• 제목/요약/키워드: spectral changes

검색결과 427건 처리시간 0.024초

Polyplex Formation of Calf Thymus DNA with Branched and Linear Polyethyleneimine

  • Han, Jung-Ho;Kim, Seog K.;Cho, Tae-Sub;Lee, Jae-Cheol;Joung, Hyun-Sook
    • Macromolecular Research
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    • 제12권5호
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    • pp.501-506
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    • 2004
  • We have investigated the spectral properties of DNA, including its electric absorption, circular and linear dichroism (CD and LD), and fluorescence emission, in the DNA-linear polyethyleneimine (LPEI) and DNA-branched polyethyleneimine (BPEI) complexes at various polymer concentrations. The spectral properties of both complexes are similar. We observed a relatively moderate change in the absorption and CD spectra at low amine/DNA phosphate (NIP) ratios (< 0.5), followed by a drastic collapse within the N/P range from 0.8 and 1.0. The absorption and CD spectra recovered as the N/P ratio increased to ca. 1.2. In contrast, the LD and emission of ethidium intercalated between the DNA bases decreased almost linearly at N/P ratios between 0.0 and 1.0. These spectra never recovered at higher N/P ratios. We believe that the moderate changes in the spectrum at low N/P ratios occurred because of electrostatic interactions between DNA and BPEI, while the collapsed spectra at N/P ratios between 0.5 and 1.5 occurred because of condensation/aggregation of the DNA. Considering the structure of the polymers, we suggest that the secondary amino group of LPEI and all three amino groups of BPEI are equally involved in DNA condensation.

統計的인 方法에 依한 連結音의 音素分割 알고리듬 (A Segmentation Algorithm of the Connected Word Speech by Statistical Method)

  • 조정호;홍재근;김수중
    • 대한전자공학회논문지
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    • 제26권4호
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    • pp.151-163
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    • 1989
  • 本 論文에서는 音聲信號의 音素分割을 위한 統計的인 方法을 硏究하였다. 이 方法은 3個의 AR 모델을 使用하여, 이 中 2個의 모델은 音聲의 스펙트럼 變化前 및 變化後의 安定된 部分에서 求해지고 이들 間의 距離가 커지면 音素가 바뀐 것으로 간주된다. 다른 한 모델은 두 固定 모델 사이에 位置하며 音素間의 境界를 推定하는데 使用된다. 이 音素分割 알고리듬을 連結音에 對해 試驗해 본 結果, 從來의 方法에 비해 音素의 境界點을 좀더 正確히 찾을 수 있고, 또한 過度分割 誤謬도 줄일 수 있었다.

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Vibration-based damage monitoring of harbor caisson structure with damaged foundation-structure interface

  • Lee, So-Young;Nguyen, Khac-Duy;Huynh, Thanh-Canh;Kim, Jeong-Tae;Yi, Jin-Hak;Han, Sang-Hun
    • Smart Structures and Systems
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    • 제10권6호
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    • pp.517-546
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    • 2012
  • In this paper, vibration-based methods to monitor damage in foundation-structure interface of harbor caisson structure are presented. The following approaches are implemented to achieve the objective. Firstly, vibration-based damage monitoring methods utilizing a variety of vibration features are selected for harbor caisson structure. Autoregressive (AR) model for time-series analysis and power spectral density (PSD) for frequency-domain analysis are selected to detect the change in the caisson structure. Also, the changes in modal parameters such as natural frequency and mode shape are examined for damage monitoring in the structure. Secondly, the feasibility of damage monitoring methods is experimentally examined on an un-submerged lab-scaled mono-caisson. Finally, numerical analysis of un-submerged mono-caisson, submerged mono-caisson and un-submerged interlocked multiple-caissons are carried out to examine the effect of boundary-dependent parameters on the damage monitoring of harbor caisson structures.

결정질과 비정질 PV모듈의 자연광 스펙트럼에 따른 Isc의 변화 (Transition of Isc according to Natural Solar Spectrum on c-Si and a-Si PV Module)

  • 공지현;지양근;강기환;유권종;안형근;한득영
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2009년도 추계학술발표대회 논문집
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    • pp.86-91
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    • 2009
  • In this paper, we analyze the Transition of Isc by natural solar spectrum of c-Si and a-Si PV module. Commonly, performance of photovoltaic (PV) module is estimated under the standard test condition (STC). That is, solar irradiance $1kW/m^2$, solar spectrum distribution: AM1 5G, module temperature $25^{\circ}C$ This means it rarely meets actual outdoor conditions. The solar spectrum always changes. So it is rare to fit the standard solar spectrum AM1 5G defined in ASTM G173-03 or IEC 60904-3. Thus spectral response of PV module is different depending on the material. so we estimated the variation of Isc at every minutes by comparing c-Si PV module with a-si PV module for outdoor conditions.

