• Title/Summary/Keyword: solvent-resistance

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Fabrication of transparent conducting films of carbon nanotubes using a spray method

  • Geng, Hong Zhang;Lee, Kyu;Song, Young-Il;Kim, Gil-Yong;Choi, Ha-Kyu;Jun, Bae-Jung;Ahn, Kay-Hyeok;Lee, Young-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.525-528
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    • 2006
  • Transparent conducting films were fabricated on polyethylene terephthalate substrate by a spray method using double-walled carbon nanotubes dispersed in organic solvent and water-based solution. We analyzed the films by absorption spectra, sheet resistance, and scanning electron microscopy. Transparent conducting films with high uniformity and high transparency were fabricated by the spray method. We found that the dispersion particularly nanodispersion of CNTs was of crucial importance to improve the film performance.

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Conducting Characteristics of ABS/PPy Composite Film Prepared by Electrochemical Polymerization (전기화학적 중합으로 제조된 ABS/PPy 복합 박막의 전도특성)

  • Kim, J.;Yoon, D.Y.;Kim, D.H.;Han, C.;Kim, S.
    • Journal of the Korean Electrochemical Society
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    • v.5 no.3
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    • pp.164-167
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    • 2002
  • ABS/Polypyrrole composite film has been synthesized by means of electrochemical polymerization in order to enhance the oxidant stability by using ABS(Acrylonitrile-Butadiene-Strene) as a host-polymer. While the acetonitrile as a solvent swells the host-polymer ABS on Pt plate, and then the pyrrole in an electrolyte penetrates the Pre-coated ABS film during electrochemical Polymerization. Comparing with the sin91e-component Polypynole film, the resulting conducting ABS/PPy composite nim shows the good reliability for the uniform resistance and the enhancement of the oxidant stabilization.

A Study on the Drag Reduction by Shear-thinning Fluid in Turbulent Flow Fields (난류유동장에서 Shear - thinning 유체에 의한 마찰저항 감소에 관한 연구)

  • 차경옥;김재근;오율권
    • Journal of Advanced Marine Engineering and Technology
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    • v.21 no.2
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    • pp.126-135
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    • 1997
  • Drag reduction in polymer solutions is the phenomenon where by extremely dilute solutions of high molecular weight polymers exhibit frictional resistance to flow much lower than the pure solvent. This effect, largely unexplained as yet, has attracted the attention of polymer scientists and fluid flow specialists. Although applications are beginning to appear, the principle interest to data has been in attempting to relate the effect to the fluid mechanics of turbulent flow. Drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, and pool and boiling flow. But the research on drag reduction in two phase flow is not intensively investigated. Therefore, experimental investigations have been carried out to analyze the drag reduction produced by polymer addition in the single phase and two phase flow system. The objectives of the proposed investigation are primarily in identifying and developing high performance polymer additives for fluid transportations with the benefits of turbulent drag. Also we want to is to evaluate the drag reduction in horizontal flow by measuring pressure drop and mean velocity. Experimental results show higher drag reduction using co - polymer(A611P) then using polyacrylamide (PAAM) and faster degradation using PAAM than using A611P under the same superficial velocity.

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Indium Tin Oxide (ITO) Coatings Fabricated using Nanoparticle Slurry and Sol

  • Cheong, Deock-Soo;Yun, Dong-Hun;Kim, Dong-Hwan;Han, Kyoung-R.
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.516-519
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    • 2011
  • Indium tin oxide (ITO) coatings were made using an ITO slurry and an ITO sol. This was achieved by dispersing nanosized ITO powder in a mixed solvent without any dispersant and developing an adhesive ITO sol from indium acetate and tin tetrachloride in a mixture of DMF and n-butanol. Coating was carried out in one step by spin coating an ITO slurry, which was then followed by an ITO sol over it. Here, the sol penetrates into the nano ITO particle layers to make them adhere to each other as well as to a glass substrate. This is then followed by sintering at 500$^{\circ}C$ for 1 h to produce a uniform film consisting of ITO particles of about 50 nm and 10 nm. ITO films were obtained with sheet resistances from 450 to 1500 ohm/${\Box}$ by varying spin speed and concentration. Transmittance is higher than 90% at 550 nm.

Effect of Humidity and Operating Temperature of Polymer Sensor to Methanol Gas (Methanol 가스에 대한 고분자 센서의 온도와 습도 영향 고찰)

  • Lee, K.M.;Hoh, Y.S.;Jun, H.K.;Sohn, S.O.;Huh, J.S.
    • Korean Journal of Materials Research
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    • v.13 no.12
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    • pp.796-800
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    • 2003
  • The polypyrrole prepared with pyrrole monomer, APS and DBSA was synthesized by chemical Polymerization at $V^{\circ}C$ under atmosphere conditions. After dissolving polypyrrole powder to the chloroform including DBSA, polypyrrole film was prepared on the alumina substrate with an interdigitated electrode by using the dip-coating method. This film was soaked in methanol solvent for 1 h at room temperature and heated to $70^{\circ}C$ for 4 h in $N_2$. Initial resistance was increased with the increasing humidity and decreasing temperature. The sensitivity was increased with lower humidity and decreasing temperature. The best linearity was achieved at $25^{\circ}C$ and low humidity of 0%.

