• Title/Summary/Keyword: spectral changes

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Synthesis and Properties of New Polymeric Photostabilizers Containing HALS Groups (HALS 그룹을 가진 새로운 고분자형 자외선 안정제의 합성 및 특성)

  • 김한식;채규호
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.625-634
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    • 2001
  • New polymeric photostabilizers containing hindered amine light stabilizer (HALS) were prepared by the reaction of liquid polyisoprene rubber grafted maleic anhydride (MAH) and 2,2,5,6-tetramethyl-4-piperidinol (TMPO). Their chemical composition and physical properties were characterized by titration, GPC and TGA analysis. The effects of polymeric HALS on the photooxidation of the styrene-butadiene rubber were studied from the UV, IR spectral changes, and photo-crosslinking was examined by the measurement of the insoluble fraction. The photooxidation of SBR upon irradiation was inhibited by addition of the new polymeric HALS. The extraction resistance of new polymeric photostabilizer was much better than that of the low molecular weight compound which is prepared by the reaction of MAH and TMPO. The new polymeric HALS ate fairly compatible with the SBR.

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SPECIAL CONSIDERATION ON THE RADARSAT REPEAT-PASS SAR INTERFEROMETRY

  • Kim, Sang-Wan;Won, Joong-Sun;Moon, Wooil-M.
    • Proceedings of the KSRS Conference
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    • 1999.11a
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    • pp.474-478
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    • 1999
  • SAR interferometry (InSAR) using the space-borne Synthetic Aperture Radar (SAR) have recently become one of the most effective tools monitoring surface changes caused by landslides, earthquakes, subsidences or volcanic eruption. This study focuses on examining the feasibility of InSAR using the RADARSAT data. Although the RABARSAT SAR with its high resolution and variable incidence angle has several advantages for repeat-pass InSAR, it has two key limitations: first, the orbit is not precisely known; and second, RADARSAT's 24-day repeat pass interval is not very favourable for retaining useful coherence. In this study, two pairs of RADARSAT data in the Nahanni area, NWT, Canada have been tested. We will discuss about the special consideration required on the interferometric processing steps specifically for RADARSAT data including image co-registration, spectral filtering in both azimuth and range, estimation of the interferometric baseline, and correction of the interferogram with respect to the "flat earth" phase contribution. Preliminary results can be summarized as: i) the properly designed azimuth filter based upon the antenna characteristic improves coherence considerably if difference in Doppler centroid of the two images is relatively large; ii) the co-registration process combined by fringe spectrum and amplitude cross-correlation techniques results in optimal matching; iii) the baseline is not always possible to be estimated from the definitive orbit information.

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Effect of a Sudden Increase in Light Intensity on Normalized Difference Vegetation Index (NDVI) Reflected from Leaves of Tobacco (급격한 광도 변화가 담배 잎에서 반사되는 Normalized Difference Vegetation Index에 미치는 영향)

  • Suh, Kyehong
    • Journal of Environmental Science International
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    • v.26 no.4
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    • pp.543-547
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    • 2017
  • Normalized Difference Vegetation Index (NDVI) has played an important role in assessing green plant biomass through remote sensing on global scale since the early 1970s. The concept of NDVI is based on the fact that green plants show higher reflection in near-infrared region than in visible region of the electromagnetic spectrum. However, it is well known that the relocation of chloroplasts in plant leaf cells may dramatically change the optical properties of plant leaves. In this study I traced the changes in the reflectance and transmittance properties of Tobacco leaves at the wavelengths of 660 and 800 nm after a sudden increase in light intensity. The results showed that NDVI of leaves gradually decreased from 72.7% to 69.9% when exposed to a sudden increase in light intensity from 30 to $1,200{\mu}mol/m^2{\cdot}s$. This means that the error resulting from the physiological status of the plant should be accounted for a more precise understanding of ground truth corresponding to the data from the remotely acquired images.

