• Journal of the Korean Society for Environmental Technology
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• v.19 no.6
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• pp.586-599
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• 2018

To learn about the discharge facility management of industrial complexes and the discharge characteristics of water pollutants in drainage, 11 sites were selected, including 16 discharge companies of Hanam Industrial Complex and High-Tech Scientific Industrial Complex and 4 drainages of the industrial complexes. Through the analysis, it was found that 12(75 %) of the 16 discharge companies had specific hazardous substances other than those registered at the time of installation and registration of the wastewater discharge facilities. In terms of other pollutants, 11 of the 16 companies(about 69 %) were found to have pollution items that differed from those included in approved and reported items lists. In addition, Formaldehyde, Mn, Zn, and Ba were discharged from 11 out of the 16 companies. Significantly, one of the specific hazardous water pollutants, Cu, was detected in all discharge facilities at levels from 0.029 to 0.929 mg/L. Even in major complexes drainages and the main stream of the Yeongsangang. As, Dichloromethane, and Chloroform were detected. However, it cannot be conclusively claimed that it is probable that these substances were actually discharged from the above facilities because research was only done in a limited range(Class 1 to Class 3), and therefore, further research is required. In the future, it will be necessary to expand the research scope of the discharge companies in order to establish a database of water pollutants, and to improve permits and reported items based on discharged substances.

• Korean Journal of Materials Research
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• v.29 no.12
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• pp.812-817
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• 2019

A zinc-air battery is one of most promising advanced batteries due to its high specific energy density, low cost, and environmental friendliness. However, zinc anodes in zinc-air batteries lead to several issues including self-discharge, corrosion reaction, and hydrogen evolution reaction (HER). In this paper, viscosity of electrolyte has been controlled to suppress the corrosion reaction, HER, and self-discharge behavior. Various viscosity average molecular weights of poly(acrylic acid) (PAA) are adopted to prepare the electrolyte. The evaporation of electrolytes is proportional to the increase in molecular weight. In addition, enhanced self-discharge behavior is obtained when the gelling agent with high molecular weight is used. In addition, the zinc-air cell assembled with lower viscosity average molecular weight of PAA (M_v ~ 450,000) delivers 510.85 mAh/g and 489.30 mAh/g of discharge capacity without storage and with 6 hr storage, respectively. Also, highest capacity retention (95.78 %) is obtained among studied materials.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3003-3008
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• 2007

Critical nozzle has been frequently employed to measure the flow rate of various gases, but hydrogen gas, especially being at high-pressure condition, was not nearly dealt with the critical nozzle due to treatment danger. According to a few experimental data obtained recently, it was reported that the discharge coefficient of hydrogen gas through the critical nozzle exceeds unity in a specific range of Reynolds number. No detailed explanation on such an unreasonable value was made, but it was vaguely inferred as real gas effects. For the purpose of practical use of high-pressure hydrogen gas, systematic research is required to clarify the critical nozzle flow of high-pressure hydrogen gas. In the present study, a computational fluid dynamics(CFD) method has been applied to predict the critical nozzle flow of high-pressure hydrogen gas. Redlich-Kwong equation of state that take account for the forces and volume of molecules of hydrogen gas were incorporated into the axisymmetric, compressible Navier-Stokes equations. A fully implicit finite volume scheme was used to numerically solve the governing equations. The computational results were validated with some experimental data available. The results show that the coefficient of discharge coefficient is mainly influenced by the compressibility factor and the specific heat ratio, which appear more remarkable as the inlet total pressure of hydrogen gas increases.

• Macromolecular Research
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• v.10 no.1
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• pp.40-43
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• 2002

Poly(1', 4'-phenylene-1", 4"-(2"-(2""-ethyl-hexyloxy)) phenylene-1",4"-phenylene-2,5-oxadiazolyl) (PPEPPO) was synthesized and its electrochemical characteristics was investigated as electrode material in redox supercapacitor. The cyclic voltammetry (CV) shows there was scarcely a redox reaction and further suggests n-doping is difficult to occur in this system. However, the discharge curve between 3.0 to 0.01 V is continuously decreased like a straight line, similar to the discharge pattern of EDLC. The initial specific discharge capacitance is ~6.4 F/g, while the specific capacitance of 1000th cycle is ~0.1 F/g. The PPEPPO can be used as the electrode of supercapacitor, emissive material, as well as charge-transporting material in polymer LED.ansporting material in polymer LED.

