• Wind and Structures
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• v.30 no.2
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• pp.155-163
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• 2020

Previous research has shown that wind acceleration components produce a signal that can vibrate single-degree of-freedom oscillators, whose dynamic responses enable to configure design spectra for structures subject to wind. These wind design spectra present an alternative method for evaluating the dynamic response of structures and are a suitable tool for running modal analyses. Here, a generalised method for producing wind design spectra is proposed. The method consists of scaling existing spectra to adjust to a wider range of building properties and terrain conditions. The modelling technique is tested on a benchmark building to prove that its results are consistent with experimental evidence reported in the past.

• Publications of The Korean Astronomical Society
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• v.29 no.3
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• pp.35-44
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• 2014

In ground-based astronomical spectroscopic observations, there are many telluric absorption lines that are laid on the spectra of celestial objects. To study the physical properties of the celestial objects with these contaminated spectra, the telluric lines should be removed. A conventional method for removing the telluric lines is using the standard stellar spectrum as telluric line. In this paper, we introduce a technique to calculate synthetic telluric spectra and use them to remove telluric lines from a spectrum of a celestial object. We used Line-by-Line Radiative Transfer Model (LBLRTM) for calculating a synthetic spectrum and selected Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) model as atmospheric model. We apply our method to some spectra obtained by Bohyunsan Observatory Echelle Spectrograph (BOES) to show that the telluric lines are well removed from the observed spectra by our model within an accuracy of 2% which is close to the 1-sigma rms of the original spectra.

• Mass Spectrometry Letters
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• v.10 no.3
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• pp.93-101
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• 2019

Algorithms and software for predicting tandem mass spectra have been developed in recent years. In this work, we explore how distinct in silico $MS^2$ spectra are predicted for isomers, i.e. compounds having the same formula and similar molecular structures, to differentiate between them. We used the CFM-ID 2.0/3.0 predictor with regard to (a) test compounds, whose experimental mass spectra had been randomly sampled from the MassBank of North America (MoNA) collection, and to (b) the most widespread isomers of test compounds searched in the PubChem database. In the first validation test, in silico mass spectra constitute a reference library, and library searches are performed for test experimental spectra of "unknowns". The searches led to the true positive rate (TPR) of ($46-48{\pm}10$)%. In the second test, in silico and experimental spectra were interchanged and this resulted in a TPR of ($58{\pm}10$)%. There were no significant differences between results obtained with different metrics of spectral similarity and predictor versions. In a comparison of test compounds vs. their isomers, a statistically significant correlation between mass spectral data and structural features was observed. The TPR values obtained should be regarded as reasonable results for predicting tandem mass spectra of related chemical structures.

• Bulletin of the Korean Chemical Society
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• v.35 no.3
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• pp.749-752
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• 2014

New software was developed for the assignment of elemental formulae based on high-resolution mass spectra and subsequent hydrogen/deuterium exchange data. Entire peaks in high-resolution mass spectra were grouped by their Kendrick mass defect values, and the weighted RMS deviations between theoretical and experimental values were used to determine elemental formulae. After this initial assignment, formulae containing deuterium atoms were sorted in order to interpret hydrogen/deuterium exchange spectra. The software was successfully applied to hydrogen/deuterium exchange spectra of resins and aromatic fractions from heavy crude oil.

• Carbon letters
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• v.8 no.4
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• pp.307-312
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• 2007

A method for evaluating bulk sensitive structural characteristics of unpurified, as-purified, and acid treated single walled carbon nanotubes (SWNTs) was described in the present study. The optical spectra of SWNT solutions were well resolved after prolonged sonication and they were correlated to the diameter and the distribution of nanotubes. The acid-treated SWNTs were similar to as-purified SWNTs in terms of catalyst residue, radial breathing mode (RBM) in the Raman spectra, and the first band gap energy of semiconducting tubes in the optical spectra. The solution phase optical spectra were more sensitive to changes in the small diameter and metallic tubes after the acid treatment than were the RBM spectra.

• Proceedings of the Earthquake Engineering Society of Korea Conference
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• 2003.03a
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• pp.238-246
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• 2003

By using simulated ground motions, which is sum of earthquake signals and noise, we measured the distortion of response spectra due to noise. We found that the distortion is more closely related to the signal-to-noise (S/N) ratio of root-mean-square (RMS) measurement than that of conventional peak measurement. Given a S/M ratio, the distortion of absolute acceleration response spectra is independent on the earthquake magnitude, while that of relative displacement response spectra has a strong dependence on the earthquake magnitude. This means that, when we calculate response spectra from time histories, we can efficiently predict the distortion of acceleration response spectra simply by measuring the RMS SJN ratios, or the distortion of displacement response spectra by combining the RMS S/N ratios and the earthquake magnitudes.

• Journal of the Korean Chemical Society
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• v.13 no.1
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• pp.25-28
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• 1969

UV absorption spectra of some metalized monoazo complexes have been measured, and the structure of the complexes is discussed based on the spectra. A compressed octahedron is proposed as the geometrical structure of the complexes.

• Bulletin of the Korean Chemical Society
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• v.13 no.2
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• pp.148-155
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• 1992

Computerized interpretation of vapor phase infrared spectra using a novel expert system approach for spectra/structure correlation for vapor phase spectra is introduced. Rapid identification of aromatic functional groups of components in gaseous mixture can be achieved using this expert system.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1284-1284
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• 2001

The transesterification of molten ethylene/vinylacetate (EVA) copolymers by octanol as a reagent and sodium methoxide as a catalyst in an extruder has been monitored by on-line near infrared (NIR) spectroscopy. A total of 60 NIR spectra were acquired for 37 minutes with the last spectrum recorded 31 minutes after the addition of octanol and catalyst was stopped. The experimental spectra show strong baseline fluctuations which are corrected for by multiplicative scatter correction (MSC). The chemometric methods of orthogonal projection approach (OPA) and multivariate curve resolution (MCR) were used to resolve the spectra and to derive concentration profiles of the species. The detailed analysis reveals the absence of completely pure variables that leads to small errors in the calculation of pure spectra. The initial estimation of a concentration that is necessary as an input parameter for MCR also presents a non-trivial task. We obtained results that were not ideal but applicable for practical concentration control. They enable a fast monitoring of the process in real-time and resolve the spectra of the EVA copolymer and the ethylene/vinyl alcohol (EVAL) copolymer to be very close to the reference spectra. The chemometric methods used and the decomposed spectra are discussed in detail.

• Honam Mathematical Journal
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• v.41 no.1
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• pp.67-87
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• 2019

The main aim of this study is to characterize new classes of multicone graphs which are determined by their adjacency spectra, their Laplacian spectra, their complement with respect to signless Laplacian spectra and their complement with respect to their adjacency spectra. A multicone graph is defined to be the join of a clique and a regular graph. If n is a positive integer, a friendship graph $F_n$ consists of n edge-disjoint triangles that all of them meet in one vertex. It is proved that any connected graph cospectral to a multicone graph $F_n{\nabla}F_n=K_2{\nabla}nK_2{\nabla}nK_2$ is determined by its adjacency spectra as well as its Laplacian spectra. In addition, we show that if $n{\neq}2$, the complement of these graphs are determined by their adjacency spectra. At the end of the paper, it is proved that multicone graphs $F_n{\nabla}F_n=K_2{\nabla}nK_2{\nabla}nK_2$ are determined by their signless Laplacian spectra and also we prove that any graph cospectral to one of multicone graphs $F_n{\nabla}F_n$ is perfect.