• Title/Summary/Keyword: spectral mixture

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SHM-based probabilistic representation of wind properties: statistical analysis and bivariate modeling

  • Ye, X.W.;Yuan, L.;Xi, P.S.;Liu, H.
    • Smart Structures and Systems
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    • v.21 no.5
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    • pp.591-600
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    • 2018
  • The probabilistic characterization of wind field characteristics is a significant task for fatigue reliability assessment of long-span railway bridges in wind-prone regions. In consideration of the effect of wind direction, the stochastic properties of wind field should be represented by a bivariate statistical model of wind speed and direction. This paper presents the construction of the bivariate model of wind speed and direction at the site of a railway arch bridge by use of the long-term structural health monitoring (SHM) data. The wind characteristics are derived by analyzing the real-time wind monitoring data, such as the mean wind speed and direction, turbulence intensity, turbulence integral scale, and power spectral density. A sequential quadratic programming (SQP) algorithm-based finite mixture modeling method is proposed to formulate the joint distribution model of wind speed and direction. For the probability density function (PDF) of wind speed, a double-parameter Weibull distribution function is utilized, and a von Mises distribution function is applied to represent the PDF of wind direction. The SQP algorithm with multi-start points is used to estimate the parameters in the bivariate model, namely Weibull-von Mises mixture model. One-year wind monitoring data are selected to validate the effectiveness of the proposed modeling method. The optimal model is jointly evaluated by the Bayesian information criterion (BIC) and coefficient of determination, $R^2$. The obtained results indicate that the proposed SQP algorithm-based finite mixture modeling method can effectively establish the bivariate model of wind speed and direction. The established bivariate model of wind speed and direction will facilitate the wind-induced fatigue reliability assessment of long-span bridges.

Identification of Palustrine Wetlands in Paldang Reservoir Using Spectral Mixture Analysis of Multi-temporal Landsat Imagery (다중시기 위성영상의 분광혼합화소분석에 의한 팔당 상수원보호구역의 소택형 습지 판별)

  • Kim, Sang-Wook;Park, Chong-Hwa
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.7 no.3
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    • pp.48-55
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    • 2004
  • 본 연구는 중 저해상도 위성영상을 이용하여 하천주변 습지를 판별해내는 보다 개선된 기법을 개발해 내는데 그 목적이 있다. 중 저해상도 위성영상의 하나의 화소는 일반적으로 하나의 동질한 물체의 분광반사값을 나타내기보다는 다양한 분광값을 가진 물체들의 대표값으로 나타나게 된다. 특히 본 연구에서는 식생, 수문 및 토양요소의 혼합체인 습지의 판별을 위해서, 하나의 화소가 하나의 물체를 대표함을 전제로 하는 기존의 분석방법 보다는, 혼합화소 (mixed pixel)를 대상지 의 토지 피복을 가장 잘 반영 하는 순수한 화소값(endmember)들로 분해함으로써 보다 정확한 판별 및 분류를 가능케 하고자 하였다. 이를 위하여 일반적으로 극세분광 위성영상의 분석에 활용되는 기법인 분광혼합화소분석(Spectral Mixture Analysis)을 이용하였는데, 습지 각 화소의 식생, 수문 및 토양요소의 흔합정도를 분해한 후, 이들의 분할영상 (fraction images)을 추출해내고 이를 분석에 이용하였다. 팔당상수원보호구역의 소택형 습지를 대상으로 봄 가을의 Landsat 영상에 대한 분석을 수행하였으며, 도출된 결과는 다음과 같다. 첫째, 봄 가을 각각의 영상에 대하여 4개씩 endmember를 선정하였으며, 분할영상과 원자료 각각에 대하여 습지판별을 수행한 결과, 가을영상에 대하여 분할영상을 이용한 방법의 소택 형 습지 판별 정확도가 가장 높은 값을 보여주었다(생산자 정확도 : 83.3%, 사용자 정확도 : 86.5%). 둘째, 소택형 습지로 판별된 지역만을 대상으로 보다 세분화된 분류가 가능한 지 알아보기 위하여 소택형 습지로 판별된 지역의 영상에 대해 ISODATA 무감독분류를 수행한 결과 2개의 클러스터로 대별되었다. 현장조사, 기존 연구의 수심자료 및 식생에 대한 조사를 바탕으로 위의 2개의 클러스터를 조사한 결과, 수문조건에 따른 분류인 아계(subsystem) 단계의 '영구적 침수형 소택형 습지'와 '계절적 침수형 소택형 습지'로 분류할 수 있었다.

