• Title/Summary/Keyword: specific heat coefficient

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Crystal Growth of Yb:YCa4O(BO3)3 and Investigation of Spectroscopic and Thermal Properties (Yb:YCa4O(BO3)3 단결정 성장과 분광 및 열적 특성 연구)

  • Kim, Choong-Ryeul;Lee, Hyeon-Jun;Yu, Young-Moon
    • Journal of the Korean Ceramic Society
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    • v.39 no.8
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    • pp.795-800
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    • 2002
  • Yb:$YCa_4O(BO_3)_3$ (Yb:YCOB) single crystal, in which the concentration of $Yb^{3+}$ ion 20 at%, was grown by the Czocharalski method using an iridium crucible under N2 atmosphere. The optimum growth parameters to get a high quality of single crystals were found to be 1.5∼2 mm/h of pulling rate and 10∼20 rpm of rotation rate. According to the results of spectroscopic properties, absorption edge of Yb:YCOB was 236 nm. Two strong absorption line due to $Yb^{3+}$ ions were observed at 900 and 975 nm. Thermal expansion coefficients of Yb:YCOB crystal along a, b and c crystallographic axes from 320 to 650 K were 12.1${\times}10^{-6}$/K, 5.9${\times}10^{-6}$/K, 12.9${\times}10^{-6}$/K, respectively. Specific heat was 0.162 $cal/g{\cdot}K$ at 330 K.

Adsorption of Cd on Carbonaceous Adsorbent Developed from Automotive Waste Tire (자동차 폐타이어로부터 발달된 탄소질 흡착제에 의한 Cd의 흡착)

  • Kim, Younjung;Uh, Eun Jeong;Choi, Jong Ha;Hong, Yong Pyo;Kim, Daeik;Ryoo, Keon Sang
    • Journal of the Korean Chemical Society
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    • v.61 no.6
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    • pp.339-345
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    • 2017
  • Carbonaceous adsorbent (CA-WTP) was prepared by heat treatment at $400^{\circ}C$ for 2 h in N2 atmosphere using waste tire powder (WTP). WTP and CA-WTP were first characterized by thermo-gravimetric analysis (TGA), energy dispersive X-ray spectrometer (EDS), scanning electron microscopy (SEM), specific surface area analysis (BET) and FT-IR spectroscopy. Then, they were tested as adsorbents for removal of Cd in water. CA-WTP exhibited much higher specific surface area and total pore volume than WTP itself and showed higher adsorption capacity for Cd. Equilibrium data of adsorption were analyzed using Freundlich and Langmuir isotherm models. It was seen that both Freundlich and Langmuir isotherms have correlation coefficient $R^2$ value larger than 0.95. The results of studies indicate that CA-WTP developed from WTP by heat treatment could be used as efficient adsorbent for the removal Cd from water.

Friction Stability of Materials with $ZrSiO_4$ Addition ($ZrSiO_4$가 첨가된 마찰재의 마찰 안정성)

  • 이동규;박상찬
    • Journal of the Korean Society of Safety
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    • v.14 no.3
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    • pp.110-119
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    • 1999
  • This study was conducted to invent brake of non-steel material without using asbestos and disc pad added $ZrSiO_4$ was made. The physical properties and friction characteristics were investigated by varying methods. The physical properties were inspected of shear strength, hardness, heat expansion, specific gravity, % of gashole, thickness variation, weight variation and pH variation. The friction stability was measured by friction coefficient on variations of speed, temperature and deceleration condition. It was found that the physical properties were in general excellent. According to the friction characteristics tests, $ZrSiO_4$ had an abrasive property. As a results, the friction materials containing $ZrSiO_4$ 3~5vol% showed better resistance to fading and improved friction stability than the materials without ZrSiO$_4$.

