• Journal of the Korean Electrochemical Society
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• v.22 no.4
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• pp.164-171
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• 2019

Nano-sized $SnO_2$ powders were synthesized via a solvent thermal reaction using $SnClO_4$, NaOH, and ethylene glycol at $150^{\circ}C$. TGA, SEM, FT-IR, XRD, and Potentiostat/Galvanostat were employed to investigate the chemical and electrochemical characteristics of the synthesized $SnO_2$. The structure of $SnO_2$ was amorphous, and when heat treated at $500^{\circ}C$, it was transformed into a crystalline structure. The morphology obtained by SEM micrographs of the as-synthesized $SnO_2$ showed powder features that had diameters ranging 100 to 200 nm. The electrochemical performance of the crystalline $SnO_2$ as a Li-air battery cathode was better than that of the amorphous $SnO_2$. The specific capacity of the crystalline $SnO_2$ was at least 350 mAh/g at 10 mA/g discharge rate. However, there was some capacity loss of all the cells during the consecutive cycles. Keywords : Lithium-Air Battery.

• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.439-439
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• 2015

The temporal and spatial relationship of the weather elements such as rainfall and temperature is closely linked to the streamflow simulation, especially, to the flood forecasting problems. For the study area, Imjin river basin, which has the specific characteristics in geography with river cross operation between North and South Korea, the meteorological information in the northern area is totally deficiency, lead to the inaccuracy of streamflow estimation. In the paper, this problem is solved by using the combination of global (such as soil moisture content, land use) and local hydrologic components data such as weather data (precipitation, evapotranspiration, humidity, etc.) for the model-driven runoff (surface flow, lateral flow and groundwater flow) data in each subbasin. To compute the streamflow in Imjin river basin, this study is applied the hydrologic model SURR (Sejong Univ. Rainfall-Runoff) which is the continuous rainfall-runoff model used physical foundations, originally based on Storage Function Model (SFM) to simulate the intercourse of the soil properties, weather factors and flow value. The result indicates the spatial variation in the runoff response of the different subbasins influenced by the input data. The dependancy of runoff simulation accuracy depending on the qualities of input data and model parameters is suggested in this study. The southern region with the dense of gauges and the adequate data shows the good results of the simulated discharge. Eventually, the application of SURR model in Imjin riverbasin gives the accurate consequence in simulation, and become the subsequent runoff for prediction in the future process.

• Journal of Veterinary Clinics
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• v.38 no.5
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• pp.231-234
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• 2021

A 14-month-old, intact female Maltese (case 1) and a 26-month-old, spayed female Dachshund (case 2) had persistent regurgitation over 1 year and 2 years, respectively. In both cases, there were not specific findings in blood examination. Diagnostic imaging and fluoroscopy revealed that gastroesophageal reflux (GER) occurred when the patients ate a barium meal without abdominal contraction. They were treated with proton-pump inhibitor (esomeprazole), sucralfate and prokinetics (cisapride) while in a standing position for an hour after every meal, according to the gastroesophageal disease (GERD) suggested treatment. The case 1 dog was discharged with improved clinical signs, and the case 2 dog also had been improved clinical signs; however, aspiration pneumonia occurred in case 2, which was thought to be a complication from GERD. After receiving treatment for aspiration pneumonia, the case 2 dog was discharged from the hospital. Since there was no further improvement in symptoms after discharge, the case 1 dog was euthanized by owner's request, and the case 2 is alive, having only mild clinical signs upon the writing of this paper.

• Journal of ILASS-Korea
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• v.24 no.3
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• pp.105-113
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• 2019

In this paper, a study of Urea-SCR System for Dosing Injector for responding to enhanced environmental regulations has been conducted. There is a limit to the experimental approach due to the structural characteristics of the injector. In order to overcome this problem, The analysis was performed assuming unsteady turbulent flow through computational fluid analysis and the internal flow characteristics of the injector were analyzed. By changing the nozzle shape of the injector, the performance factors of the swirl injector by shape were selected and compared. The design parameters were modified by changing the diameter of the nozzle at a constant ratio compared to the base model. Swirl coefficient, outlet mass flow, and sac volume were selected as performance parameters of the injector. The Conv. model to which the taper was applied showed the dominance in mass flow rate, discharge coefficient and swirl because of the smooth fluid flow by shape. Swirl coefficient, outlet mass flow, and sac volume were selected as performance parameters of the injector. As a result of the comparison coefficient derivation with those performance parameters for comparing the performance of the model-specific injector, the Conv-140 model with the nozzle diameter expanded by 140% showed the best value of the comparison coefficient.

• Applied Chemistry for Engineering
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• v.30 no.3
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• pp.324-330
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• 2019

Petal-like nickel cobaltite ($NiCo_2O_4$)/reduced graphene oxide (rGO) composites with different $rGO-to-NiCo_2O_4$ weight ratios were synthesized using a simple hydrothermal method and subsequent thermal treatment. In the $NiCo_2O_4/rGO$ composite, the $NiCo_2O_4$ 3-dimensional nanomaterials contributed to the improvement of electrochemical properties of the final composite material by preventing the restacking of the rGO sheet and securing ion movement passages. The composite structure was examined by field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and Fourier-transform infrared (FT-IR) spectroscopy. The FE-SEM and TEM images showed that petal-like $NiCo_2O_4$ was supported on the rGO surface. Cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS) were used for the electrochemical analysis of composites. Among the prepared composites, $0.075g\;rGO/NiCo_2O_4$ composite showed the highest specific capacitance of $1,755Fg^{-1}$ at a current density of $2Ag^{-1}$. The cycle performance and rate capability of the composite material were higher than those of using the single $NiCo_2O_4$ material. These nano-structured composites could be regarded as valuable electrode materials for supercapacitors that require superior performance.