Impervious Surface Mapping of Cheongju by Using RapidEye Satellite Imagery (RapidEye 위성영상을 이용한 청주시의 불투수면지도 생성기법)

  • Park, Hong Lyun;Choi, Jae Wan;Choi, Seok Keun
    • Journal of Korean Society for Geospatial Information Science
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    • v.22 no.1
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    • pp.71-79
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    • 2014
  • Most researches have created the impervious surface map by using low-spatial-resolution satellite imagery and are inefficient to generate the object-based impervious map with a broad area. In this study, segment-based impervious surface mapping algorithm is proposed using the RapidEye satellite imagery in order to map impervious area. At first, additional bands are generated by using TOA reflectance conversion RapidEye data. And then, shadow and water class are extracted using training data of converted reflectance image. Object-based impervious surface can be generated by spectral mixture analysis based on land cover map of Ministry of Environment with medium scale, in the case of other classes except shadow and water classes. The experiment shows that result by our method represents high classification accuracy compared to reference data, quantitatively.

Determination of Bi Impurity in Lead Stock Standard Solutions by Hydride-generation Inductively Coupled Plasma Mass Spectrometry

  • Park, Chang J.
    • Bulletin of the Korean Chemical Society
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    • v.25 no.2
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    • pp.233-236
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    • 2004
  • Total impurity analysis of a primary standard solution is one of the essential procedures to determine an accurate concentration of the standard solution by the gravimetry. Bi impurity is determined in Pb standard solutions by inductively coupled plasma mass spectrometry (ICP-MS). The direct nebulization of the Pb standard solution produces a significant amount of the Pb matrix-induced molecular ions which give rise to a serious spectral interference to the Bi determination. In order to avoid the spectral interference from the interferent $^{208}PbH^+$, the hydride generation method is employed for the matrix separation. The Bi hydride vapor is generated by reaction of the sample solution with 1% sodium borohydride solution. The vapor is then directed by argon carrier gas into the ICP after separation from the mixture solution in a liquid-gas separator made of a polytetrafluoroethylene membrane tube. The presence of 1000 ${\mu}$g/mL Pb matrix caused reduction of the bismuthine generation efficiency by about 40%. The standard addition method is used to overcome the chemical interference from the Pb matrix. Optimum conditions are investigated for the hydride-generation ICPMS. The detection limit of this method is 0.5 pg/mL for the sample solutions containing 1000 ${\mu}$g/mL Pb matrix.

Effect of $TiO_2$ in the Lead-Zinc-Borosilicate Solder Glass ($TiO_2$ 의 첨가가 Lead-Zinc-Borosilicate 봉착 유리에 미치는 영향)

  • 채수철;김철영
    • Journal of the Korean Ceramic Society
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    • v.21 no.4
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    • pp.349-354
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    • 1984
  • The purpose of present study is to find the structure crystallization mechanism and physical properties in $TiO_2$ containing lead zinc borosilicate glass system. The experiments such as differential thermal analysis infrared spectral analysis. X-ray diffraction analysis and thermal expansion measurements have been done. Differential thermal analysis of coarse and fine glass powder showed bulk nucleating mechanism for high $TiO_2$ containing glasses and surface nucleation mechanism for low $TiO_2$ containing glasses. The prepared glasses crystallized to crystalline mixture of PbO.2ZnO. $B_2O_3$ .4PbO.2ZnO.$5B_2O_3$and 2PbO.ZnO.$B_2O_3$ when heat-treated in the range of 480 and 51$0^{\circ}C$ and crystallized to PbTiO3 when heat-treated at $600^{\circ}C$. Obtained crystalline phase of $PbTiO_3$ in glass matrix strongly affects to thermal expansion coefficient and the value of crystallized glass varied 68.0 to $107.1{\times}10-7$/$^{\circ}C$ depending on the amount of $TiO_2$added. Infrared spectral analysis showed that [$BO_3$] triangle and [$BO_3$] tetrahedral units were coexisted in the glass with high content of PbO.