A Study Median Frequency Analysis of Surface EMG on Gender Differences (성별에 따른 표면근전도의 중앙주파수 분석에 관한 연구)

  • Lee, Sang-Sik;Lee, Ki-Young;Go, Jae-Wook;Park, Won-Yeop
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.5 no.1
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    • pp.20-25
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    • 2012
  • Gender differences have been studied by using spectral features such as median frequency (MDF) respectively. MDF is the most commonly used as a feature to describe muscle conduction velocity. The aim of this paper is to detect gender differences from surface EMG signals during isotonic contractions of the bicep Brachii. Eight volunteers participated in surface EMG recordings placed on the biceps brachii and each recording experiment continued until their exhaustion. We used feature values and regressive slopes and compared the feature changes from the onset to the endurance time to find gender differences. The result of experiments shows that the regressive slope of these features is valid to measure gender differences.

Determination of Optimal Toxic Concentration and Accumulation of Cadmium in Broiler Chicks

  • Subhan, Fazli;Khan, Ayaz;Wahid, Fazli;Shehzad, Adeeb;Jan, Amin Ullah
    • Toxicological Research
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    • v.27 no.3
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    • pp.143-147
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    • 2011
  • Cadmium is considered one of the most toxic, non biodegradable heavy metal for the human and animals. The purpose of the present study was to investigate the changes in biochemical parameters of blood and accumulation of cadmium in various tissue caused by various levels of dietary cadmium chloride ($CdCl_2$) in broiler chicks. $CdCl_2$ was administered through drinking water to broiler chicks. In spectral analysis, $CdCl_2$ treatment caused a significant increase in Glutamate pyruvate transaminase (GPT), creatinine and uric acid levels in all treated groups. Intriguingly, the GPT, creatinine, and uric acid levels were significantly higher at 75 mg/kg as compared to the groups treated with high doses (100, 125 and 150 mg/kg) of $CdCl_2$. Atomic Absorption Spectrophotometer (AAS) was used for the determination of Cd accumulation in kidney, liver and Breast muscles. AAS analysis revealed that Cd accumulation is increased in breast muscles as compared to liver and kidney at higher doses of Cd than 75 mg/kg.

Determination of Ethanol in Blood Samples Using Partial Least Square Regression Applied to Surface Enhanced Raman Spectroscopy

  • Acikgoz, Gunes;Hamamci, Berna;Yildiz, Abdulkadir
    • Toxicological Research
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    • v.34 no.2
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    • pp.127-132
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    • 2018
  • Alcohol consumption triggers toxic effect to organs and tissues in the human body. The risks are essentially thought to be related to ethanol content in alcoholic beverages. The identification of ethanol in blood samples requires rapid, minimal sample handling, and non-destructive analysis, such as Raman Spectroscopy. This study aims to apply Raman Spectroscopy for identification of ethanol in blood samples. Silver nanoparticles were synthesized to obtain Surface Enhanced Raman Spectroscopy (SERS) spectra of blood samples. The SERS spectra were used for Partial Least Square (PLS) for determining ethanol quantitatively. To apply PLS method, $920{\sim}820cm^{-1}$ band interval was chosen and the spectral changes of the observed concentrations statistically associated with each other. The blood samples were examined according to this model and the quantity of ethanol was determined as that: first a calibration method was established. A strong relationship was observed between known concentration values and the values obtained by PLS method ($R^2=1$). Second instead of then, quantities of ethanol in 40 blood samples were predicted according to the calibration method. Quantitative analysis of the ethanol in the blood was done by analyzing the data obtained by Raman spectroscopy and the PLS method.

Ground-based and On-satellite Observations of Be and B Stars (인공위성관측과 지상관측에 의한 Be성과 B성의 연구)

  • 정장해
    • Journal of Astronomy and Space Sciences
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    • v.5 no.1
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    • pp.9-18
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    • 1988
  • Gamma Cassiopeae has been observe at Yonsei University Observatory(YUO) for 31 nights in the period 1983-1987 and a total of 312 UBV observations(104 in each colour) was secured. Light curves of ${\gamma}$ Cas in V, B-V, and U-B have been constructed with the YUO data; among them we present selected light curves of 5 different long nights. Discussed are the general photometric behaviour of ${\gamma}$ Cas, especially in connection with B-V changes, V/R variations of $H\alpha$ and H$\beta$, and high velocity narrow component(hvnc) exhibited in the far UV. Six spectral image sets of $\varepsilon$Per archived on IUE satellite are reduced and their line profiles in C IV and Si IV resonance lines are analyzed to find out any change, but the evidence is unlikely.