• Progress in Superconductivity and Cryogenics
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• v.11 no.1
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• pp.16-19
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• 2009

Recently, for improvement of the magnetic field of high temperature superconductor (HTS) apparatus, many studies investigating on operating in the range of $20{\sim}65K$ with liquid helium or the conducting method using cryocooler is actively reviewed. Also, the cooling method using solid nitrogen as cryogen is being suggested. Since the nitrogen has very large specific heat in solid state, it is expected that it can enable long time operation without a continuous supply of cooling energy. However, there is still insufficient data on the characteristics of solid nitrogen such as thermodynamic properties and liquid-solid phase change. Especially, there was almost no study done on the electrical insulation properties of solid nitrogen so far. In this study, solid nitrogen to find the electrical characteristics was made by using cryocooler and cryostat, and investigated the flashover discharge and breakdown. The results of this study will be useful as a basic data for electrical insulation design of the HTS system using solid nitrogen as cryogen.

• Journal of the Korean institute of surface engineering
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• v.56 no.5
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• pp.320-327
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• 2023

In this study, the nickel hydroxide (Ni(OH)₂) electrode for supercapacitor was prepared via hydrothermal method. Based on the nickel (Ni) foam, the electrode does not require any additional binder material or post-processing. Nickel nitrate (Ni(NO₃)₂) and hexamethylenetetramine (C₆H₁₂N₄) were used for synthesis, and the synthesis condition was 12 hours at 80 ℃. X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) were used to analyze the structural characteristics of the electrode, and it shown that the nickel hydroxide was successfully prepared after only the one-step hydrothermal synthesis. The electrochemical properties were analyzed through the half-cell test. The prepared electrode shown a pair of oxidation/reduction peaks, indicating that the driving method included the redox reaction on the electrode surface. After the charge/discharge test, the specific capacitance was calculated as the value of 438 F/g at 3 A/g.

• Journal of the Korean Applied Science and Technology
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• v.40 no.6
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• pp.1191-1200
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• 2023

The lithium ion battery has applied to various fields of energy storage systems such as electric vehicle and potable electronic devices in terms of high energy density and long-life cycle. Despite of various research on the electrode and electrolyte materials, there is a lack of research for investigating of the binding materials to replace polymer based binder. In this study, we have investigated petroleum pitch/polymer composite with various ratios between petroleum pitch and polymer in order to optimize the electrochemical and physical performance of the lithium-ion battery based on petroleum pitch/polymer composite binder. The electrochemical and physical performances of the petroleum pitch/polymer composite binder based lithium-ion battery were evaluated by using a charge/discharge test, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and universal testing machine (UTM). As a result, the petroleum pitch(MP-50)/polymer(PVDF) composite (5:5 wt % ratio) binder based lithium-ion battery showed 1.29 gf mm^-1 of adhesion strength with 144 mAh g^-1 of specific dis-charge capacity and 93.1 % of initial coulombic efficiency(ICE) value.

• Journal of the Korean Society of Safety
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• v.38 no.6
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• pp.1-8
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• 2023

The health state of the oil transformer is evaluated by the age of use and the state of internal defects. Mineral Oil, used as an insulator for oil transformers, creates specific gases and compounds through chemical reactions caused by heat, moisture, and partial discharge inside the transformer. It is possible to determine the aging and defect of the transformer through these gases and compounds. So, it is an important indicator to evaluate the health of a transformer. In this study, factors for assessing the health of transformers were hierarchically categorized, and key factors for each hierarchy were selected for design weighting. These weights were determined through surveys conducted with experts in the fields of transformer design, operation, and quality. For the health of a transformer, defect-related factors are approximately three times more important than factors related to aging. Additionally, defect-related factors showed a higher weighting for gases generated at high temperatures. Furthermore, Furan was determined to have a high weight, directly associated with insulating paper aging. Based on these findings, a health index was proposed, and a comparative analysis was conducted by categorizing 40 operational transformers into normal and comparison groups to evaluate and validate it.

• Korean Journal of Ecology and Environment
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• v.42 no.3
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• pp.350-363
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• 2009

Inter- and intra-specific differences in removal activities, filtering rates (FR) and production of feces-and pseudo-feces (PF) between a native freshwater bivalve in Korea, Anodonta woodiana Lea and Unio douglasiae Griffith et Pidgeon, were compared using a continuous removal of organic matters (CROM) system. The CROM system comprised five steps; input of polluted water, control of water flow, mussel treatment, analysis of water quality and discharge of clean water. The study was designed to compare the removal activity of organic matters between A. woodiana and U. douglasiae, and the intra-specific differences between density and length in A. woordiana. Results clearly indicate that two kinds of mussels had obvious removal activities of seston in the eutrophic reservoir. First, if both are similar in shell length, there were no significant inter-specific differences in removal activity between A. woordiana and U. douglasiae (P>0.5), but FRs of U. douglasiae was relatively high due to low ash-fee dry weight. Second, if both are same in animal density, the smaller mussels (1$\sim$2 years old) showed a higher filtering rate and production of feces- and pseudo-feces and less release of ammonium than the larger mussels. Third, if both are same in biomass, FRs and PF of mussels were higher in the low-density tank than the high-density tank, While the Concentration of $NH_4$-N and $PO_4$-P released WRS similar to each other (P>0.5). Therefore, these results suggest that CROM system using a young bivalve A. woordiana can be applied to control the nuisance seston in eutrophic lake system, if a relevant species and density were selected. Additional pilot tests to optimize the age and density of domestic bivalves were needed for the generalization of CROM operation.