Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

2D Correlation Analysis of Spin-Coated Films of Biodegradable P(HB-co-HHx)/PEG Blends

  • Kim, Min-Kyung (Department of Chemistry, and Institute for Molecular Science and Fusion Technology, Kangwon National University) ;
  • Ryu, Soo-Ryeon (Department of Chemistry, and Institute for Molecular Science and Fusion Technology, Kangwon National University) ;
  • Noda, Isao (The Procter & Gamble Company) ;
  • Jung, Young-Mee (Department of Chemistry, and Institute for Molecular Science and Fusion Technology, Kangwon National University)
  • Received : 2011.08.29
  • Accepted : 2011.09.19
  • Published : 2011.11.20
Download PDF
⟨ Previous Next ⟩

Abstract

We investigated thermal behavior of spin-coated films of P(HB-co-HHx)/PEG blends by using infraredreflection absorption (IRRAS) spectroscopy and 2D correlation spectroscopy. Based on 2D IRRAS correlation spectra, we could determine the sequence of spectral intensity changes with increasing temperature that PEG band changes first and then a band for crystalline component of P(HB-co-HHx) changes before a band for amorphous component. The intensities of bands for PEG and amorphous P(HB-co-HHx) were changed greatly as PEG weigh % of P(HB-co-HHx)/PEG blends increased. Transition temperatures of P(HB-co-HHx)/PEG blends were successfully determined by 2D gradient mapping method. The transition temperature of spincoated films of 98/2 and 90/10 P(HB-co-HHx)/PEG blends and 80/20 P(HB-co-HHx)/PEG blend determined by 2D gradient map are, respectively, about 137.5 and $132.5^{\circ}C$. Furthermore, P(HB-co-HHx)/PEG blends show an additional transition temperature that have been interpreted in terms of different lamellar thicknesses in spin coated films.