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Increased Gamma-band Neural Synchrony by Pleasant and Unpleasant Visual Stimuli (긍정, 부정 감정 유발 시각자극에 의한 감마-대역 신경동기화 증가)

  • Yeo, Donghoon;Choi, Jeong Woo;Kim, Kyung Hwan
    • Journal of Biomedical Engineering Research
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    • v.39 no.2
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    • pp.94-102
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    • 2018
  • It is known that gamma-band activity (GBA) and phase synchrony (GBPS) are induced by emotional visual stimuli. However, the characteristics of GBA and GBPS according to different emotional states have not been identified. The purpose of this study is to investigate the changes in gamma-band neuronal synchronization induced by positive and negative emotional visual stimuli using electroencephalograms (EEGs). Thirteen healthy male subjects have participated in the experiment. The induced spectral power in gamma-band was the highest for negative stimuli, and the lowest for neutral stimuli in 300-2,000 ms after the stimulus onset. The inter-regional phase synchronization in gamma-band was increased in 500-2,000 ms, mainly between the bilateral frontal regions and the parieto-occipital regions. Larger number of significant connections were found by negative stimuli compared to positive ones. Judging from temporal and spatial characteristics of the gamma-band activity and phase synchrony increases, the results may imply that affective visual stimuli cause stronger memory encoding than non-emotional stimuli, and this effect is more significant for negative emotional stimuli than positive ones.

Isolation of epi-Oleanolic Acid from Korean Mistletoe and Its Apoptosis-Inducing Activity in Tumor Cells

  • Jung, Myung-Ju;Yoo, Yung-Choon;Lee, Kyung-Bok;Kim, Jong-Bae;Song, Kyung-Sik
    • Archives of Pharmacal Research
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    • v.27 no.8
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    • pp.840-844
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    • 2004
  • A triterpene was isolated as a cytotoxic principle from the dichloromethane extract of Korean mistletoe (KM; Viscum album colora turn) by repeated silica gel chromatography and recrystalli-zation. In in vitro analysis of cytotoxic activity using various human and murine tumor cell lines, the dichloromethane extract of KM was highly cytotoxic against these cells. We isolated the most active compound, referred to VD-3, from the dichloromethane extract of KM. The VD-3 was shown to be less cytotoxic to normal cells (murine splenocytes). From the identification of the chemical structure of VD-3 by spectral data and chemical synthesis, the compound was proven to be epi-oleanolic acid. Tumor cells treated with VD-3 showed a typical pattern of apo-ptotic cell death, such as apparent morphological changes and DNA fragmentation. These results indicate that epi-oleanolic acid is an important compound responsible for antitumor activity of KM.

Effects on Fractal Dimension by Automobile Driver's EEG during Highway Driving : Based on Chaos Theory (직선 고속 주행시 운전자의 뇌파가 프랙탈 차원에 미치는 영향: 카오스 이론을 중심으로)

  • 이돈규;김정룡
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.23 no.57
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    • pp.51-62
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    • 2000
  • In this study, the psycho-physiological response of drivers was investigated in terms of EEG(Electroencephalogram), especially with the fractal dimensions computed by Chaotic algorithm. The Chaotic algorithm Is well Known to sensitively analyze the non-linear information such as brain waves. An automobile with a fully equipped data acquisition system was used to collect the data. Ten healthy subjects participated in the experiment. EEG data were collected while subjects were driving the car between Won-ju and Shin-gal J.C. on Young-Dong highway The results were presented in terms of 3-Dimensional attractor to confirm the chaotic nature of the EEG data. The correlation dimension and fractal dimension were calculated to evaluate the complexity of the brain activity as the driving duration changes. In particular, the fractal dimension indicated a difference between the driving condition and non-driving condition while other spectral variables showed inconsistent results. Based upon the fractal dimension, drivers processed the most information at the beginning of the highway driving and the amount of brain activity gradually decreased and stabilized. No particular decrease of brain activity was observed even after 100 km driving. Considering the sensitivity and consistency of the analysis by Chaotic algorithm, the fractal dimension can be a useful parameter to evaluate the psycho-physiological responses of human brain at various driving conditions.

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