A Study on Measurement of Mechanical Properties of Polyther Polyol Base Polyurethane Dispersion by 1,4-butanediol Chain Extension (Polyether Polyol을 이용한 수분산 폴리우레탄의 1,4-butanediol 사슬연장에 의한 물성변화)

  • Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.711-718
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    • 2014
  • In this paper, the mechanical property change was investigated by adding 1,4-butanediol as chain extender of polyurethane dispersion for leather coating. Reagents for the synthesis were polypropylene glycol(PPG), isoporon diisocyanate(IPDI), dimethylolpropionic acid(DMPA) and 1,4-BD. All samples showed good solvent resistance and flexibility by different content of the 1,4-BD. As results, samples which contains a lot of 1,4-BD showed good properties whth strength of $1.80kg_f/mm^2$ and abrasion test measurement of 49.54 mg.loss. According to elongation test, the sample which contains low amount of 1,4-BD was good property as 364 %.

WC-Co Milling Inserts Manufactured by Powder Injection Molding (분말사출성형에 의한 WC-Co 계 milling insert 제조)

  • 성환진
    • Journal of Powder Materials
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    • v.6 no.1
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    • pp.88-95
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    • 1999
  • The purpose of this study is to investigate the manufacturing feasibility of WC-Co milling inserts via Powder Injection Molding (PIM) process. WC-Co is used in a wide variety of cutting tools due to its high hardness, stiffness, compressive strength and wear resistance properties. WC-Co parts for a high stress application were conventionally produced by the press and sinter method, which were Iimited to 2 dimensional shapes. Manufacturing WC-Co parts for a high stress application by PIM implies that tool efficiency can be highly improved due to increased freedom is design. P30 grade WC powder (WC-Co-TiC-TaC system) was mixed with RIST-5B133 binder and injection molded into milling inserts (Taegu Tech. Model WCMX 06T 308). The mean grain size of the powder was about 0.8$\mu$m. Injection molded specimens were debound by solvent extraction and thermal degradation method at various conditions. The specimens were sintered at 140$0^{\circ}C$ for 1 hr in vacuum. Carbon content, weight loss, dimensional change, and macro defects of the specimen were carefully monitored at each stage of the PIM process. PIMed WC-Co milling inserts reached 100% full density after sinteing. Its mechanical properties and micro-structures were comparable with the press and sintered milling insert. Carbon content of the sintered WC-Co insert was mainly determained by the atmosphere of thermal debinding. By controlling powder loading and injection molding condition, dimensional accuracy could be obtained within 0.4%. We confirm that PIM can not only be an alternative manufacturing method for WC-Co parts economically but also provide a design freedom for more effieient cutting tools.

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Synthesis and Properties of Self-photocuring Polyurethane Acrylate Oligomer for Color Pre-coated metal (선도장 컬러강판용 도료에 적용하기 위한 자가 광경화형 폴리우레탄 아크릴레이트 올리고머 합성 및 물성)

  • Park, So-Young;Cheon, Jungmi;Jeong, Boo Young;Lee, Do Hyeok;Chun, Jae Hwan
    • Journal of Adhesion and Interface
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    • v.21 no.1
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    • pp.14-19
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    • 2020
  • In this study, we synthesized a self-photocuring intermediate(SPI) by Michael addition reaction and synthesized polyurethane acrylate oligomer. Analysis and physical properties of the synthesized SPI and polyurethane acrylate oligomer were confirmed by FT-IR, NMR and UTM. As the content of the SPI increased, the tensile strength increased and the elongation decreased. In addition, since the film was hydrophobic, the surface energy tended to decrease. When the content of the SPI was 40 wt%, adhesion, processability, and pencil hardness were excellent, and solvent resistance was excellent overall.

A Development on the Non-Photomask Plate Making Technology for Screen Printing (II) (포토마스크가 필요 없는 스크린 제판 기술 개발(II))

  • Park, Kyoung-Jin;Kang, Hyo-Jin;Kim, Sung-Bin;Nam, Su-Yong;Ahn, Byung-Hyun
    • Journal of the Korean Graphic Arts Communication Society
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    • v.26 no.2
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    • pp.45-54
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    • 2008
  • We have manufactured a photoresist which has excellent dispersity and good applying property due to 330 cps of viscosity for environment-friendly and economical maskless screen plate making. And the photoresist applied on the screen stretched was exposed with mask by UV-LED light source so we could manufacture the photoresist which proper for the UV light source. And it was developed by air spray with $1.7\;kgf/cm^2$ of injection pressure. Because of the excellence of power and resolution of the UV-LED light sourse, the pencil hardness and solvent resistance of curing photoresist film were excellent as those of conventional photoresist film. Moreover the $100{\mu}m$-width stripe image which has sharp edges was formed. So we confirmed a possibility of dry development process by air spray method.

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A Development on the Non-Photomask Plate Making Technology for Screen Printing (III) (포토마스크가 필요 없는 스크린 제판 기술 개발(III))

  • Kang, Hyo-Jin;Park, Kyoung-Jin;Kim, Sung-Bin;Nam, Su-Yong;Ahn, Byung-Hyun
    • Journal of the Korean Graphic Arts Communication Society
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    • v.26 no.2
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    • pp.55-64
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    • 2008
  • We designed a UV-LED exposure system which has 365nm dominant wavelength due to the environment-friendly and economical maskless screen plate making. And the photoresist applied on the screen stretched was exposed without mask by beam projector with UV-LED light source. Then it was developed by air spray with $1.7\;kgf/cm^2$ of injection pressure. The pencil hardness and solvent resistance of curing photoresist film were excellent as those of conventional photoresist film and the maximum resolution of line image formed by maskless screen plate making. was $100{\mu}m$, so we could establish the possibility of environment-friendly maskless screen plate making technology. But the sharpness of the patterns were ${\pm}40{\mu}m$ since the exposure system for maskless plate making has weak light intensity and the diffusion of light.

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