• 한국재료학회지
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• 제32권12호
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• pp.533-537
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• 2022

Flexible zinc-air batteries have many merits, including low cost, high safety, environmentally friendliness applicability, etc. One of the key factors to improve the performance of flexible zinc-air batteries is to use a gel electrolyte. In this study, gel electrolytes were synthesized from potato, sweet potato, and corn starch. In a comparison of each starch, the corn starch-based gel electrolyte showed the highest discharge capacity of 12.41 mAh/cm² in 20 mA and 6.47 mAh/cm² in 30 mA. It also delivered a higher specific discharge capacity of 7.06 mAh/cm² than the other materials after 100° bending. In addition, the electrochemical impedance spectroscopy (EIS) was analyzed to calculate the ionic conductivity. The potato, sweet potato, and corn starch-based gel electrolytes showed electrolyte resistances (Re) of 0.306, 0.298, and 0.207 Ω, respectively. In addition, the corn starch-based gel electrolyte delivered the highest ionic conductivity of 0.121 S cm^-1 among the other gel electrolytes. Thus, the corn starch-based gel electrolyte was verified to improve the performance of flexible zinc-air batteries.

• 한국분말재료학회지
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• 제15권5호
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• pp.352-358
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• 2008

The present study focused on the synthesis of a bismuth-antimony-tellurium-based thermoelectric nanopowders using plasma arc discharge process. The chemical composition, phase structure, particle size of the synthesized powders under various synthesis conditions were analyzed using XRF, XRD and SEM. The powders as synthesized were sintered by the plasma activated sintering. The thermoelectric properties of sintered body were analyzed by measuring Seebeck coefficient, specific electric resistivity and thermal conductivity. The chemical composition of the synthesized Bi-Sb-Te-based powders approached that of the raw material with an increasing DC current of the are plasma. The synthesized Bi-Sb-Te-based powder consist of a mixed phase structure of the $Bi_{0.5}Sb_{1.5}Te_{3}$, $Bi_{2}Te_{3}$ and $Sb_{2}Te_{3}$ phases. This powder has homogeneous mixing state of two different particles in an average particle size; about 100nm and about 500nm. The figure of merit of the sintered body of the synthesized 18.75 wt.%Bi-24.68 wt.%Sb-56.57 wt.%Te nanopowder showed higher value than one of the sintered body of the mechanically milled 12.64 wt.%Bi-29.47 wt.%Sb-57.89 wt.%Te powder.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1995년도 하계학술대회 논문집 C
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• pp.1034-1038
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• 1995

The purpose of this study is to research and develop $TiS_2$ composite cathode for lithium polymer battery(LPB). $TiS_2$ electrode represent a class of insertion positive electrode used in Li secondary batteries. In this study, we investigated preparation of $TiS_2$ composite cathode and AC impedance response of $TiS_2$ composite/SPE/Li cells as a function of state of charge(SOC) and cycling. The resistance of B type cell using $TiS_2PEO_8LiClO_4PC_5EC_5$ composite cathode was lower than that of A type cell using $TiS_2PEO$ composite cathode. The cell resistance of B type cell is high for the first few percent discharge, decreases for midium discharge and then increases again toward the end of discharge. We believe the magnitude of the cell resistance is dominated by passivation layer impedance and small cathode resistance. AC impedance results indicate that the cell internal resistance increase with cycling, and this is attributed to change of passivation layer impedance with cycling. The passivation layer resistance($R_f$) of B type cell decreases for the 2nd cycling and then increases again with cycling. Redox coulombic efficiency of B type cell was about 141% at 1st cycle and 100% at 12th cycle. Also, $TiS_2$ specific capacity was 115 mAh/g at 12 cycle.

• 항공우주기술
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• 제9권2호
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• pp.176-184
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• 2010

지구 저궤도 위성의 임무 운용 시 전력 시스템을 안전하고 운용하고 에너지 균형을 만족하는 임무를 설계하기 위해 계획된 임무에 대한 전력 파라미터를 예측해야 한다. 이 논문에서는 다양한 미션 프로파일에 대해 위성의 생성 전력, 소모 전력, 배터리 방전 정도(Depth of Discharge, 이하 DoD), 버스 전압, 충/방전 전류 등을 예측함으로써 미션의 유효성 및 에너지 균형을 검증하기 위한 전력 시뮬레이터를 제안한다. 제안된 전력 시뮬레이터에는 인공위성의 생성 전력을 모사하기 위해 태양전지판(Solar Array, 이하 SA)의 모델, SAR (Solar Array Regulator)의 3가지 동작 모드를 구현하였다. 또한 소모 전력을 모사하기 위해 버스 및 탑재체의 각 유닛 별 소모 전력, Unit on/off configuration, 탑재체 운용 모드 등을 고려하였다. 버스 전압 및 충/방전 전류를 예측하기 위해 배터리 및 주변 회로를 모델링하고 임의의 DoD, 충방전 전류에 대해 배터리 전압 및 버스 전압을 예측한다. 구현된 전력 시뮬레이터를 이용해 에너지 균형을 분석하고 임무 계획의 적합성을 쉽게 판단할 수 있다.

