• 제목/요약/키워드: specific surface areas

검색결과 257건 처리시간 0.029초

Comparison of the Nitrification Efficiencies of Three Biofilter Media in a Freshwater System

  • Harwanto, Dicky;Oh, Sung-Yong;Jo, Jae-Yoon
    • Fisheries and Aquatic Sciences
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    • 제14권4호
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    • pp.363-369
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    • 2011
  • Total ammonia nitrogen (TAN) removal efficiencies of a sand filter (SF), polystyrene microbead filter (PF), and Kaldnes bead filter (KF) media were evaluated under ammonia loading rates of 5, 25, and 50 g $m^{-3}day^{-1}$. The volume of each filter media tested was 7 L, and the water flow rate for all filter media was 24 L/min. The specific surface areas of the SF, PF, and KF were 7,836, 3,287, and 500 $m^2/m^3$, respectively. Sand was fluidized and the other two media were trickle filtered. The volumetric TAN removal rate increased with increasing ammonia loading rate for all filter media. Mean volumetric TAN removal rates under the ammonia loading rates of 5, 25, and 50 g $m^{-3}day^{-1}$ in SF (39.3, 168.6, and 322.7 g $m^{-3}day^{-1}$, respectively) were higher than those in PF (35.0, 157.4, and 310.5 g $m^{-3}day^{-1}$, respectively) and KF (32.1, 142.5, and 288.1 g $m^{-3}day^{-1}$, respectively). These results were related to differences in the specific surface areas of the filter media. PF was the most economic media for efficiently removing TAN.

Radionuclide-Specific Exposure Pathway Analysis of Kori Unit 1 Containment Building Surface

  • Byon, Jihyang;Park, Sangjune;Ahn, Seokyoung
    • 방사성폐기물학회지
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    • 제18권3호
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    • pp.347-354
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    • 2020
  • Site characterization for decommissioning Kori Unit 1 is ongoing in South Korea after 40 years of successful operation. Kori Unit 1's containment building is assumed to be mostly radioactively contaminated, and therefore radiation exposure management and detailed contamination investigation are required for decommissioning and dismantling it safely. In this study, site-specific Derived Concentration Guideline Levels (DCGLs) were derived using the residual radioactivity risk evaluation tool, RESRAD-BUILD code. A conceptual model of containment building for Kori Unit 1 was set up and limited occupational worker building inspection scenario was applied. Depending on the source location, the maximum contribution source and exposure pathway of each radionuclide were analyzed. The contribution of radionuclides to dose and exposure pathways, by source location, is expected to serve as basic data in the assessment criteria of survey areas and classification of impact areas during further decommissioning and decontamination of sites.

도시지역을 관통하는 홍수파의 특성에 관한 수치적 연구 (2) : 적용 및 분석 (A Numerical Study on Characteristics of Flood Wave Passing through Urban Areas (2) : Application and Analysis)

  • 정우창;조용식;이진우
    • 한국방재학회 논문집
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    • 제10권1호
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    • pp.65-72
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    • 2010
  • 본 연구에서는 댐 붕괴로 인한 홍수파에 영향을 미치는 도시지역의 효과에 대해 두 가지 수리모형실험에 근거하여 수치적으로 분석되었으며, 계산된 지점별 수심은 측정결과와 비교적 잘 일치하였다. 첫 번째 수리모형실험에 대해 도시지역 전반부에서 상대적으로 높은 수심영역과 흐름의 지체현상이 발생하였으며, 홍수파의 원활한 전파에 큰 장애요소가 됨을 알 수 있었다. 두번째 수리모형실험에 대해서는 유입량의 증가에 따라 도시지역의 전반부에서 후반부로 전파될 때 수심은 급격히 감소하는 구간과 느리게 감소하는 구간으로 구별되며, 도시지역 전반부에 도달하는 홍수파의 최초시간은 유입량이 증가함에 따라 감소되는 경향을 나타내었다.

