• 제목/요약/키워드: soot 입자

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다양한 화재조건에서 플라스틱 종류에 따른 연기입자의 크기분포 변화 측정 (Measurement of the Size Distribution of Smoke Particles with Plastic Types Under Various Fire Conditions)

  • 구재학;황철홍
    • 한국화재소방학회논문지
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    • 제31권6호
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    • pp.8-15
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    • 2017
  • 화재발생 시에 대부분의 인명 피해는 연기에 의해 발생되는데, 최근 건축 내장재에서 차지하는 플라스틱의 양이 많아지며 발생되는 연기의 유독성이 점차적으로 증가되고 있다. 연기에 의한 인체피해의 상당부분은 흡입연기의 폐침전과 관련이 있으며, 연기입자의 크기분포는 폐침전 특성에 직접적인 영향을 미친다. 따라서 플라스틱 종류에 따른 연기입자의 크기별 발생량 검토는 폐침전에 의한 인체피해 연구에 필수적으로 요구된다. 최근의 목재와 폴리프로필렌(PP)에 대한 연기입자의 발생특성 연구에서 PP의 연기입자 크기분포 특성이 몇 가지 측면에서 목재와는 확연히 다르게 나타났다. 이에 따라, 본 연구에서는 다른 플라스틱들도 연기입자 크기분포에서 PP와 같은 특성을 보이는지 알아보기 위해서 대표적인 4가지 플라스틱(LDPE, PA66, PMMA, PVC)에 대하여 연기입자 크기분포 측정실험을 수행하였다. 특정 조건에서 연소생성물을 균일하게 생성하고 분석하기 위하여 ISO/TS 19700 기준에 따른 등속튜브연소로를 이용하여 연소로의 온도와 산소공급량에 따라 다양한 화재조건에서 연기입자를 균일하게 발생시키고, 정전저압 임팩터를 사용하여 연기입자의 크기에 따른 개수농도를 실시간으로 측정하였다. 실험 결과 4가지 플라스틱의 연기입자 크기분포 특성은 여러 측면에서 PP와 유사하며 목재와는 확연히 다르게 나타났다.

압축착화 엔진에서 함산소 혼합연료의 연소 및 미세입자 배출물 특성 (Combustion and Nano-particulate Emissions Characteristics of a Compression Ignition Engine Fueled with Oxygenated Blending Fuel)

  • 차준표;윤승현;전문수;이창식
    • 한국자동차공학회논문집
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    • 제17권5호
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    • pp.61-66
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    • 2009
  • An experimental investigation was conducted to analyze the effects of biodiesel-ethanol and biodiesel-diesel blended fuels on the characteristics of combustion and exhaust emissions, and size distributions of particulate matter in a single cylinder diesel engine. The three types of test fuel were biodiesel and two blended fuels which were added ethanol and diesel by 20 % volume based fraction into biodiesel, respectively. In this study, the injection rate, combustion pressure, exhaust emissions and size distributions of particulate matter were measured under various injection timings and injection pressures. The experimental results show that biodiesel-ethanol blended fuel has lengthened ignition delay and low combustion pressure in comparison with those of biodiesel and biodiesel-diesel blended fuel even if all fuels indicated similar trends of injection rate under equal injection pressures. In addition, the ethanol blended fuel significantly reduced nitrogen oxidies (NOx) and soot emissions. And then the size distribution of particulate matters shows that blended fuels restrain the formation of particles which were beyond the range of 150nm comparison with biodiesel fuel.

DOC-DPF-SCR 시스템에 의한 디젤 배기 내 $NO_x$, 입자상 물질 저감 과정의 일관 모델링 및 성능 예측 (Unified Modeling and Performance Prediction of Diesel $NO_x$ and PM Reduction by DOC-DPF-SCR System)

  • 정승채;윤웅섭
    • 한국자동차공학회논문집
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    • 제16권4호
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    • pp.110-119
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    • 2008
  • Computer methods with simplified mathematical models in conjunction with empirical model parameters can be efficiently practiced into an optimization of a diesel aftertreatment system. Components of prime interests are diesel particulate filter, diesel oxidation catalyst and de-$NO_x$ catalytic converter. de-$NO_x$, de-PM, and de-HC processes in each part are individually modeled, formulated and then combined into an integrated analysis procedure for a unified simulation of the diesel emission aftertreatment. The model is empirically tuned and validated with comprehensive engine and laboratory data. The effects of emission species and space velocity on the $NO_x$ and soot reductions are parametrically investigated. A lowered $NO_2/NO_x$ ratio due to PM oxidation in DPF contributes to promote the $NO_x$ reduction by SCR at intermediate gas temperatures. $NO_x$ reduction is inert to the PM oxidation at high temperatures. Rate of PM trapping strongly depends on temperature and $NO_x$ concentration.