• Water for future
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• v.26 no.4
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• pp.85-95
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• 1993

Three purposes of this study are as follows: The first was the development of the extention method for the limited data observed in an urban drainage basin. The second was the analysis of the correlation between storm water runoff and NPS(non-point source) pollutant discharge, The last was the calculation of the monthly and annual specific NPS loads using the established correlation. the selected model was the SWMM monthly and annual specific NPs loads using the established correlation. The selected model was the SWMM (Storm Water Management model) developed by the US EPA(environmental Protection Agency). As a result of this study, the best correlation between storm wate runoff and NPS pollutants discharge was produced by the non-linear correlation between runoff rate(mm/hr)and specific loads rate(g/ha/sec)for all pollutants studied ; SS, COD, BOD, and TN. The best correlation through the analysis based on evently total mass was made by the linear correlation between the specific accumulated runoff(mm) and the specific accumulated loads(kg/ha) for CASE 1., and by the non-linear correlation for CASE 2. The NPS annual specific loads for the urban basin studied were 4933 kg/ha/year for SS, 775kg/ha/year for BOD, 3094kg/ha /year for COD,257kg/ha/year for TN, respectively. And the proportion of the NPS annual specific loads to the total annual specific loads were 42 % for SS, 13 % for BOD, 29% for COD, and 21 % for TN.

• Journal of Korea Water Resources Association
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• v.38 no.6 s.155
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• pp.485-494
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• 2005

It is very important to analyze the correlation between discharge and water quality. The observation of discharge and water quality are effective at same point as well as same time for real time management. But no less significant is the fact that there are some of real time water quality monitoring stations far from the T/M water stage. Pyeongchanggang station is one of them. In this case, it need to observe accurate discharge data, and to develop forecasting program or system using real time data. In this paper, discharge on Pyeongchanggang station was calculated by developed runoff neural network model, and compared with discharge using WMS(Watershed Modeling System) model. WMS shows better results when peak discharge is small and hydrograph is smooth. Forecasted discharge of neural network model have achieved the highest overall accuracy of specific discharge and WMS. Neural network model forecast change of discharge well on unrecored station.

• Macromolecular Research
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• v.17 no.10
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• pp.746-749
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• 2009

Poly(ethylene terephthalate) (PET) fabric/poly(3,4-ethylenedioxythiophene) (PEDOT) composite with stable and high electrochemical activity was fabricated by chemical and electrochemical polymerization of 3,4-ethylenedioxythiophene (EDOT) on a PET fabric in sequence. Effects of polymerization conditions on the following characteristics of the composite were studied: electrical conductivity and surface morphology. The electrochemical properties were also investigated by cyclic voltammetry and cyclic charge/discharge experiments. The specific volume resistivity, electrical conductivity and specific discharge capacitance of the composite were 0.034 $\Omega-cm$ and 25 S/cm, and 54.5 F/g, respectively.

• Journal of Electrochemical Science and Technology
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• v.3 no.4
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• pp.178-184
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• 2012

A porous nickel (P-Ni) substrate was prepared by selective leaching of zinc from pressed pellets containing powders of Ni & Zn in 4 M NaOH solution. Anodic deposition of manganese oxide onto the porous Ni substrate ($MnO_x$/P-Ni) formed nano-flakes of manganese oxide layers as revealed in SEM studies. Pseudocapacitance of this oxide electrode was evaluated by cyclic voltammetry (CV) and chronopotentiometry (CHP) in 2 M NaOH solution. The specific capacitance of the Mn oxide electrode was as high as 1515 F $g^{-1}$, which was ten times higher than Mn oxide deposited on a flat Ni-ribbon. 80% of capacity was retained after 200 charge/discharge cycles. The system showed no loss of activity in dry form over period of days. The impedance studies indicated highly conducting $MnO_x$/P-Ni substance and the obtained specific capacitance from impedance data showed good agreement with the charge/discharge measurements.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.28-31
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• 2002

The water level fluctuation (WLF) method is a conventional method for quantifying groundwater recharge by multiplying the specific yield to the water level rise. A 2-D unconfined flow model with a time series of the recharge rate is developed. It is used for elucidating the errors of the WLF method which is implicitly based on the tank model where the horizontal flow in the saturated zone is ignored. Simulations show that the recharge estimated by the WLF method is underestimated for the observation well near the discharge boundary. This is due to the fact that the hydraulic stress resulting from the recharge is rapidly dissipating by the horizontal flow near the discharge boundary Simulations also reveal that the recharge was significantly underestimated with increase in the hydraulic conductivity and the recharge duration, and decrease in the specific yield.

• Journal of the Korean Ceramic Society
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• v.45 no.11
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• pp.662-666
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• 2008

Electrochemical properties of carbon cryogel electrode for the application of composite electrode materials mixed with metal oxide in supercapacitor have been studied. Carbon cryogels were synthesized by sol-gel polycondensation of resorcinol with form aldehyde, followed by a freeze drying, and then pyrolysis in an inert atmosphere. Physical properties of carbon cryogel were characterized by BET, X-ray diffraction (XRD) and scanning electron microscopy (SEM). It is found that carbon cryogel is amorphous material. The electrochemical properties of carbon cryogel were measured by cyclic voltammetry as a function of concentration of liquid electrolyte, galvanostatic charge-discharge with different scan rates and electrochemical impedance measurements. The result of cyclic voltammetry indicated that the specific capacitance value of a carbon cryogel electrode was approximately 150.2 F/g (at 5 mV/s in 6M KOH electrolyte).