Magnetite와 무기성 슬러지의 이산화탄소 분해 특성 (Decomposition Characteristics of Carbon Dioxide Using Magnetite and Inorganic Sludge)

  • 박준석;전제열;박영구
    • 한국응용과학기술학회지
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    • 제27권3호
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    • pp.344-352
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    • 2010
  • Magnetite and inorganic sludge were mainly composed of $Fe_2O_4$ and $Fe_2O_3$, respectively. Initial specific surface areas of magnetite and inorganic sludge were 130 $m^2$/g and 31.7 $m^2$/g. $CO_2$ decomposition rate for inorganic sludge was increased with temperature. Maximum $CO_2$ decomposition rates were shown 89% for magnetite at $350^{\circ}C$ and 84% for inorganic sludge at $500^{\circ}C$. Specific surface area for magnetite was not varied significantly after $CO_2$ decomposition. However, specific surface area for inorganic sludge was greatly decreased from initial 130 $m^2$/g to approximately 50~60 $m^2$/g after reaction. Therefore, it was estimated that magnetite could be used for $CO_2$decomposition for a long time and inorganic sludge should be wasted after $CO_2$ decomposition reaction.

Formation of an aluminum hydroxide nanofiber by a hydrolysis of aluminum nanopowder

  • Oh Young-Hwa;Lee Geun-Hee;Park Joong-Hark;Rhee Chang-Kyu;Kim Whung-Whoe
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2004년도 International Symposium on Powder Materials and Processing
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    • pp.80-81
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    • 2004
  • The results obtained are summarized as follows; (1) Boehmite produced in the high temperature and acid region showed a nano fibrous shape with several nm in diameter and several hundreds nm in length having high specific surface areas with a maximum value of $409m^2/g$. (2) In order to obtain nano fibrous boehmite with high surface areas from nano metal powder, the hydrolysis reaction should be done at a high temperature over $50^{\circ}C$, high acidity under pH 6, and terminated before a transition to the bayerite phase.

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페놀 수지로부터 유도된 금속이 함유된 활성탄의 특성화 (Characterization of metal-containing activated carbon derived from phenolic resin)

  • 오원춘;장원철;김범수
    • 분석과학
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    • 제14권4호
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    • pp.349-355
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    • 2001
  • 금속 염화물을 이용한 화학적 활성화 방법으로 페놀 수지로부터 미세기공과 증기공을 가지는 활성탄을 제조하였다. 본 연구에서 질소 흡착 데이터는 생성된 활성탄 표면의 물리적 성질을 특성화하는데 사용하였다. 표면 특성과 공동분포 분석 결과로부터, 페놀수지는 $962.3m^2/g$ 이상의 비표면적을 가지는 미세기공과 증기공을 가지는 활성탄을 생성함을 나타내었다. 이러한 동공구조를 가지는 활성탄은 금속 염화물($CdCl_2$, $CuCl_2$)의 양을 조절하여 만들어 졌으며, 동공의 발달은 금속염화물의 양이 증가함에 따라 증가함을 알 수 있었다. 열역학적인 DSC 데이터로부터, 첫 번째 발열반응의 엔탈피 변화 값(${\Delta}H$)은 금속염화물의 증가와 함께 증가하였다.

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Synthesis and Hydrogen Adsorption Properties of Porous Polymer

  • Wang, Qi;Liu, Jin;Zhang, Jing;Oh, Won-Chun
    • 한국재료학회지
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    • 제26권6호
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    • pp.332-336
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    • 2016
  • Three kinds of porous polymer were synthesized using a solvothermal of tri-4,4'-diphenylmethane diisocyanate (MDI-trimer) and different diamino monomers. The effects of the synthesis conditions and the monomer selection on the synthesis of porous polymer properties were studied. The results show that the synthesis of $NH_2$-containing monomer molecules smaller the microporous polymers was easy to implement; the specific surface areas of the polymers are related to the monomer ratio and the reaction time. The results show that the synthesized porous polymer had good hydrogen storage performance; the hydrogen storage ability improved with the addition of heterocyclic nitrogen.

