• Title/Summary/Keyword: spectra

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Effect of Smooth Hysteretic Behavior for Inelastic Response Spectra (비탄성 응답스펙트럼에 대한 완만한 곡선형 이력거동의 영향)

  • Song, Jong-Keol
    • Journal of the Earthquake Engineering Society of Korea
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    • v.14 no.1
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    • pp.1-9
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    • 2010
  • The actual hysteretic behavior of structural elements and systems is closer to smooth hysteretic behavior than piece-wise linear behavior. This paper presents a methodology for computing the constant-ductility inelastic response spectra for smooth hysteretic behaviors. The effect of the hysteretic smoothness on the inelastic response spectra for acceleration, displacement, and input energy is evaluated. The results indicate that increasing smoothness in the hysteretic behavior decreases the inelastic response spectra.

Electronic Spectra and Quenching of Dimethylanilines (Dimethylanline의 Electronic Spectra와 消光)

  • Jung, Kyung-Hoon;Lee, Ik-Choon
    • Journal of the Korean Chemical Society
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    • v.8 no.4
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    • pp.158-163
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    • 1964
  • Electronic spectra and quenching constants for ten N,N-dimethylanilines (DMA) have been determined. The $250m{\mu}$ absorption band (C band) of DMA was shown to be mainly responsible for the quenching. This band was confirmed as an $n{\to}{\pi}^{\ast}$ band through substituent and medium effects on the spectra shifts. The energy absorbed by this band then transfers to triplet and down to the lowest triplet state, $^{3}La$, where the energy is lost by non-radiative collisions.

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Low Resolution Near-Infrared Stellar Spectra Observed by CIBER

  • Kim, MinGyu;Lee, Hyung Mok
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.76.2-76.2
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    • 2016
  • We present near-infrared (0.8 - 1.8 microns) spectra of 63 bright (J_mag < 10) stars observed with Low Resolution Spectrometer (LRS) onboard the rocket-borne Cosmic Infrared Background Experiment (CIBER). Two Micron All Sky Survey (2MASS) photometry information is used to find cross-matched stars after reduction and extraction of the spectra. We identify the spectral types of observed stars by comparing with spectral templates from the Infrared Telescope Facility (IRTF) library. All the observed spectra are consistent with late F to M stellar spectral types, and we identify various infrared absorption lines. As our observations are performed above the Earth's atmosphere, our spectra are free from telluric contamination. Including HST/NICMOS and Cassini/VIMS, the spectral coverage has rarely been achieved in space, and the methods developed here can inform statistical studies with future low-resolution spectral measurements such as GAIA photometric and radial velocity spectrometer.

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Studies on the Chemical Components of Fruits of Forsythia Koreana NAKAI (II) Ocurrence of betaine in the fruits of Forsythia Koreana (Forsythia koreana NAKAI 씨 (토연교)의 성분에 관한 연구 (II) (Betaine의 분리 및 확인))

  • Cang Sae Hee;Kim Jae Soon;Huh Tae Soung
    • Journal of the Korean Chemical Society
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    • v.15 no.1
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    • pp.1-3
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    • 1971
  • The methanol extract of the fruits of Forsythia Koreana NAKAI was separated and purified. The quaternary base chloride was obtained. Through the mass spectrogram, ultraviolet spectra, infrared spectra, elemental analysis and qualitative tests it was identified as betaine hydrochloride.

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Simulations of Two-Dimensional Electronic Correlation Spectra

  • Kim, Hak Jin;Jeon, Seong Jun
    • Bulletin of the Korean Chemical Society
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    • v.22 no.8
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    • pp.807-815
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    • 2001
  • Two-dimensional (2D) correlation method, which generates the synchronous and the asynchronous 2D spectrum by complex cross correlation of the Fourier transformed spectra, is an analysis method for the changes of the sample spectrum induced by vari ous perturbations. In the present work, the 2D electronic correlation spectra have been simulated for the cases where the sample spectrum composed of two gaussian bands changes linearly. When only the band amplitudes of the sample spectrum change, the synchronous spectrum shows strong peaks at the band centers of the sample spectrum, but the asynchronous spectrum does not make peaks. When the sample spectrum shifts without changing intensity and width, the synchronous spectrum shows peaks around the initial and final positions of the band maximum and the asynchronous spectrum shows long peaks spanning the shifting range. The band width change produces the complex 2D correlation spectra. When the sample spectrum shifts with band broadening, the width change by 50% of full width at half maximum (FWHM) does not give so large an effect on the correlation spectrum as the spectral shift by one half of FWHM of the sample spectrum.

