• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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• pp.100-101
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• 2004

Many researches in Korea have been performed to understand the pollution of stream waters by acid mine drainage. However, few studies have been conducted regarding the effect of particulate and colloidal fractions on the transport of trace metals. To estimate harmful effects of trace metals, it is important to evaluate the particulate and colloidal metals as well as dissolved metals, because particulate and colloidal fractions of trace metals play an important role in transport of trace metals and may adversely affect habitats and organisms in riverine system. Colloids are solids with effective diameters in size range from 0.001 $\mu$m to 1 $\mu$m. According to Jone et al. (1974), metals in surface water, like Al, Fe, and Mn, require filtration with pore-size membranes smaller than 0.45 $\mu$m to define dissolved concentrations. The main objective of this study is to understand the effects of particulate, colloidal, and truly dissolved fractions on the transport and fate of trace metals in acid mine drainage. This study was conducted for the Onjeong creek in the Uljin mine area. Sampling was carried out in 13 sites, spatially covering the area from mine dumps to the downstream Onjeong reservoir. To examine the metal partitioning between particulate, colloidal, and truly dissolved fraction, we used successive filtration techniques consisting of conventional method (using 0.45 $\mu$m membranes) and tangential-flow ultrafiltration (using 0.001 $\mu$mm membranes). Ultrafiltration may seperate much smaller particles from aqueous phase (Josephson, 1984; Hernandez and Stallard, 1988). The analysis of metals were performed by inductively coupled plasma - atomic emission spectrometer (ICP-AES: model Perkin Elmer OPTIMA3000XL). Anions such as SO$_4$, Cl and NO$_3$ were measured with ion chromatograph (IC: model Dionex 120). Sample analysis is still in progress. The preliminary data show that the studied creek is severely polluted by Al, Fe, Mn, Pb and Zn. Toward upstream sites with relatively lower pH, less than 50% of Al and Fe occur in the sorbed form on particles or colloids, whereas more than 80% of Al and Fe occur in the sorbed form in downstream sites or tributaries with relatively higher pH. Less than 30% of Zn is present in particle or colloidal forms in the whole range of creek. Truly dissolved fraction of trace metals is negatively correlated with pH. The Kd values for Al, Fe and Zn consistently increase with increasing pH and decrease with increasing particle concentration.

• 한국ITS학회 논문지
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• 제18권5호
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• pp.64-78
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• 2019

본 논문은 공간 상관성을 고려하여 서울의 택시통행에 영향을 미치는 요인을 분석한 것으로 택시의 GPS 자료를 이용하였다. 먼저 이들 자료를 이용하여 택시통행의 평균 통행시간, 평균 통행거리, 시공간적 분포 등의 통행특성을 분석하였다. 분석결과, 상당수의 택시통행이 평일 오전 첨두(8-9시)와 심야(0-1시) 시간대에 집중하는 것으로 나타났으며, 평균 통행거리와 통행시간은 각각 5.9km와 13분으로 나타났다. 이는 택시가 주로 단거리 통행수단이나 심야에 대중교통의 대체수단으로 활용되고 있음을 보여주고 있다. 다음으로 Moran's I 검정을 통해 교통존 기반의 택시통행들이 공간적으로 상관성이 있음을 규명하였다. 따라서 이를 고려한 택시통행에 대한 공간회귀모형(공간시차모형과 공간오차모형)을 추정하였으며, 인구사회 변수(가구수, 고령자수, 여성인구비, 자동차대수 등), 교통서비스 변수(지하철역수, 버스 정류장수 등), 토지이용 변수(인구밀도, 고용밀도, 주거면적 등) 등을 독립변수로 고려하였다. 모형분석 결과 이들 변수들이 통계적으로 유의하게 택시통행에 영향을 미치는 것으로 나타났다.