platform with Machine-learning Enabled Classification of Mixed Analytes

  • Jae Hee Cho;Garam Bae;Ki-Seok An
    • Journal of Sensor Science and Technology
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    • v.33 no.3
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    • pp.139-146
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    • 2024
  • Surface-enhanced Raman scattering (SERS) enables the detection of various types of π-conjugated biological and chemical molecules owing to its exceptional sensitivity in obtaining unique spectra, offering nondestructive classification capabilities for target analytes. Herein, we demonstrate an innovative strategy that provides significant machine learning (ML)-enabled predictive SERS platforms through surface-engineered graphene via complementary hybridization with Au nanoparticles (NPs). The hybridized Au NPs/graphene SERS platforms showed exceptional sensitivity (10-7 M) due to the collaborative strong correlation between the localized electromagnetic effect and the enhanced chemical bonding reactivity. The chemical and physical properties of the demonstrated SERS platform were systematically investigated using microscopy and spectroscopic analysis. Furthermore, an innovative strategy employing ML is proposed to predict various analytes based on a featured Raman spectral database. Using a customized data-preprocessing algorithm, the feature data for ML were extracted from the Raman peak characteristic information, such as intensity, position, and width, from the SERS spectrum data. Additionally, sophisticated evaluations of various types of ML classification models were conducted using k-fold cross-validation (k = 5), showing 99% prediction accuracy.

Comparative Analysis of Structural Damage Potentials Observed in the 9.12 Gyeongju and 11.15 Pohang Earthquakes (9.12 경주지진 및 11.15 포항지진의 구조손상 포텐셜 비교연구)

  • Lee, Cheol-Ho;Kim, Sung-Yong;Park, Ji-Hun;Kim, Dong-Kwan;Kim, Tae-Jin;Park, Kyoung-Hoon
    • Journal of the Earthquake Engineering Society of Korea
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    • v.22 no.3
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    • pp.175-184
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    • 2018
  • In this paper, comparative analysis of the 9.12 Gyeongju and 11.15 Pohang earthquakes was conducted in order to provide probable explanations and reasons for the damage observed in the 11.15 Pohang earthquake from both earthquake and structural engineering perspectives. The damage potentials like Arias intensity, effective peak ground acceleration, etc observed in the 11.15 Pohang earthquake were generally weaker than those of the 9.12 Gyeongju earthquake. However, in contrast to the high-frequency dominant nature of the 9.12 Gyeongju earthquake records, the spectral power of PHA2 record observed in the soft soil site was highly concentrated around 2Hz. The base shear around 2 Hz frequency was as high as 40% building weight. This frequency band is very close to the fundamental frequency of the piloti-type buildings severely damaged in the northern part of Pohang. Unfortunately, in addition to inherent vertical irregularity, most of the damaged piloti-type buildings had plan irregularity as well and were non-seismic. All these contributed to the fatal damage. Inelastic dynamic analysis indicated that PHA2 record demands system ductility capacity of 3.5 for a structure with a fundamental period of 0.5 sec and yield base shear strength of 10% building weight. The system ductility level of 3.5 seems very difficult to be achievable in non-seismic brittle piloti-type buildings. The soil profile of the PHA2 site was inversely estimated based on deconvolution technique and trial-error procedure with utilizing available records measured at several rock sites during the 11.15 Pohang earthquake. The soil profile estimated was very typical of soil class D, implying significant soil amplification in the 11.15 Pohang earthquake. The 11.15 Pohang earthquake gave us the expensive lesson that near-collapse damage to irregular and brittle buildings is highly possible when soil is soft and epicenter is close, although the earthquake magnitude is just minor to moderate (M 5+).

Acoustic Characteristics of Watermelon for Internal Quality Evaluation (내부품질 판정을 위한 수박의 음파특성)

  • 최동수;최규홍;이강진;이영희;김만수
    • Journal of Biosystems Engineering
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    • v.27 no.1
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    • pp.59-66
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    • 2002
  • The objectives of the study were to analyze the acoustic characteristics related to the internal quality factors of watermelon(Citrulus Vulgaris Schrad). Among the various internal quality factors, only four factors such as ripeness, inside cavity, yellow belt and blood flesh were considered in this study. Relationships between the internal quality factors, the day after fruit set and the day after harvest were also investigated. Test apparatus was the same as the apparatus described in the previous study(Choi et at., 2000). The selected sample was divided into four groups; 69 samples used for ripeness tests 56 samples for ripeness test along the day after fruit set and for yellow belt detection, 60 samples for ripeness along the day after harvest 44 samples fur blood flesh detection. It was shown that the first peak frequencies shifted to the lower range and the energy ratios of the bandwidths between 0∼550 Hz to the bandwidths between 850∼2500 Hz increased as the day after fruit set elapsed. Since the acoustic responses of the watermelon such as frequency and magnitude began to change from 10 days after harvest, the storage period of watermelon in a normal temperature condition seemed to be approximately 10 days after harvest. The ratios of the first peak amplitude to the maximum peak amplitude fur the sound watermelon showed the higher value than that fur watermelon with cavity inside, and the separation between the sound and cavity inside could be accomplished by the ratio value of 0.25. The energy ratios (0∼550 Hz/850∼2,500 Hz) for the watermelon with cavity inside showed the higher value than 2.3. The frequency characteristics of the yellow belt watermelon appeared mostly in the range of 600∼900 Hz frequencies. The yellow belt watermelon showing the energy spectral density function at this frequency range to be over 70 seemed to be not a marketable commodity, The energy ratios(0∼550 Hz/850∼2,500 Hz) for the blood flesh watermelon showed the higher value than 3.5.