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A New Hearing Aid Algorithm for Speech Discrimination using ICA and Multi-band Loudness Compensation

  • Lee Sangmin;Won Jong Ho;Park Hyung Min;Hong Sung Hwa;Kim In Young;Kim Sun I.
    • Journal of Biomedical Engineering Research
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    • v.26 no.3
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    • pp.177-184
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    • 2005
  • In this paper, we proposed a new hearing aid algorithm to improve SNR(signal to noise ratio) of noisy speech signal and speech perception. The proposed hearing aid algorithm is a multi-band loudness compensation based independent component analysis (ICA). The proposed algorithm was compared with a conventional spectral subtraction algorithm on behind-the-ear type hearing aid. The proposed algorithm successfully separated a target speech signal from background noise and from a mixture of the speech signals. The algorithms were compared each other by means of SNR. The average improvement of SNR by ICA based algorithm was 16.64dB, whereas spectral subtraction algorithm was 8.67dB. From the clinical tests, we concluded that our proposed algorithm would help hearing aid user to hear clearly a target speech in noisy conditions.

Speech Enhancement Based on IMCRA Incorporating noise classification algorithm (잡음 환경 분류 알고리즘을 이용한 IMCRA 기반의 음성 향상 기법)

  • Song, Ji-Hyun;Park, Gyu-Seok;An, Hong-Sub;Lee, Sang-Min
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.12
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    • pp.1920-1925
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    • 2012
  • In this paper, we propose a novel method to improve the performance of the improved minima controlled recursive averaging (IMCRA) in non-stationary noisy environment. The conventional IMCRA algorithm efficiently estimate the noise power by averaging past spectral power values based on a smoothing parameter that is adjusted by the signal presence probability in frequency subbands. Since the minimum of smoothing parameter is defined as 0.85, it is difficult to obtain the robust estimates of the noise power in non-stationary noisy environments that is rapidly changed the spectral characteristics such as babble noise. For this reason, we proposed the modified IMCRA, which adaptively estimate and updata the noise power according to the noise type classified by the Gaussian mixture model (GMM). The performances of the proposed method are evaluated by perceptual evaluation of speech quality (PESQ) and composite measure under various environments and better results compared with the conventional method are obtained.

Mass-Spectral Identification of an Extracellular Protease from Bacillus subtilis KCCM 10257, a Producer of Antibacterial Peptide Subtilein

  • SONG HYUK-HWAN;GIL MI-JUNG;LEE CHAN
    • Journal of Microbiology and Biotechnology
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    • v.15 no.5
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    • pp.1054-1059
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    • 2005
  • An extracellular protease was identified from Bacillus subtilis KCCM 10257 by N-terminal sequencing and mass spectral analysis. The molecular mass of the extracellular protease was estimated to be 28 kDa by SDS-PAGE. Sequencing of the N-terminal of the protease revealed the sequence of A(G,S,R)QXVPYG(A)V(P,L)SQ. The N-terminal sequence exhibited close similarity to the sequence of other proteases from Bacillus sp. A mass list of the monoisotopic peaks in the MALDI-TOF spectrum was searched after peptide fragmentation of the protease. Six peptide sequences exhibiting monoisotopic masses of 1,276.61, 1,513.67, 1,652.81, 1,661.83, 1,252.61, and 1,033.46 were observed from the fragmented protease. These monisotopic masses corresponded to the lytic enzyme L27 from Bacillus subtilis 168, and the Mowse score was found to be 75. A doubly charged Top product (MS) at a m/z of 517.3 exhibiting a molecular mass of 1034.6 was further analyzed by de novo sequencing using a PE Sciex QSTAR Hybrid Quadropole-TOF (MS/MS) mass spectrometer. MS/MS spectra of the Top product (MS) at a m/z of 517.3 obtained from the fragmented peptide mixture of protease with Q-star contained the b-ion series of 114.2, 171.2, 286.2, 357.2, 504.2, 667.4, 830.1, and 887.1 and y-ion series of 147.5, 204.2, 367.2, 530.3, 677.4, 748.4, 863.4, and 920.5. The sequence of analyzed peptide ion was identified as LGDAFYYG from the b- and y-ion series by de novo sequencing and corresponded to the results from the MALDI-TOF spectrum. From these results the extracellular protease from Bacillus subtilis KCCM 10257 was successfully identified with the lytic enzyme L27 from Bacillus subtilis 168.