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Hyperbolic Reaction-Diffusion Equation for a Reversible Brusselator: Solution by a Spectral Method

  • 이일희;김광연;조웅인
    • Bulletin of the Korean Chemical Society
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    • 제20권1호
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    • pp.35-41
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    • 1999
  • Stability characteristics of hyperbolic reaction-diffusion equations with a reversible Brusselator model are investigated as an extension of the previous work. Intensive stability analysis is performed for three important parameters, Nrd, β and Dx, where Nrd is the reaction-diffusion number which is a measure of hyperbolicity, β is a measure of reversibility of autocatalytic reaction and Dx is a diffusion coefficient of intermediate X. Especially, the dependence on Nrd of stability exhibits some interesting features, such as hyperbolicity in the small Nrd region and parabolicity in the large Nrd region. The hyperbolic reaction-diffusion equations are solved numerically by a spectral method which is modified and adjusted to hyperbolic partial differential equations. The numerical method gives good accuracy and efficiency even in a stiff region in the case of small Nrd, and it can be extended to a two-dimensional system. Four types of solution, spatially homogeneous, spatially oscillatory, spatio-temporally oscillatory and chaotic can be obtained. Entropy productions for reaction are also calculated to get some crucial information related to the bifurcation of the system. At the bifurcation point, entropy production changes discontinuously and it shows that different structures of the system have different modes in the dissipative process required to maintain the structure of the system. But it appears that magnitude of entropy production in each structure give no important information related for states of system itself.

Seismic attributes for characterization of a heavy-oil shaly-sand reservoir in the Muglad Basin of South Sudan

  • Deng, William A.;Kim, Taeyoun;Jang, Seonghyung
    • Geosciences Journal
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    • 제22권6호
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    • pp.1027-1039
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    • 2018
  • Seismic attributes are often used to identify lithology and evaluate reservoir properties. However, interpretation based only on structural attributes and without knowledge of the Vp/Vs ratio can limit the ability to evaluate changes in heavy oil reservoirs. These limitations are often due to less obvious impedance differences. In order to investigate pieces of evidence of a heavy-oil shaly-sand reservoir from seismic data, besides geochemistry, we studied seismic attributes and characterized the reservoir using seismic stack data and well logging data. The study area was the Muglad rift basin in South Sudan. We conducted a seismic complex analysis to evaluate the target reservoir. To delineate the frequency responses of the different lithological units, we applied the spectral decomposition method to the target reservoir. The most unexpected result was continuous bands of strong seismic reflectors in the target reservoir, which extended across the borehole. Spectral decomposition analysis showed that the low-frequency zone of 25 Hz dominant frequency was consistent with instantaneous attributes. This approach can identify lithology, reveal frequency anomalies, and filter the stacked section into low- and high-frequency bands. The heavy-oil reservoir zones exhibited velocity attenuation and the amplitude was strongly frequency dependent.

Theoretical Analysis and Optimization of Extrinsic Fabry-Perot Interferometer Optical-fiber Humidity-sensor Structures

  • Yin, Xiao Lei;Wang, Ning;Yu, Xiao Dan;Li, Yu Hao;Zhang, Bo;Li, Dai Lin
    • Current Optics and Photonics
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    • 제5권6호
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    • pp.652-659
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    • 2021
  • The theoretical analysis and optimization of extrinsic Fabry-Perot interferometer (EFPI) opticalfiber humidity sensors are deeply investigated. For a typical dual-cavity structure composed of an optical fiber and a humidity-sensitive membrane (HSM), the changes in refractive index (RI) and initial length are discussed for polymer materials and porous oxide materials when relative humidity (RH) increases. The typical interference spectrum is simulated at different RH using MATLAB. The spectral change caused by changing HSM RI and initial length are simulated simutineously, showing different influences on humidity response. To deeply investigate the influence on RH sensitivity, the typical response sensitivity curves for different HSM lengths and air-cavity lengths are simulated. The results show that the HSM is the vital factor. Short HSM length can improve the sensitivity, but for HSM RI and length the influences on sensitivity are opposite, because of the opposite spectral-shift trend. Deep discussion and an optimization method are provided to solve this problem. According to analysis, an opaque HSM is helpful to improve sensitivity. Furthermore, if using an opaque HSM, a short air cavity and long HSM length can improve the sensor's sensitivity These results provide deep understanding and some ideas for designing and optimizing highly sensitive EFPI fiber humidity sensors.

