• 한국환경기술학회지
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• 제19권6호
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• pp.586-599
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• 2018

산업단지의 배출시설관리와 배수로 수질오염물질의 배출 특성을 파악하기 위하여 하남산업단지와 첨단과학산업단지의 배출업체 16개 업체와 산업단지 배수로 4개를 포함한 11개 지점을 선정하여 조사하였다. 그 결과 배출업체 16개 업체 중 12개(75 %)의 업체에서 폐수배출시설 설치 허가 및 신고 시 등록한 항목이외의 특정수질유해물질이 검출되었고, 기타오염물질은 16개 업체 중 11개(약 69 %)의 업체에서 허가 및 신고 항목과 다른 오염항목이 검출된 것으로 조사되었다. 그리고 Formaldehyde, Mn, Zn, Ba 항목이 16개 업체 중 11개 업체에서 배출되는 것으로 나타났다. 특히, 특정수질유해물질 중 Cu는 0.029 ~ 0.929 mg/L로 모든 배출시설에서 검출 되는 것으로 나타났고, 영산강수계 주요 산단 배수로 및 본류에서도 As, Dichloromethane, Chloroform 등이 검출되었으나, 제한적인 범위(1종 ~ 3종)에서 수행되어 배출업체에서 배출되었다고 개연성을 평가하는 것은 한계가 있기 때문에 보다 많은 연구가 필요할 것으로 보인다. 향후 배출업체의 범위를 확대 조사하여 수질오염물질 DB를 구축하고, 허가 및 신고사항을 배출물질에 맞게 개선하는 것이 필요하다.

• 한국재료학회지
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• 제29권12호
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• pp.812-817
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• 2019

A zinc-air battery is one of most promising advanced batteries due to its high specific energy density, low cost, and environmental friendliness. However, zinc anodes in zinc-air batteries lead to several issues including self-discharge, corrosion reaction, and hydrogen evolution reaction (HER). In this paper, viscosity of electrolyte has been controlled to suppress the corrosion reaction, HER, and self-discharge behavior. Various viscosity average molecular weights of poly(acrylic acid) (PAA) are adopted to prepare the electrolyte. The evaporation of electrolytes is proportional to the increase in molecular weight. In addition, enhanced self-discharge behavior is obtained when the gelling agent with high molecular weight is used. In addition, the zinc-air cell assembled with lower viscosity average molecular weight of PAA (M_v ~ 450,000) delivers 510.85 mAh/g and 489.30 mAh/g of discharge capacity without storage and with 6 hr storage, respectively. Also, highest capacity retention (95.78 %) is obtained among studied materials.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.3003-3008
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• 2007

Critical nozzle has been frequently employed to measure the flow rate of various gases, but hydrogen gas, especially being at high-pressure condition, was not nearly dealt with the critical nozzle due to treatment danger. According to a few experimental data obtained recently, it was reported that the discharge coefficient of hydrogen gas through the critical nozzle exceeds unity in a specific range of Reynolds number. No detailed explanation on such an unreasonable value was made, but it was vaguely inferred as real gas effects. For the purpose of practical use of high-pressure hydrogen gas, systematic research is required to clarify the critical nozzle flow of high-pressure hydrogen gas. In the present study, a computational fluid dynamics(CFD) method has been applied to predict the critical nozzle flow of high-pressure hydrogen gas. Redlich-Kwong equation of state that take account for the forces and volume of molecules of hydrogen gas were incorporated into the axisymmetric, compressible Navier-Stokes equations. A fully implicit finite volume scheme was used to numerically solve the governing equations. The computational results were validated with some experimental data available. The results show that the coefficient of discharge coefficient is mainly influenced by the compressibility factor and the specific heat ratio, which appear more remarkable as the inlet total pressure of hydrogen gas increases.

• Macromolecular Research
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• 제10권1호
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• pp.40-43
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• 2002

Poly(1', 4'-phenylene-1", 4"-(2"-(2""-ethyl-hexyloxy)) phenylene-1",4"-phenylene-2,5-oxadiazolyl) (PPEPPO) was synthesized and its electrochemical characteristics was investigated as electrode material in redox supercapacitor. The cyclic voltammetry (CV) shows there was scarcely a redox reaction and further suggests n-doping is difficult to occur in this system. However, the discharge curve between 3.0 to 0.01 V is continuously decreased like a straight line, similar to the discharge pattern of EDLC. The initial specific discharge capacitance is ~6.4 F/g, while the specific capacitance of 1000th cycle is ~0.1 F/g. The PPEPPO can be used as the electrode of supercapacitor, emissive material, as well as charge-transporting material in polymer LED.ansporting material in polymer LED.

• 물과 미래
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• 제26권4호
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• pp.85-95
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• 1993