CARS Spectra of HCI, N₂, and C₂H₂ in the Gas Phase

  • 백선종;김중희;박주연;이성열;김홍래
    • Bulletin of the Korean Chemical Society
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    • v.16 no.9
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    • pp.810-813
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    • 1995
  • Coherent anti-Stokes Raman scattering (CARS) spectra of HCl, N2, and the ν1 fundamental of C2H2 have been measured in the gas phase. The measured spectra show rotational structures which originate from the Q-branch transitions. The spectra have successfully been simulated with proper selection rules, line positions, and relative intensities from room temperature Boltzmann population distributions. The vibration-rotation interaction constant α of HCl in the ground electronic state has been measured from the rotationally resolved CARS spectra which is α=0.3076 cm-1. Possibilities of optical pumping and of measuring state specific energy distributions of molecules are discussed.

Vertical response spectra for an impact on ground surface

  • Constantopoulos, Ioannis V.;Van Wessem, Yukiko;Verbrugge, Jean-Claude
    • Earthquakes and Structures
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    • v.3 no.3_4
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    • pp.435-455
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    • 2012
  • An impact on the ground surface may represent several phenomena, such as a crash of an airplane or an explosion or the passage of a train. In order to analyze and design structures and equipment to resist such a type of shocks, the response spectra for an impact on the ground must be given. We investigated the half-space motions due to impact using the finite element method. We performed extensive parametric analyses to define a suitable finite element model and arrive at displacement time histories and response spectra at varying distances from the impact point. The principal scope of our study has been to derive response spectra which: (a) provide insight and illustrate in detail the half-space response to an impact load, (b) can be readily used for the analysis of structures resting on a ground subjected to an impact and (c) are a new family of results for the impact problem and can serve as reference for future research.

A Study on the High Resolution Infrared Spectra of an Asymmetric Top Molecule $CF_2Cl_2$

  • Jung, Hyun-Chai
    • Bulletin of the Korean Chemical Society
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    • v.9 no.5
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    • pp.275-280
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    • 1988
  • The high resolution IR spectra of freon-12($CF_2Cl_2$) for the bands of 671cm$^{-1},\;922cm^{-1},\;1102cm^{-1},\;and\;1160cm^{-1}$ were taken and the rotational vibrational analysis has been carried out. The band types of $671cm^{-1}\;and\;1102cm^{-1}$ were confirmed to be A and those of $922cm^{-1}\;and\;1160cm^{-1}$ were confirmed to be B. The theoretically synthesized spectra were matched with the experimentally obtained spectra to get some informations of the molecular rotational behavior as well as the overall band shape of the spectra.

Towards improved floor spectra estimates for seismic design

  • Sullivan, Timothy J.;Calvi, Paolo M.;Nascimbene, Roberto
    • Earthquakes and Structures
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    • v.4 no.1
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    • pp.109-132
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    • 2013
  • Current codes incorporate simplified methods for the prediction of acceleration demands on secondary structural and non-structural elements at different levels of a building. While the use of simple analysis methods should be advocated, damage to both secondary structural and non-structural elements in recent earthquakes have highlighted the need for improved design procedures for such elements. In order to take a step towards the formation of accurate but simplified methods of predicting floor spectra, this work examines the floor spectra on elastic and inelastic single-degree of freedom systems subject to accelerograms of varying seismic intensity. After identifying the factors that appear to affect the shape and intensity of acceleration demands on secondary structural and non-structural elements, a new series of calibrated equations are proposed to predict floor spectra on single degree of freedom supporting structures. The approach uses concepts of dynamics and inelasticity to define the shape and intensity of the floor spectra at different levels of damping. The results of non-linear time-history analyses of a series of single-degree of freedom supporting structures indicate that the new methodology is very promising. Future research will aim to extend the methodology to multi-degree of freedom supporting structures and run additional verification studies.

NEW INSIGHT ON BROWN DWARF ATMOSPHERES REVEALED BY AKARI

  • Sorahana, S.;Yamamura, I.
    • Publications of The Korean Astronomical Society
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    • v.27 no.4
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    • pp.183-184
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    • 2012
  • We present the latest results from the Mission Program NIRLT, the NIR spectroscopic observations of brown dwarfs using the IRC on board AKARI. The near-infrared spectra in the wavelength range between 2.5 and $5.0{\mu}m$ is especially important to study the brown dwarf atmospheres because of the presence of non-blended bands of major molecules, including $CH_4$ at $3.3{\mu}m$, $CO_2$ at $4.2{\mu}m$, CO at $4.6{\mu}m$ and $H_2O$ around $2.7{\mu}m$. Our observations were carried out in the grism-mode resulting in a spectral resolution of ~ 120. In total, 27 sources were observed and 18 good spectra were obtained. We investigate the behavior of three molecular absorption bands, CO, $CH_4$ and $CO_2$, in brown dwarf spectra relative to their spectral types. We find that the $CH_4$ band appears in the spectra of dwarfs later than L5 and CO band is seen in the spectra of all spectral types. $CO_2$ is detected in the spectra of late-L and T type dwarfs.