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Nanocrystalline Materials-an Overview

  • Suryanarayana, C.
    • Journal of Powder Materials
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    • v.3 no.4
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    • pp.233-245
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    • 1996
  • Nanocrystalline materials, with a grain size of typically <100 nm, are a new class of materials with properties vastly different from and often superior to those of the conventional coarse-grained materials. These materials can be synthesized by a number of different techniques and the grain size, morphology, and composition can be controlled by controlling the process parameters. In comparison to the coarse-grained materials, nanocrystalline materials show higher strength and hardness, enhanced diffusivity, improved ductility/toughness, reduced, density, reduced elastic modulus, higher electrical resistivity, increased specific heat, higher coefficient of thermal expansion, lower thermal conductivity, and superior soft and hard magnetic properties. Limited quantities of these materials are presently produced and marketed in the US, Canada, and elsewhere. Applications for these materials are being actively explored. The present article discusses the synthesis, structure, thermal stability, properties, and potential application of nanocrystalline materials.

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Thermoelectric Properties of PbTe Sintered Body Fabricated by Mechanical Alloying Process (기계적합금화 공정에 의해 제조된 PbTe 소결체의 열전특성)

  • 이길근;정해용;이병우
    • Journal of Powder Materials
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    • v.8 no.2
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    • pp.110-116
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    • 2001
  • Abstract To investigate the effect of mechanical alloying process to thermoelectric properties of PbTe sintered body, Pb-Te mixed powder with Pb : Te : 1 : 1 composition was mechanically alloyed using tumbler-ball mill. Thermoelectric properties of the sintered body were evaluated by measuring of the Seebeck coefficient and specific electric resistivity from the room temperature to 50$0^{\circ}C$. Sintered body of only mechanically alloyed PbTe powder showed p-type behavior at the room temperature, and occurred type transition from p-type to n-type at about 30$0^{\circ}C$. PbTe sintered body which was fabricated using heat treated powder in $H_2$ atmosphere after mechanical alloying showed stable n-type behavior under 50$0^{\circ}C$. N-type PbTe sintered body fabricated by mechanical alloying process had 4 times higher power factor than that fabricated by the melt-crushing process. Application of a mechanical alloying process to fabricate of n-type PbTe thermoelectric material seemed to be useful to increase the power factor of PbTe sintered body.

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Characteristics of Pressure-Drop Oscillations in a Boiling Channel (비등유로의 압력강하 요동특성)

  • Kim, B.J.;Shin, K.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.1
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    • pp.132-141
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    • 1995
  • Characteristics of pressure-drop oscillations(PDO) in a boiling channel were studied numerically and compared with experimental data. Effects of initial and boundary conditions on PDO were investigated in terms of oscillation period and amplitude. The period and amplitude of PDO increased with increasing of the compressible volume in the surge tank and the heat input. PDO occurred within the specific range of the fluid temperature, at which oscillation period and amplitude diminished rapidly with the increase of the fluid temperature. The increase of the loss coefficient in fluid supply line resulted in slightly longer oscillation period and larger amplitude. Numerical results showed good agreement with the experimental data.

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A Compilation and Evaluation of Thermal and Mechanical Properties of Bentonite-based Buffer Materials for a High- level Waste Repository

  • Cho, Won-Jin;Lee, Jae-Owan;Kang, Chul-Hyung
    • Nuclear Engineering and Technology
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    • v.34 no.1
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    • pp.90-103
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    • 2002
  • The thermal and mechanical properties of compacted bentonite and bentonite-sand mixture were collected from the literatures and compiled. The thermal conductivity of bentonite is found to increase almost linearly with increasing dry density and water content of the bentonite. The specific heat can also be expressed as a function of water ontent, and the coefficient of thermal expansion is almost independent on the dry density. The logarithm of unconfined compressive strength and Young’s modulus of elasticity increase linearly with increasing dry density, and in the case of constant dry density, it can be fitted to a second order polynomial of water content. Also the unconfined compressive strength and Young’s modulus of elasticity of the bentonite-sand mixture decreases with increasing sand content. The Poisson’s ratio remains constant at the dry density higher than 1.6 Mg/m$_3$, and the shear strength increases with increasing dry density.