• 한국수소및신에너지학회논문집
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• 제13권4호
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• pp.259-269
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• 2002

A battery based on the lithium/elemental sulfur redox couple has the advantage of high theoretical specific capacity of 1,675 mAh/g-sulfur. However, Li/S battery has bad cyclic durability at room temperature due to sulfur active material loss resulting from lithium polysulfide dissolution. To improve the cycle life of Li/S battery, PEGDME (Poly(ethylene glycol) dimethyl ether) 500 containing 1M LiTFSI salt which has high viscosity was used as electrolyte to retard the polysulfide dissolution and nano-sized $Mg_{0.6}Ni_{0.4}O$ was added to sulfur cathode as additive to adsorb soluble polysulfide within sulfur cathode. From experimental results, the improvement of the capacity and cycle life of Li/S battery was observed( maximum discharge capacity : 1,185 mAh/g-sulfur, C50/C1 = 85 % ). Through the charge-discharge test, we knew that PEGDME 500 played a role of preventing incomplete charge-discharge $behavior^{1,2)$. And then, in sulfur dissolution analysis and rate capability test, we first confirmed that nano-sized $Mg_{0.6}Ni_{0.4}O$ had polysulfide adsorbing effect and catalytic effect of promoting the Li/S redox reaction. In addition, from BET surface area analysis, we also verified that it played the part of increasing the porosity of sulfur cathode.

• 한국생산제조학회지
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• 제6권4호
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• pp.72-79
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• 1997

A study is a experiment which is figure out to optimum discharge cutting condition of the surface roughness, electronic discharging speed and electrode wear ration with Ton , Toff and V(voltage) as an input condition according to the current(Ip) in an electric spark machine : 1) Electrode is utilized Cu and Graphite. 2) Work piece is used the material of carbon steel. The condition of experiment is : 1) Current is varied 0.7(A) to 50(A) and the time of electric discharging to work piece in each time is 30(min) to 60(min). 2) After the upper side of work piece was measured in radius(5$\mu$m) of stylus analyzed the surface roughness to ade the table and graph of Rmax by yielding data. 3) Electro wear ratio is : \circled1Cooper was measured ex-machining and post-machining by the electronic balance. \circled2The ex-machining of graphite measured by it, the post-machining was found the data from volume $\times$specific gravity and analyzed to made its table and graph on ground the data. 4) In order to keep the accuracy of voltage affected to the work piece was equipped with the A.V. R and the memory scope was sticked to the electric spark machine. 5) In order to preserve the precision of current, to get rid of the noise occured by internal resistance of electric spark machine and to force injecting for the discharge fluid , it made the fixed table for a work piece to minimize the work error by means of one's failure during the electric discharging.

• 조명전기설비학회논문지
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• 제22권4호
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• pp.107-113
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• 2008

본 실험은 구동 온도와 방전관의 길이에 따라 변화하는 ICP 광원의 전기 광학적 특성에 대해서 알아보았다. 광원의 전기 광학적 특성이 정상상태에 놓이는 구동 조건을 확인하기 위하여 시간에 따른 전력 소모와 광속의 변화를 측정하였다. 전력소모와 광속의 시간에 따른 변화를 측정한 결과를 통해서 볼 때 최초구동에서 70분이 경과한 이후부터 전력소모는 초기값에 대해 1.45[%], 광속은 0.36[%]의 안정성을 나타냈다. 항온챔버 내에서 온도를 5구간으로 나뉘어 변화하면서 구동 온도에 따른 ICP 광원의 광학적 특성을 알아보았다. 휘도는 온도의 상승과 비례적으로 증가하였으나 $46.7[^{\circ}C]$ 이상에서는 오히려 감소하는 결과를 얻을 수 있었다. 파센법칙과 함께 보일-샤를의 법칙을 통해 0.02[Torr]의 압력이 변화함에 따라 더 높은 방전전압이 요구되지만 충분한 전압이 안정기에서 공급되지 못하기 때문이라 판단된다. 이와 더불어 방전관 길이에 따라 광원에 인가되는 전력과 전류을 측정하였다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 추계학술발표회
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• pp.574-578
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• 2003