본 연구의 목적은 도시소유역에서의 부족한 유량 및 NPS 오염물 자료의 확충과 이를 통한 유출과 NPS 오염물 배출 간의 상관관계의 분석 및 월, 년 NPS 부하량 산정에 의한 물질수지의 분석에 있다. 본 연구를 위한 자료의 확충을 위해서 미국 EPA의 SWMM 모형을 사용하였으며, 상관관계의 분석 및 물질수지의 분석은 NPS 오염에 가장 영향이 큰 선행괘천기간을 긴 경우(CASE 1.)와 짧은 경우(CASE 2.)로 분리하여 수행하였으며, 연구 결과를 요약하면 다음과 같다. 1) 사상별 시간자료의 분석 : CASE 1.과 CASE 2. 모두, 유량과 농도간의 상관관계 보다는 유량과 부하량간의 상관관계가 좋았으며, 선형 상관관계보다는 비선형 상관관계가 좋았다. 결과적으로 두 CASE 모두 비유량-비부하율 관계는 비선형 산관관계가 가장 좋았다. 2) 사상별 총량자료의 분석 : CASE 1.은 비누적유량-비누적부하량의 선형상관관계가 CASE 2.는 비선형 상관관계가 좋았다. 3) 유역의 NPS 년비부하량 산정 결과, 년평균 단위 강우량당 비부하량은 CASE 1.이 CASE 2.보다 모든 오염물에서 약 2.5배였다. 4) 호우기와 갈수기의 NPS 오염물의 비교 결과, 갈수기의 CASE 1.의 비중이 훨씬 컸다. 5) NPS 년비부하량과 PS 년비부하량을 비교한 결과, NPS 오염물이 유역 및 하천의 오염에 상당히 기여함을 알 수 있었다.

• 한국수자원학회논문집
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• 제38권6호
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• pp.485-494
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• 2005

유량과 수질의 관계를 분석하는 것은 매우 중요하다. 하천의 실시간적 관리를 위해서는 유량과 수질의 측정이 동일한 지점에서 동시간적으로 이루어져야 보다 효과적이다. 그러나 수질자동측정망 지점과 T/M 수위관측소가 원거리에 위치한 경우들이 있으며, 평창강 수질자동측정망 지점이 그 중 하나이다. 이러한 지점에서는 보다 정확한 유량 산정과 이를 활용한 예측 프로그램이나 시스템이 요구된다. 이번 연구에서는 미계측 지점인 평창강 수질자동측정망 지점에 유량예측 신경망 모형을 적용하고, 적용성을 검토하기 위해 WMS 모형의 모의결과와 비교하였다. WMS 모형은 첨두유량이 작고, 수문곡선이 단조로운 사상에 적합한 것으로 나타났다. 신경망 모형의 유출량 예측값은 비유량과 WMS 모형의 모의값에 근사하였으며, 미계측 지점에서의 유출량 변화성향을 잘 반영하는 것으로 나타났다.

• Macromolecular Research
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• 제17권10호
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• pp.746-749
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• 2009

Poly(ethylene terephthalate) (PET) fabric/poly(3,4-ethylenedioxythiophene) (PEDOT) composite with stable and high electrochemical activity was fabricated by chemical and electrochemical polymerization of 3,4-ethylenedioxythiophene (EDOT) on a PET fabric in sequence. Effects of polymerization conditions on the following characteristics of the composite were studied: electrical conductivity and surface morphology. The electrochemical properties were also investigated by cyclic voltammetry and cyclic charge/discharge experiments. The specific volume resistivity, electrical conductivity and specific discharge capacitance of the composite were 0.034 $\Omega-cm$ and 25 S/cm, and 54.5 F/g, respectively.

• Journal of Electrochemical Science and Technology
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• 제3권4호
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• pp.178-184
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• 2012

A porous nickel (P-Ni) substrate was prepared by selective leaching of zinc from pressed pellets containing powders of Ni & Zn in 4 M NaOH solution. Anodic deposition of manganese oxide onto the porous Ni substrate ($MnO_x$/P-Ni) formed nano-flakes of manganese oxide layers as revealed in SEM studies. Pseudocapacitance of this oxide electrode was evaluated by cyclic voltammetry (CV) and chronopotentiometry (CHP) in 2 M NaOH solution. The specific capacitance of the Mn oxide electrode was as high as 1515 F $g^{-1}$, which was ten times higher than Mn oxide deposited on a flat Ni-ribbon. 80% of capacity was retained after 200 charge/discharge cycles. The system showed no loss of activity in dry form over period of days. The impedance studies indicated highly conducting $MnO_x$/P-Ni substance and the obtained specific capacitance from impedance data showed good agreement with the charge/discharge measurements.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2002년도 추계학술발표회
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• pp.28-31
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• 2002

The water level fluctuation (WLF) method is a conventional method for quantifying groundwater recharge by multiplying the specific yield to the water level rise. A 2-D unconfined flow model with a time series of the recharge rate is developed. It is used for elucidating the errors of the WLF method which is implicitly based on the tank model where the horizontal flow in the saturated zone is ignored. Simulations show that the recharge estimated by the WLF method is underestimated for the observation well near the discharge boundary. This is due to the fact that the hydraulic stress resulting from the recharge is rapidly dissipating by the horizontal flow near the discharge boundary Simulations also reveal that the recharge was significantly underestimated with increase in the hydraulic conductivity and the recharge duration, and decrease in the specific yield.

• 한국세라믹학회지
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• 제45권11호
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• pp.662-666
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• 2008

Electrochemical properties of carbon cryogel electrode for the application of composite electrode materials mixed with metal oxide in supercapacitor have been studied. Carbon cryogels were synthesized by sol-gel polycondensation of resorcinol with form aldehyde, followed by a freeze drying, and then pyrolysis in an inert atmosphere. Physical properties of carbon cryogel were characterized by BET, X-ray diffraction (XRD) and scanning electron microscopy (SEM). It is found that carbon cryogel is amorphous material. The electrochemical properties of carbon cryogel were measured by cyclic voltammetry as a function of concentration of liquid electrolyte, galvanostatic charge-discharge with different scan rates and electrochemical impedance measurements. The result of cyclic voltammetry indicated that the specific capacitance value of a carbon cryogel electrode was approximately 150.2 F/g (at 5 mV/s in 6M KOH electrolyte).