2D Correlation Analysis of Spin-Coated Films of Biodegradable P(HB-co-HHx)/PEG Blends

  • Kim, Min-Kyung;Ryu, Soo-Ryeon;Noda, Isao;Jung, Young-Mee
    • Bulletin of the Korean Chemical Society
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    • 제32권11호
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    • pp.4005-4010
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    • 2011
  • We investigated thermal behavior of spin-coated films of P(HB-co-HHx)/PEG blends by using infraredreflection absorption (IRRAS) spectroscopy and 2D correlation spectroscopy. Based on 2D IRRAS correlation spectra, we could determine the sequence of spectral intensity changes with increasing temperature that PEG band changes first and then a band for crystalline component of P(HB-co-HHx) changes before a band for amorphous component. The intensities of bands for PEG and amorphous P(HB-co-HHx) were changed greatly as PEG weigh % of P(HB-co-HHx)/PEG blends increased. Transition temperatures of P(HB-co-HHx)/PEG blends were successfully determined by 2D gradient mapping method. The transition temperature of spincoated films of 98/2 and 90/10 P(HB-co-HHx)/PEG blends and 80/20 P(HB-co-HHx)/PEG blend determined by 2D gradient map are, respectively, about 137.5 and $132.5^{\circ}C$. Furthermore, P(HB-co-HHx)/PEG blends show an additional transition temperature that have been interpreted in terms of different lamellar thicknesses in spin coated films.

Coherent fiber-optic intrusion sensor for long perimeters monitoring

  • Choi Kyoo Nam
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2004년도 학술대회지
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    • pp.876-879
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    • 2004
  • The buried fiber optic cable as a distributed intrusion sensor for detecting and locating intruders along the long perimeters is proposed. Phase changes resulting from either the pressure of the intruder on the ground immediately above the buried fiber or from seismic disturbances in the vicinity are sensed by a phase-sensitive optical time-domain reflectometer. Light pulses from a Er:fiber cw laser with a narrow, <3kHz-range, spectral width and a frequency drift of < 1 MHz/min are injected into one end of the fiber, and the backscattered light from the fiber is monitored with a photodetector. Results of preliminary studies, measurement of phase changes produced by pressure and seismic disturbances in buried fiber optic cables and simulation of ${\varphi}-OTDR$ response over long fiber paths, to establish the feasibility of the concept are described. The field experiments indicate adequate phase changes, more than 1t-rad, are produced by intruders on foot and vehicle for burial depths in the 0.2 m to 1 m range in sand, clay and fine gravel soils. The simulations predict a range of 10 km with 35 m range resolution and 30 km with 90 m range resolution. This technology could in a cost-effective manner provide enhanced perimeter security.

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Ground-based Observations for the Upper Atmosphere at King Sejong Station, Antarctica

  • Jee, Geonhwa;Kim, Jeong-Han;Lee, Changsup;Kim, Yong Ha
    • Journal of Astronomy and Space Sciences
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    • 제31권2호
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    • pp.169-176
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    • 2014
  • Since the operation of the King Sejong Station (KSS) started in Antarctic Peninsula in 1989, there have been continuous efforts to perform the observation for the upper atmosphere. The observations during the initial period of the station include Fabry-Perot Interferometer (FPI) and Michelson Interferometer for the mesosphere and thermosphere, which are no longer in operation. In 2002, in collaboration with York University, Canada, the Spectral Airglow Temperature Imager (SATI) was installed to observe the temperature in the mesosphere and lower thermosphere (MLT) region and it has still been producing the mesopause temperature data until present. The observation was extended by installing the meteor radar in 2007 to observe the neutral winds and temperature in the MLT region during the day and night in collaboration with Chungnam National University. We also installed the all sky camera in 2008 to observe the wave structures in the MLT region. All these observations are utilized to study on the physical characteristics of the MLT region and also on the wave phenomena such as the tide and gravity wave in the upper atmosphere over KSS that is well known for the strong gravity wave activity. In this article, brief introductions for the currently operating instruments at KSS will be presented with their applications for the study of the upper atmosphere.