• 제목/요약/키워드: spectral changes

검색결과 425건 처리시간 0.025초

${\beta}$-시클로덱스트린과 아스피린의 포접화합물의 구조에 관한 연구 (Structure Study of Inclusion Complex of ${\beta}-Cyclodextrin$ and Aspirin)

  • 최희숙
    • Journal of Pharmaceutical Investigation
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    • 제21권4호
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    • pp.223-230
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    • 1991
  • The structural specificity and the chemical dynamics between ${\beta}-cyclodextrin$ and aspirin were studied by FT-IR UN, $^1H$ NMR. $^{13}C NMR$. and FAB-MS spectroscopy in solution and solid state, A stable solid inclusion complex was prepared by the recrystallization method, From the spectral changes of the host and guest molecules, orientational preference for binding in the cyclodextrin cavity was determined.

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The development of near infrared calibrations for assessing grass herbage quality

  • Sharma, Hss;Mellon, R.;Johnson, D.;Fletcher, H.
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1611-1611
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    • 2001
  • The main selection parameters used by forage grass (rye and Italian rye grass) breeders are dry-matter yield, seasonal growth, persistency, disease resistance, heading date, and heading. These characteristics can all be identified usually in the segregating F2 population, however characteristics such as soluble carbohydrate level, protein, lipid and digestibility cannot be identified. The emphasis of this work is to introduce a quantitative selection process for characterization of herbage quality e.g. protein, water-soluble carbohydrates, fiber fractions, dry matter digestibility. NIRS calibrations are currently being developed for identifying grass genotypes to assist the selection process, thereby allowing the opportunity to actively breed improved herbage quality. The changes in fibre fractions, associated components and digestibility of a number of grass clones at different growth stages are being assessed changes taking place during a growing season. This will provide a database of the major changes taking place during a growing season. Attempts to classify quality differences between genotypes will be carried out using multivariate analysis of the spectral data. I addition changes associated with maturity of grass will be considered in order to develop robust calibrations.

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Inter-Cell Interference Management for Next-Generation Wireless Communication Systems

  • Kwon, Ho-Joong;Ko, Soo-Min;Seo, Han-Byul;Lee, Byeong-Gi
    • Journal of Communications and Networks
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    • 제10권3호
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    • pp.258-267
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    • 2008
  • In this paper, we examine what changes the next-generation wireless communication systems will experience in terms of the technologies, services, and networks and, based on that, we investigate how the inter-cell interference management should evolve in various aspects. We identify that the main driving forces of the future changes involve the data-centric services, new dynamic service scenarios, all-IP core access networks, new physical-layer technologies, and heavy upload traffic. We establish that in order to cope with the changes, the next-generation inter-cell interference management should evolve to 1) set the objective of providing a maximal data rate, 2) take the form of joint management of power allocation and user scheduling, 3) operate in a fully distributed manner, 4) handle the time-varying channel conditions in mobile environment, 5) deal with the changes in interference mechanism triggered by the new physical-layer technologies, and 6) increase the spectral efficiency while avoiding centralized coordination of resource allocation of the users in the uplink channel.

Effects of partially earth-anchored cable system on dynamic wind response of cable-stayed bridges

  • Won, Jeong-Hun;Yoon, Ji-Hyun;Park, Se-Jun;Kim, Sang-Hyo
    • Wind and Structures
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    • 제11권6호
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    • pp.441-453
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    • 2008
  • In this study, a partially earth-anchored cable system is studied in order to reduce the dynamic wind response of cable-stayed bridges. The employment of earth-anchored cables changes the dynamic characteristics of cable-stayed bridges under wind loads. In order to estimate the changes in the member forces, the spectral analysis for wind buffeting loads are performed and the peak responses are evaluated using 3-D finite element models of the three-span cable-stayed bridges with the partially earth-anchored cable system and with the self-anchored cable system, respectively. Comparing the results for the two different models, it is found that the earth-anchored cables affect longitudinal and vertical modes of the bridge. The changes of the natural frequencies for the longitudinal modes remarkably decrease the peak bending moment in the pylon and the movements at the expansion joints. The small changes of the natural frequencies for the vertical modes slightly increase bending moments and deflections in the girder. The original effects of the partially earth-anchored cable system are also shown under wind loads; the decrement of girder axial forces and bearing uplifting forces, and the increment of cable forces in the earth-anchored cables.