Keywords

References

  1. Bastiolo, C. In Handbook of Biodegradable Polymers; Rapra Technology Limited; UK, 2005.
  2. Chiellini, E.; Solaro, R. In Recent Advances in Biodegradable Polymers and Plastics; Wiley-VCH; Weinheim, 2003.
  3. Satkowski, M. M.; Melik, D. H.; Autran, J.-P.; Green, P. R.; Noda, I.; Schechtman, L. A. In Biopolymers; Steinbuchel, A., Doi, Y., Eds.; Wiley-VCH: Wienhiem, 2001; p 231.
  4. Noda, I.; Green, P. R.; Satkowski, M. M.; Schechtman, L. A. Biomacromolecules 2000, 6, 580.
  5. Sato, H.; Murakami, R.; Padermshoke, A.; Yamaguchi, H.; Terauchi, H.; Ekgasit, S.; Noda, I.; Ozaki, Y. Macromolecules 2004, 37, 3763. https://doi.org/10.1021/ma049863t
  6. Furukawa, T.; Sato, H.; Murakami, R.; Zhang, J.; Duan, Y.-X.; Noda, I.; Ochiai, S.; Ozaki, Y. Macromolecules 2005, 38, 6445. https://doi.org/10.1021/ma0504668
  7. Zhang, J.; Sato, H.; Furukawa, T.; Tsuji, H.; Noda, I.; Ozaki, Y. J. Phys. Chem. B 2006, 110, 24463. https://doi.org/10.1021/jp065233c
  8. Sato, H.; Mori, K.; Murakami, R.; Ando, Y.; Takahashi, I.; Zhang, J.; Terauchi, H.; Hirose, F.; Senda, K.; Tashiro, K.; Noda, I.; Ozaki, Y. Macromolecules 2006, 39, 1525. https://doi.org/10.1021/ma051777l
  9. Zhang, J.; Sato, H.; Noda, I.; Ozaki, Y. Macromolecules 2005, 38, 4274. https://doi.org/10.1021/ma0501343
  10. Jung, Y. M.; Sato, H.; Noda, I. Anal. Sci. 2007, 23, 881. https://doi.org/10.2116/analsci.23.881
  11. Furukawa, T.; Sato, H.; Murakami, R.; Zhang, J.; Noda, I.; Ochiai, S.; Ozaki, Y. Polymer 2007, 48, 1749. https://doi.org/10.1016/j.polymer.2007.01.020
  12. Vogel, C.; Wessel, E.; Siesler, H. W. Biomacromolecules 2008, 9, 523. https://doi.org/10.1021/bm701035p
  13. Guo, L.; Sato, H.; Hashimoto, T.; Ozaki, Y. Macromolecules 2011, 44, 2229. https://doi.org/10.1021/ma102601p
  14. Ji, H.; Kim, S. B.; Noda, I.; Jung, Y. M. Spectrochimica Acta Part A 2009, 71, 1873. https://doi.org/10.1016/j.saa.2008.07.007
  15. Ji, H.; Hwang, H.; Kim, S. B.; Noda, I.; Jung, Y. M. J. Mol. Struct. 2008, 883-884, 167. https://doi.org/10.1016/j.molstruc.2007.12.031
  16. Choi, H. C.; Ryu, S. R.; Ji, H.; Kim, S. B.; Noda, I.; Jung, Y. M. J. Phys. Chem. B 2011, 114, 10979.
  17. Noda, I.; Ozaki, Y. Two-Dimensional Correlation Spectroscopy: Applications in Vibrational Spectroscopy; John Wiley & Sons: Inc.; New York, 2004.
  18. Jung, Y. M.; Noda, I. Appl. Spectrosc. Rev. 2006, 41, 515. https://doi.org/10.1080/05704920600845868
  19. Noda, I. Appl. Spectrosc. 1993, 47, 1329. https://doi.org/10.1366/0003702934067694
  20. Jung, Y. M.; Shin, H. S.; Czarnik-Matusewicz, B.; Noda, I.; Kim, S. B. Appl. Spectrsc. 2002, 56, 1568. https://doi.org/10.1366/000370202321116039
  21. Chae, B.; Lee, S. W.; Jung, Y. M.; Ree, M.; Kim, S. B. Appl. Spectrosc. 2008, 62, 497. https://doi.org/10.1366/000370208784344361
  22. Jung, Y. M.; Shin, H. S.; Kim, S. B.; Noda, I. J. Phys. Chem. B 2008, 112, 3611. https://doi.org/10.1021/jp077043n
  23. Avella, M.; Martescelli, E. Polymer 1988, 29, 1731. https://doi.org/10.1016/0032-3861(88)90384-9
  24. Izawa, K.; Ogasawara, T.; Masuda, H.; Okabayashi, H.; Noda, I. Macromolecules 2002, 35, 92. https://doi.org/10.1021/ma010760+
  25. Lim, J. S.; Noda, I.; Im, S. S. J. Polym. Sci. Part B: Polym. Phys. 2006, 44, 2852. https://doi.org/10.1002/polb.20937
  26. Czarnik-Matusewicz, B.; Kim, S. B.; Jung, Y. M. J. Phys. Chem. B 2009, 113, 559. https://doi.org/10.1021/jp808396g
  27. Vogel, C.; Wessel, E.; Siesler, H. W. Biomacromolecules 2008, 9, 523. https://doi.org/10.1021/bm701035p

Cited by

  1. Projection 2D correlation analysis of spin-coated film of biodegradable P(HB-co-HHx)/PEG blend vol.60, pp.None, 2011, https://doi.org/10.1016/j.vibspec.2012.02.008
  2. Frontiers of two-dimensional correlation spectroscopy. Part 2. Perturbation methods, fields of applications, and types of analytical probes vol.1069, pp.None, 2011, https://doi.org/10.1016/j.molstruc.2014.01.016
  3. Frontiers of Two-Dimensional Correlation Spectroscopy. Part 1. New concepts and noteworthy developments vol.1069, pp.None, 2014, https://doi.org/10.1016/j.molstruc.2014.01.025
  4. Influence of polyethylene glycol (PEG) chain length on the thermal behavior of spin-coated thin films of biodegradable poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)/PEG blends vol.1124, pp.None, 2011, https://doi.org/10.1016/j.molstruc.2016.02.059
  5. Studies on Chemical IR Images of Poly(hydroxybutyrate– co –hydroxyhexanoate)/Poly(ethylene glycol) Blends and Two-Dimensional Correlation Spectroscopy vol.11, pp.3, 2011, https://doi.org/10.3390/polym11030507
  6. Chemical images and 2D-COS analysis of spin-coated PHBHx/PEG blend films vol.1216, pp.None, 2011, https://doi.org/10.1016/j.molstruc.2020.128344