ELPI를 이용한 산화촉매 장착 고속 직접분사식 디젤엔진의 입자상물질 계측 (Measurements of Particulate Matters for the HSDI Diesel Engine with DOC using the ELPI)

  • 최병철;장세현
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 춘계학술대회
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    • pp.2245-2250
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    • 2003
  • Particulate matters(PM) have bad effect on the health. We carried out measurements of diesel PM under $10{\mu}m$ diameter from a HSDI diesel engine with a diesel oxidation catalyst(DOC) by using the ELPI. This paper compares the two results of the smoke level and the PM level of masses and numbers. We also investigated the effect of the DOC. Under high speed and load, HSDI diesel engine exhausts much masses of particulate matters over 100nm diameter, and a number of PM from 7 to 100nm diameters at the same condition. DOC could reduce the total mass of the PM. However, the DOC could increase the number of ultra fine PM. Before light-off of the soot, the DOC absorb the PM and the DOC oxidize the PM after light-off temperature. The fine PM could be made during the oxidation. Therefore, the advanced DOC is needed to reduce the number of the fine PM.

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EGR Cooler Fouling 저감을 위한 촉매 장착 EGR Cooler System 평가 (Evaluation of Catalyst Assisted EGR Cooler System for EGR Cooler Fouling Reduction)

  • 홍광석;박정수;이교승
    • 한국자동차공학회논문집
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    • 제19권5호
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    • pp.76-81
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    • 2011
  • Exhaust gas recirculation is the well-known and widely used NOx reduction technology for diesel engines. More effective EGR cooler has been developed and applied to diesel engines to meet the reinforced emission regulation. However, the contaminated EGR cooler by diesel exhaust gas reduces the performance of the engine and NOx reduction rate. The buildup of deposits in EGR coolers cause significant degradation in heat transfer performance, often on the order of 20~30%. Deposits also increase pressure drop across coolers and thus may degrade engine efficiency under some operation conditions. In this study, as a solution for this problem, DOC assisted EGR cooler is designed and then investigated to reduce fouling and its impact on cooler performance. A single channel EGR cooler fouling test apparatus and soot particle generator were developed to represent the real EGR cooler and exhaust gas of diesel engine. EGR cooler effectiveness of the case with catalyst of pt 30g/ft3 decreased just up to 5%. This value was 45% less compared to the case without catalyst which decreased up to 9% after 10hours experiments.

난류 혼합 대류유동에서 고 흡수, 방사하는 입자의 열 확산에 관한 연구 (Study on Thermophoresis of Highly Absorbing, Emitting Particles in Turbulent Mixed Convection Flows)

  • 여석준
    • 한국대기환경학회지
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    • 제12권3호
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    • pp.231-241
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    • 1996
  • The effect of radiation and buoyancy on the thermophoresis phenomenon owing to the presence of highly absorbing, emitting particles (such as soot or pulverized coal) suspended in a two phase flow system was investigated numerically for a turbulent mixed convection flow. The analysis of conservation equations for a gas-particle flow system was performed on the basis of a two-fluid model from a continuum Eulerian viewpoint. The modified van Driest and Cebeci mixing length turbulence model was adopted in the anaylsis of turbulent flow. In addition, the P-1 approximation was used to evaluate the radiation heat transfer. As expected from the particle concentration and drift velocity distribution, the cumulative collection efficiency E (x) becomes larger when the buoyancy effect increases (i.e. higher Grashof number), while smaller as the radiation effect increases (i.e. higher optical thickness).