There are so many methods to estimate the groundwater recharge. These methods can be categorized into four groups. First groupis related to the water balance analysis, second group is concerned with baseflow/springflow recession, and third group is interested in some types of tracers; environmental tracers and/or temperature profile. The limitation of these types of methods is that the estimated results of recharge are presented in the form of an average over some time period. Forth group has a little different approach. They use the time series data of hydraulic head and specific yield evaluated from field test, and the results of estimation are described in the sequential form. But their approach has a serious problem. The estimated results in forth typeof methods are generally underestimated because they cannot consider the discharge phase of water table fluctuation coupled with the recharge phase. Ketchum el. at. (2000) proposed calibrated method, considering recharge- and discharge-coupled water table fluctuation. But the dischargeis considered just as the areal average with discharge rate. On the other hand, there are many methods to estimate the source wavelet with observed data set in geophysics/signal processing and geophysical methods are rarely applied to the estimation of groundwater recharge. The purpose this study is the evaluation of the applicability of one of the geophysical method in the estimation of sequential recharge rate. The applied geophysical method is called minimum entropy deconvolution (MED). For this purpose, numerical modeling with linearized Boussinesq equation was applied. Using the synthesized hydraulic head through the numerical modeling, the relative sequenceof recharge is calculated inversely. Estimated results are very concordant with the applied recharge sequence. Cross-correlations between applied recharge sequence and the estimated results are above 0.985 in all study cases. Through the numerical test, the availability of MED in the estimation of the recharge sequence to groundwater was investigated

• 한국진공학회:학술대회논문집
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• 한국진공학회 1999년도 제17회 학술발표회 논문개요집
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• pp.216-216
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• 1999

The usage of a stationary plasma thruster (SPT) ion source, invented previously for space application in Russia, in experiments with surface modifications and film deposition systems is reported here. Plasma in the SPT is formed and accelerated in electric discharge taking place in the crossed axial electric and radial magnetic fields. Brief description of the construction of specific model of SPT used in the experiments is presented. With gas flow rate 39ml/min, ion current distributions at several distances from the source are obtained. These was equal to 1~3 mA/$\textrm{cm}^2$ within an ion beam ejection angle of $\pm$20$^{\circ}$with discharge voltage 160V for Ar as a working gas. Such an extremely high ion current density allows us to obtain the Ti metal films with deposition rate of $\AA$/sec by sputtering of Ti target. It is shown a possibility of using of reactive gases in SPT (O2 and N2) along with high purity inert gases used for cathode to prevent the latter contamination. It is shown the SPT can be operated at the discharge and accelerating boltages up to 600V. The results of presented experiments show high promises of the SPT in sputtering and surface modification systems for deposition of oxide thin films on Si or polymer substrates for semiconductor devices, optical coatings and metal corrosion barrier layers. Also, we have been tried to establish in application of the modeling expertise gained in electric and ionic propulsion to permit numerical simulation of additional processing systems. In this mechanism, it will be compared with conventional DC sputtering for film microstructure, chemical composition and crystallographic considerations.

• 종양간호연구
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• 제3권1호
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• pp.5-14
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• 2003

The purpose of this study was to identify key educational and counseling needs of breast cancer patients in Korea. The data were collected from 102 breast cancer survivors. The instrument consisted of 66 items and the items were divided into five treatment stages: pre-admission, admission, discharge, chemotherapy, and radiation therapy. The subjects' mean age was 50 years and most of them were housewives. All had a mastectomy and among them 69 had chemotherapy and 42 had radiation therapy. Average post-surgical period was 47 months. The mean score of the subjects' needs was 2.99 out of 4 points. The highest educational need was to know about the method of recurrence prevention. In terms of the treatment stages, mean score for pre-admission was 3.09, admission 3.06, chemotherapy 3.03, after discharge 2.95, and radiation therapy 2.80. In the pre-admission period, etiology, diagnostic tests, treatment and prevention of the breast cancer were needed the most. During the admission period, symptom management after the operation had the highest score. After discharge, prevention of recurrence had the highest score. The results of this research will help in developing educational and counseling programs by understanding the specific needs of breast cancer patients based on the treatment stages.