유기물 첨가에 따른 다공성 실리카 세라믹스의 제조 및 특성(I) (Synthesis and Characteristics of Porous Silica Ceramics with Organic Additives(I))

  • 신진용;이범재;노재성
    • 한국세라믹학회지
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    • 제35권9호
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    • pp.958-968
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    • 1998
  • Porous silica ceramics were prepared using DCCA(Drying Control Chemical Additives) Such as uncharged polymer(Polyethylene glycol) and protein (Lipase) under H2O/Low-grade TEOS=10 C2H5OH/Low-grade TEOS=1 HC1/Low=grade TEOS=0.01 After Plain which doesn't added DCCA and samples of 11 sorts which varied molecular weight of PEG(Mw=600, 1000, 2000) quantity of Lipase and concentration of wat-er were synthesized gellation time and thermal analysis were investigated. After heat-treated at 600, cry-stal structures analyses of SiO2 polymer and characteristics of pores were investigated. Gellation time was retarded about 2-6 times as compared with plain resulting in addition of DCCA and crystal structures ex-hibited amorphous state. Moreover as increase of water a short gellation time was obtained. The samples added PEG showed increase of specific surface areas up to 20-40% and had micropores while those of Lipase were decreased about 90% and showed broad pore size distribution.

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Variation in Microbial Biomass and Community Structure in Sediments of Peter the Great Bay (Sea of Japan/East Sea), as Estimated from Fatty Acid Biomarkers

  • Zhukova Natalia V.
    • Ocean Science Journal
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    • 제40권3호
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    • pp.145-153
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    • 2005
  • Variation in the microbial biomass and community structure found in sediment of heavily polluted bays and the adjacent unpolluted areas were examined using phospholipid fatty acid analysis. Total microbial biomass and microbial community structure were responding to environmental determinants, sediment grain size, depth of sediment, and pollution due to petroleum hydrocarbons. The marker fatty acids of microeukaryotes and prokaryotes - aerobic, anaerobic, and sulfate-reducing bacteria - were detected in sediments of the areas studied. Analysis of the fatty acid profiles revealed wide variations in the community structure in sediments, depending on the extent of pollution, sediment depth, and sediment grain size. The abundance of specific bacterial fatty acids points to the dominance of prokaryotic organisms, whose composition differed among the stations. Fatty acid distributions in sediments suggest the high contribution of aerobic bacteria. Sediments of polluted sites were significantly enriched with anaerobic bacteria in comparison with clean areas. The contribution of this bacterial group increased with the depth of sediments. Anaerobic bacteria were predominantly present in muddy sediments, as evidenced from the fatty acid profiles. Relatively high concentrations of marker fatty acids of sulfate-reducing bacteria were associated with organic pollution in this site. Specific fatty acids of microeukaryotes were more abundant in surface sediments than in deeper sediment layers. Among the microeukaryotes, diatoms were an important component. Significant amounts of bacterial biomass, the predominance of bacterial biomarker fatty acids with abundance of anaerobic and sulfate-reducing bacteria are indicative of a prokaryotic consortium responsive to organic pollution.

Preparation and Properties of Pelletized Activated Carbons Using Coconut Char and Coal-Tar Pitch

  • Yang, Seung-Chun;Lee, Young-Seak;Kim, Jun-Ho;Lim, Chul-Kyu;Park, Young-Tae
    • Carbon letters
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    • 제2권3_4호
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    • pp.176-181
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    • 2001
  • A series of activated carbons were prepared from coconut shells and coal-tar pitch binder by physical activation with steam in this study. The effect of variable processes such as activation temperature, activation time and ratio of mixing was investigated for optimizing those preparation parameters. The activation processes were carried out continuously. The nitrogen adsorption isotherms at 77 K on pellet-shaped activated carbons show the same trend of Type I by IUPAC classification. The average pore sizes were about 19-21${\AA}$. The specific surface areas ($S_{BET}$) of pellet typed ACs increased with increasing the activation temperature and time. Specific surface area of AC treated for 90 min at temperature $900^{\circ}C$ was 1082 $m^2/g$. The methylene blue numbers continuously increased with increasing the activation temperature and time. On the other hand, iodine numbers highly increased till activation time of 60 min, but the rate of increase of iodine numbers decreased after that time. This indicates that new micropores were created and the existing micropores turned into mesopores and macropores because of increased reactivity of carbon surface and $H_2O$.

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