Compositional changes in mycosporine-like amino acids induced by UV radiation: marine dinoflagellate Scrippsiella sweeneyae

  • Taira, Hitomi;Yabe, Kazuo;Taguchi, Satoru
    • Journal of Photoscience
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    • 제9권2호
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    • pp.445-447
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    • 2002
  • The compositional changes in mycosporine-like amino acids (MAAs) were investigated in the marine dinoflagellate Scrippsiella sweeneyae exposed to four different spectral compositions and five relative intensities of UV-B (280-320 nm) to UV-A (320-400 nm) + photosynthetically available radiation (PAR: 400-700 nm). Neither dose nor wavelengths of UVR significantly affected the growth rates. UVR caused a significantly increase in cell volume. Cell volume in the >280nm treatment was more than two times greater at 6.8 % of UVR intensity. Production of UVR induced MAAs was dependent on the dose of UVR. However. the induction of MAAs was related to the cell growth. Greater induction of MAAs was observed at shorter wavelengths. The composition of MAAs varied with increasing light intensity of UVR.

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Sodium Dodecyl Sulfate 존재하에서 Thionine의 흡수 및 형광분광학적 성질 (Absorption and Fluorescence Spectroscopic Behavior of Thionine in the Presence of Sodium Dodecyl Sulfate)

  • 강성관;박종회;윤민중
    • 대한화학회지
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    • 제38권12호
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    • pp.857-863
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    • 1994
  • Sodium dodecyl sulfate (SDS) 존재하에서 유기색소인 thionine (TH)의 흡수 및 형광분광학적 성질을 조사 연구하였다. SDS 농도 증가에 따라 측정한 흡수 및 형광스펙트럼의 변화들로부터 i) TH-SDS 착화합물의 회합체 형성, ii)TH-SDS 회합체내의 색소분자의 stacking 과정, iii)dye-rich induced micelles의 형성에 의한 staking의 파괴 및 iv) SDS 미셀의 표면에 TH의 재분포과정 등으로 설명하였다.

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열처리에 의한 함수 티타니아의 구조적 변화 (Structural Changes of Hydrous Titania by Heat-Treatment)

  • 최병철;이문호
    • 한국재료학회지
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    • 제4권4호
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    • pp.477-482
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    • 1994
  • 열처리에 따른 함수 티타니아의 구조변화를 X-선 회절, 투과전자현미경, 적외선 흡수 및 라만 분광분석 등을 통하여 조사하였다. 과산화수소와 사염화티타의 혼합용액으로부터 $30^{\circ}C$, pH 9에서 함수 티타니아를 제조하였다. 침전물은 완전하게는 결정화되지 않은 anatase형의 티타니아였다. $700^{\circ}C$까지 열처리온도가 증가함에 따라 anatase의 결정성은 증가하였으며, 입성자은 높은 온도에서 일어났다. $700^{\circ}C$에서 anatase로부터 rutile형이 생성되었다.

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금속 이온에 대한 염료 로택산의 선택적 반응성 (Selective Response of Dye Rotaxane to Metal Ions)

  • 박종승
    • 한국염색가공학회:학술대회논문집
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    • 한국염색가공학회 2011년도 제44차 학술발표회
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    • pp.35-35
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    • 2011
  • The design and preparation of novel dye rotaxanes have gained much interest recently, since such structure usually exhibits peculiar spectral and optical changes. In spite of the promising results to date, increasing pressure remains to develop novel supramolecular structures based on stimuli-responsive systems. This presentation covers the study of inclusion complexes of cyclodextrins and various chromophores, with an emphasis on our most recent outcome of anisotropic hydrogel. In this system, physical gelation prepared from simple mixture of CD and a azo dye is completed through specific host-guest interaction. The obtained hydrogel exhibits respective morphological transitions based on supramolecular assembly and dissociation, leading to either precipitation or a sol-to-gel transition. It can identify different classes of metal ions, and, among them, naked-eye differentiation of lead ion is possible due to the coordination-induced unthreading of dye molecules. Accompanying structural changes were verified by numerous characterization techniques, including 2D-ROESY, HR-MAS, UV-Visible absorption, small-angle X-ray scattering, and induced circular dichroism measurements. Such properties discussed here will find useful in analytical applications, such as metal ion sensing and removal applications.

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