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압축 착화 엔진에서 기존 및 저온 디젤 연소에서 발생하는 배기가스의 입자상 물질에 관한 특성 비교 (Assessment of Particulate Matters from an Exhaust Gas for Conventional and Low Temperature Diesel Combustion in a Compression Ignition Engine)

  • 정용진;신현동;배충식
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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    • pp.183-186
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    • 2012
  • The characteristics of particulate matters (PM) from an exhaust gas for conventional and low temperature diesel combustion (LTC) in a compression ignition engine was experimentally investigated by the elemental, thermogravimetric analysis. Morphology of PM was also studied by the transmission electron microscopy. PM for LTC shows that it contains more volatile hydrocarbons, which can be easily evaporated than conventional regime. PM for LTC is comprised of smaller primary particles.

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연도가스 열회수용 순환유동층 열교환기의 오염저감특성 (Fouling Reduction Characteristics of a Fluidized Bed Heat Exchanger for Flue Gas Heat Recovery)

  • 이금배;전용두
    • 설비공학논문집
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    • 제16권8호
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    • pp.770-777
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    • 2004
  • Fouling and cleaning tests are performed for a uniquely designed 7,000 ㎉/hr fluidized bed heat exchanger for exhaust gas heat recovery. Fuel rich condition is maintained in the combustor for a limited time period to generate soot that is to be deposited on the heat transfer surfaces (fouling) and 600 Um glass beads are circulated inside the heat exchanger system for cleaning and enhancing the heat transfer performance. According to the present experimental study, performance degradation mode could be monitored and the effect of particle circulation on the heat transfer improvement could be identified. Through the present study, it is demonstrated that circulating particles contribute not only to the fouling reduction in gas side, but also to the heat transfer enhancement of the unit, while other possible aging factors including water side corrosion seemed to contribute to the accumulated performance deterioration.

광영동에 있어서의 비대칭인자에 대한 연구 (A Study on the Asymmetry Factor in Photophoresis)

  • 박승호
    • 설비공학논문집
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    • 제7권4호
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    • pp.694-702
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    • 1995
  • When a small absorbing particle is exposed to a strong thermal radiation incidence, it moves towards or away from the radiation source due to the nonuniform internal absorption of the radiation. It is called the photophoretic phenomena and governed by the asymmetry factor. An asymmetry factor for the total wavelength range is calculated to estimate the photophoretic phenomena of a particle in a combustor or in the atmosphere and compared to that for a single wavelength. The samples are soot particulates, water droplets, ice particles, silicon particles, $SiO_2$ particles, aluminium oxide particles, whose spectral complex refractive index are available. Although differences between total and monochromatic asymmertry factors are not much for relatively uniform distribution of the spectral refractive index, they are great in general. Therefore the use of the monochromatic factor will considerably deteriorate the accuracy of the calculation of the photophoresis.

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액중 전기선 폭발법에 의한 Ni-free Fe계 나노 합금분말의 제조: 2. 용매의 영향 및 제조 방법에 따른 분말입자의 비교 (Fabrication of Ni-free Fe-based Alloy Nano Powder by Pulsed Wire Evaporation in Liquid: Part 2. Effect of Solvent and Comparison of Fabricated Powder owing to Fabrication Method)

  • 류호진;이용희;손광욱;공영민;김진천;김병기;윤중열
    • 한국분말재료학회지
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    • 제18권2호
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    • pp.112-121
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    • 2011
  • This study investigated the effect of solvent on the fabrication of Ni-free Fe-based alloy nano powders by employing the PWE (pulsed wire evaporation) in liquid and compared the alloy particles fabricated by three different methods (PWE in liquid, PWE in Ar, plasma arc discharge), for high temperature oxidation-resistant metallic porous body for high temperature soot filter system. Three different solvents (ethanol, acetone, distilled water) of liquid were adapted in PWE in liquid process, while X-ray diffraction (XRD), field emission scanning microscope (FE-SEM), and transmission electron microscope (TEM) were used to investigate the characteristics of the Fe-Cr-Al nano powders. The alloy powder synthesized by PWE in ethanol has good particle size and no surface oxidation compared to that of distilled water. Since the Fe-based alloy powders, which were fabricated by PWE in Ar and PAD process, showed surface oxidation by TEM analysis, the PWE in ethanol is the best way to fabricate Fe-based alloy nano powder.