Predicting the Frequency of Combustion Instability Using the Measured Reflection Coefficient through Acoustic Excitation

  • Bae, Jinhyun;Yoon, Jisu;Joo, Seongpil;Kim, Jeoungjin;Jeong, Chanyeong;Sohn, Chae Hoon;Borovik, Igor N.;Yoon, Youngbin
    • International Journal of Aeronautical and Space Sciences
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    • v.18 no.4
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    • pp.797-806
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    • 2017
  • In this study, the reflection coefficient (RC) and the flame transfer function (FTF) were measured by applying acoustic excitation to a duct-type model combustor and were used to predict the frequency of the combustion instability (CI). The RC is a value that varies with the excitation frequency and the geometry of the combustor as well as other factors. Therefore, in this study, an experimentally measured RC was used to improve the accuracy of prediction in the cases of 25% and 75% hydrogen in a mixture of hydrogen and methane as a fuel. When the measured RCs were used, an unstable condition was correctly predicted, which had not been predicted when the RCs had been assumed to be a certain value. The reason why the CI occurred at a specific frequency was also examined by comparing the peak of the FTF with the resonance frequency, which was calculated using Helmholtz's resonator analysis and a resonance frequency equation. As the CI occurred owing to the interaction between the perturbation in the rate of heat release and that in the pressure, the CI was frequent when the peak of the FTF was close to the resonance frequency such that constructive interference could occur.

Analysis of Sensitivity, Correlation Coefficient and PCA of Input and Output Parameters using Fire Modeling (화재모델링을 이용한 입출력 변수의 민감도, 상관계수 분석과 주성분 분석)

  • Nam, Gi Tae;Kim, Jeong Jin;Yoon, Seok Pyo;Kim, Jun Kyoung
    • Journal of the Korean Society of Safety
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    • v.34 no.5
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    • pp.46-54
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    • 2019
  • Even though the fire performance-based design concept has been introduced for various structures and buildings, which have their own specific fire performance level, the uncertainties of input parameters always exist and, then, could reduce significantly the reliability of the fire modeling. Sensitivity analysis was performed with three limited input parameters, HRRPUA, type of combustible materials, and mesh size, which are significantly important for fire modeling. The output variables are limited to the maximum HRR, the time reaching the reference temperature($60^{\circ}C$), and that to reach limited visible distance(5 m). In addition, correlation coefficient analysis was attempted to analyze qualitatively and quantitatively the degree of relation between input and output variables above. Finally, the relationship among the three variables is also analyzed by the principal component analysis (PCA) to systematically analyze the input data bias. Sensitivity analysis showed that the type of combustible materials is more sensitive to maximum HRR than the ignition source and mesh size. However, the heat release parameter of the ignition source(HRR) is shown to be much more sensitive than the combustible material types and mesh size to both time to reach the reference temperature and that to reach the critical visible distance. Since the derived results can not exclude the possibility that there is a dependency on the fire model applied in this study, it is necessary to generalize and standardize the results of this study for the fire models such as various buildings and structures.

COMPUTATION OF LAMINAR NATURAL CONVECTION OF NANOFLUID USING BUONGIORNO'S NONHOMOGENEOUS MODEL (Buongiorno의 비균질 모델을 사용한 나노유체의 층류 자연대류 해석)

  • Choi, S.K.;Kim, S.O.;Lee, T.H.
    • Journal of computational fluids engineering
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    • v.18 no.4
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    • pp.25-34
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    • 2013
  • A numerical study of a laminar natural convection of the CuO-water nanofluid in a square cavity using the Buongiorno's nonhomogeneous model is presented. All the governing equations including the volume fraction equation are discretized on a cell-centered, non-uniform grid employing the finite-volume method with a primitive variable formulation. Calculations are performed over a range of Rayleigh numbers and volume fractions of the nanopartile. From the computed results, it is shown that both the homogeneous and nonhomogeneous models predict the deterioration of the natural convection heat transfer well with an increase of the volume fraction of nanoparticle at the same Rayleigh number, which was observed in the previous experimental studies. It is also shown that the differences in the computed results of the average Nusselt number at the wall between the homogeneous and nonhomogeneous models are very small, and this indicates that the slip mechanism of the Brown diffusion and thermophoresis effects are negligible in the laminar natural convection of the nanofluid. The degradation of the heat transfer with an increase of the volume fraction of the nanoparticle in the natural convection of nanofluid is due to the increase of the viscosity and the decrease of the thermal expansion coefficient and the specific heat. It is clarified in the present study that the previous controversies between the numerical and experimental studies are owing to the different definitions of the Nusselt number.