Chemicals Constituents from Leaves of Diospyros iturensis (Gürke) Letouzey & F. White and their Biological Activities

  • Feusso, Hermann Marius Feumo;Dongmo, Jean de dieu;Djomkam, Hermine Laure Maza;Akak, Carine Mvot;Lateef, Mehreen;Ahmed, Ayaz;Azebaze, Anatole Guy Blaise;Waffo, Alain Francois Kamdem;Ali, Muhammad Shaiq;Vardamides, Juliette Catherine
    • Natural Product Sciences
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    • v.26 no.4
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    • pp.311-316
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    • 2020
  • The chemical investigation of the methanolic crude extract of leaves of Diospyros iturensis gave us 15 known secondary metabolites identified as mixture of α-amyrenone (1) and β-amyrenone (2), β-amyrin (3), mixture of β-sitosterol (4) and stigmasterol (5), betulin (6), uvaol (7), betulinic acid (8), ursolic acid (9), corosolic acid (10), actinidic acid (11),11-O-p-hydroxybenzoylbergenin (12), bergenin (13) and mixture of stigmasterol glucoside (14) and β-sitosterol glucoside (15) respectively. The structures of secondary metabolites were elucidated with the help of NMR and mass spectral data and by comparison of their spectral data with literature. Among the fifteen isolated compounds, four compounds were identified for the first time in Diospyros genus. These included uvaol (7), corosolic acid (10), actinidic acid (11) and 11-O-p-hydroxybenzoylbergenin (12). Crude methanolic extract of leaves and four isolated compounds including betulin (6), betulinic acid (8), 11-O-p-hydroxybenzoylbergenin (12) and bergenin (13) were evaluated for their antiproliferative activity against two cancer cell lines CAL-27 and NCI-H460 by the MTT assay, antioxidant potential and inhibitory activity against the lipoxygenase and urease enzymes, respectively. The results indicated that the methanolic crude extract of leaves exhibited moderate antioxidant activity and was inactive against the two cancer cell lines. Betulin (6), 11-O-p-hydroxybenzoylbergenin (12) and bergenin (13) exhibited moderate antioxidant and lipoxygenase inhibition with IC50 = 65.8, 85.6, 82.5 μM and IC50 = 58.5, 95.2, 76.2 μM, respectively. Furthermore, 11-O-p-hydroxybenzoylbergenin (12) and bergenin (13) exhibited moderate urease inhibition activity with IC50 values of 45.6 μM and 49.8 μM, respectively.

Non-gray Radiation in the Entrance Region of a Smooth Tube (평편한 튜브의 입구 영역에서의 비회복사)

  • Seo, Tae-Beom
    • Solar Energy
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    • v.15 no.3
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    • pp.91-103
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    • 1995
  • Non-gray radiation with convection in the entrance region of a smooth tube is numerically investigated. The fluid is a mixture of carbon dioxide, water vapor, and nitrogen to simulate combustion products of propane. The flow is assumed to be laminar and hydrodynamically and thermally developing. The P-1 approximation is used to simplify the radiative transfer equation and the exponential wide band model is adapted to model the spectral absorption coefficients of non-gray gas mixture. The bulk mean temperature and Nusselt number variation along the tube axis are shown for several inlet and wall temperature pairs to show the effect of temperature on the heat transfer characteristics. Nusselt numbers for simultaneously developing flow are compared to those for thermally developing flow. In addition, the effect of the mole fraction of the non-gray gases on convective and radiative Nusselt numbers is investigated.

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